TRIS(2,3-DIBROMOPROPYL) PHOSPHATE

TRIS(2,3-DIBROMOPROPYL) PHOSPHATE = TBPP

CAS Number: 126-72-7 
EC Number: 204-799-9
Chemical formula: C9H15Br6O4P
Molar mass: 697.613 g·mol−1

Tris(2,3-dibromopropyl) phosphate ("tris") is a chemical once widely used as a flame retardant in plastics and textiles.

Tris(2,3-dibromopropyl) phosphate is a synthetic, colorless or pale yellow liquid that is insoluble in water and miscible with carbon tetrachloride, chloroform and methylene chloride. 
Tris(2,3-dibromopropyl) phosphate is no longer used in the United States. 
The primary routes of human exposure to TRIS-BP are inhalation, dermal contact and ingestion. 
Since this compound is no longer produced in the United States, the risk of exposure is low. 

However, TRIS-BP persists in fabric and plastics, making occupational and consumer exposure possible. 
Contact with this chemical can irritate the eyes and skin. 
Tris(2,3-dibromopropyl) phosphate is reasonably anticipated to be a human carcinogen. 

Tris(2,3-dibromopropyl) phosphate is a clear colorless to pale yellow viscous liquid. 
Tris(2,3-dibromopropyl) phosphate is a trialkyl phosphate.

Tris(2,3-dibromopropyl) phosphate, a widely used flame-retardant additive for textiles, is mutagenic to histidine-requiring strains of Salmonella typhimurium. 
Extracts of fabrics treated with this compound are also capable of inducing mutations in these bacterial strains.

Sensitivity to a flame retardant, Tris(2,3-dibromopropyl)phosphate (Firemaster LVT 23 P)
Tris(2,3-dibromopropyl) phosphate (TBPP) is marketed under many different trade names as a flame retardant, used in clothing and home furnishings. 
TBPP is chemically related to tricresylphosphate (TCP) and triphenylphosphate (TPP) used as plasticizers in plastics and lacquers.

The International Contact Dermatitis Research Group (ICDRG) in 1976 examined the incidence of sensitization to TDB P and found two positives among 1103 patients.
One of these two cases is reported here in detail. 
Tris(2,3-dibromopropyl) phosphate concerns a woman, aged 56, with spectacle frame dermatitis. 
The spectacle frame did not contain TDB P and sensitization with another phosphate ester is assumed.

Tris(2,3-dibromopropyl) phosphate (TDBPP) was famously banned from being used as a flame-retardant in children’s clothing in 1977, but Tris(2,3-dibromopropyl) phosphate was also extensively used in other products such as polyurethane and polystyrene foams. 
Although Tris(2,3-dibromopropyl) phosphate is not currently produced, applied, or marketed as a flame retardant, TDBPP may be added to polymers for other purposes. 

Method for determining tris (2,3-dibromopropyl) phosphate content of water:
The invention provides a method for determining tris (2, 3-dibromopropyl) phosphate content of water, and belongs to the field of organic phosphate flame retardant. 
The method mainly comprises the following steps: (1) conducting solid-phase extraction on a sample; (2) eluting and collecting the extraction column; (3) concentrating the eluent obtained in the step (2) to a constant volume; and (4) determining the concentrated liquid with a high-performance liquid chromatograph-triple quadrupole mass spectrometer. 

The method provided by the invention improves determination method of tris (2,3-dibromopropyl) phosphate in water environment; and through ultra performance liquid chromatograph-triple quadrupole mass spectrometry combination, the method for detecting tris (2,3-dibromopropyl) phosphate method has more advantages than other methods. 
The present invention using ultra performance liquid chromatograph has larger separation speed than gas chromatograph and general high performance liquid chromatograp; triple quadrupole mass spectrometry for SRM scanning realizes higher selectivity, more accurate qualitative diagnosis, and improved sensitivity. 
Therefore, the method provided by the invention has obvious advantages compared with other gas-phase method and liquid mass chromatography method.

Physical Description of Tris(2,3-dibromopropyl) phosphate:
Tris(2,3-dibromopropyl) phosphate is a clear colorless to pale yellow viscous liquid. 

General Manufacturing Information of Tris(2,3-dibromopropyl) phosphate:
Commercial production of tris(2,3-dibromopropyl) phosphate in the US was first reported in 1959.

As a result of actions taken on 8 April and 1 June 1977, the USA Consumer Product Safety Commission banned children's clothing treated with tris(2,3-dibromopropyl) phosphate, the chemical itself when used or intended to be used in children's clothing and fabric, yarn, or fiber containing Tris(2,3-dibromopropyl) phosphate when intended for use in such clothing.

Occurrence of Tris(2,3-dibromopropyl) phosphate:

Occupational exposure of Tris(2,3-dibromopropyl) phosphate:
Occupational exposures to tris(2,3-dibromopropyl) phosphate may have occurred during Tris(2,3-dibromopropyl) phosphate production in the textile and polyurethane foam industries.

Environmental occurrence of Tris(2,3-dibromopropyl) phosphate:
Environmental release in the past has been shown to result from textile finishing plants and laundering of the finished product.
Tris(2,3-dibromopropyl) phosphate was found in the air and soil in the United States in the 1970s. 
None was found in samples taken from various water and soil sources in Japan at this time. 
General population exposures may have occurred from the use of clothing treated with the compound.

Uses of Tris(2,3-dibromopropyl) phosphate:
TBPP is not manufactured in Australia, and to date, has not been imported into TBPP is not currently used in Australia, and there is no available information on former uses. 
In the past, TBPP was considered an important commercial flame retardant for children’s sleepwear. 

However, TBPP has since been banned for use in children’s clothing in the US, as a fire retardant in textile products in Japan, and in textile articles such as garments and linen in the European Commission (EC). 
Therefore, clothing and textiles imported from the US, Japan and Europe will not be treated with TBPP.

A review of import data of textiles and ready-to-wear clothing in Australia indicates that textiles and clothing are imported into Australia from countries that
do not have any restrictions or ban on the use of TBPP to treat clothing. 
Imports from these countries have increased from the year 2000 to date.

Tris(2,3-dibromopropyl) phosphate is used as flame retardant (rigid foams, clear cast acrylic sheet, lacquers, styrene-butadiene rubber, latex rubber, cured unsaturated polyesters, and plastics); From 1972-1976, infants and children were exposed by skin absorption and ingestion to TRIS treated garments.

Production of tris(2,3-dibromopropyl) phosphate in the United States in 1975 was estimated to be between 4100 and 5400 tonnes. 
There are no reports of current production anywhere other than for research purposes.

Tris(2,3-dibromopropyl) phosphate has been used as a flame retardant for plastics and in synthetic textiles and fibres, which have been fabricated into children’s clothing.

Tris(2,3-dibromopropyl) Phosphate is a flame retardant that has previously shown to be a mutagen and carcinogen in experimental animals. 
Tris(2,3-dibromopropyl) Phosphate is widely used in pastics an d textiles.

Flame retardant for plastics and synthetic fibers. 
Formerly used in children's sleepwear.

Former uses: Tris(2,3-dibromopropyl) phosphate has been recommended for use in phenolic resins, paints, paper coatings & rubber. 
Tris(2,3-dibromopropyl) phosphate is used mainly in polyester & cellulosic acetate fabrics, but Tris(2,3-dibromopropyl) phosphate has also been used in acrylic fabrics. 
Tris(2,3-dibromopropyl) phosphate may be added to textiles by the producer, although addn by dyers & finishers is believed to be more usual, at a level of 6-10% by wt. 
Tris(2,3-dibromopropyl) phosphate addn to polyurethane foams is the major use in plastics; relatively small amounts are believed to be used as an additive to polystyrene foam. 
Rigid foams containing tris(2,3-dibromopropyl) phosphate are used in insulation, furniture, automobile interior parts & water floatation devices.

Tris(2,3-dibromo-1-propyl) phosphate (TRIS) is no longer used in the United States. 
Major uses for TRIS were in plastics & flame retardant additive used in children's nightwear. 
Other applications included the treatment of packaging, draperies, institutional bedding, toys, doll clothing, & wigs.

Flame-retardant for plastics and synthetic fibers. 

Tris(2,3-dibromopropyl) phosphate was used in the United States for making flame-retardant children's clothing. 
In 1977, the Consumer Product Safety Commission banned the use of tris(2,3-dibromopropyl) phosphate in children's clothing and in fabric, yarn, and fiber when intended for use in such clothing.

Tris(2,3-dibromopropyl) phosphate has also been used as a flame retardant in polyurethane foams for cushioning, insulation, furniture, and automobile and aircraft interior parts, as well as in polystyrene foam, acrylic carpets and sheets, water flotation devices, polyvinyl and phenolic resins, paints, lacquers, paper coatings, styrene-butadiene rubber, and latexes.

Use Classification of Tris(2,3-dibromopropyl) phosphate:
Health Hazards: Carcinogens

Household Products of Tris(2,3-dibromopropyl) phosphate:
Information on 1 consumer products that contain Tris(2,3-dibromopropyl)phosphate in the following categories is provided:
Pet Care

Methods of Manufacturing of Tris(2,3-dibromopropyl) phosphate:    
A 2 step process in which bromine is added to allyl alcohol and the resultant 2,3-dibromopropanol is reacted with phosphorus oxychloride (possibly in the presence of an aluminum chloride catalyst).

Impurities of Tris(2,3-dibromopropyl) phosphate:    
Impurities in tris(2,3-dibromopropyl) phosphate include 2,3-dibromopropanol, 1,2,3- tribromopropane and 1,2-dibromo-3-chloropropane.

Formulations/Preparations of Tris(2,3-dibromopropyl) phosphate:    
High purity grade: volatiles, 1.5%
bromine content, 68.7% maximum
phosphorus content, 4.4%. Low purity grade
volatiles, 10% maximum.

Analytic Laboratory Methods of Tris(2,3-dibromopropyl) phosphate:
Method: EPA-RCA 8270D; Procedure: gas chromatography/mass spectrometry; Analyte: tris(2,3-dibromo-1-propyl) phosphate; Matrix: solid waste matrices, soils, air sampling media and water; Detection Limit: 200 ug/L.

OSW Method 8321. 
Determination of Solvent Extractable Non-Volatile Compounds by High Performance Liquid Chromatography/ Thermospray/Mass Spectrometry (HPLC/TSP/MS) or Ultraviolet (UV) Detection. 
Detection limit = 33.0 ng/uL.

Method is described for collecting semi- and nonvolatile brominated organic compounds incl tris-bp from air by using glass fiber filter and high vol air sampler. 
Analysis is by either computerized gas liquid chromatography mass spectrometry, gas liquid chromatography with electron capture detection or thin layer chromatography.

The flame retardant tris-(2,3-dibromopropyl) phosphate (Tris) was chromatographed on silica gel thin layer plates, using ethyl acetate-hexane (30+70) as the developing solvent. 
Tris was visualized by spraying the chromatogram with 1% aqueous silver nitrate followed by exposure to ultraviolet light for 40 min. 
Tris appeared as dark gray spots on a white background; the spots were quantitated by densitometry at 660 nm. 

The lower level of sensitivity was 50 ng; calibration plots were linear from 50 to 800 ng. 
The procedure was developed to determine the levels of unmetabolized Tris remaining after exposure to sewage sludge suspensions. 
Recovery of Tris from 3 sewage sludge samples fortified at the 1.0 ppm level averaged 97%.

Nonfire Spill Response of Tris(2,3-dibromopropyl) phosphate:
SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. 
Then, use absorbent paper to pick up all liquid spill material. 

Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. 
Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. 
Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. 

STORAGE PRECAUTIONS: You should store this chemical under refrigerated temperatures and away from mineral acids and bases. 

Safe Storage of Tris(2,3-dibromopropyl) phosphate:    
Separated from food and feedstuffs.

Storage Conditions of Tris(2,3-dibromopropyl) phosphate:
Storage site should be as close as practicable to lab in which carcinogens are to be used, so that only small quantities required for expt need to be carried. 
Carcinogens should be kept in only one section of cupboard, explosion-proof refrigerator, or freezer (depending on chemicophysical properties) that bears appropriate label. 

An inventory should be kept, showing quantity of carcinogen & date Tris(2,3-dibromopropyl) phosphate was acquired.
Facilities for dispensing should be contiguous to storage area.

Safety and regulation of Tris(2,3-dibromopropyl) phosphate:
Tris is mutagenic and listed as an IARC Group 2A carcinogen.
Tris(2,3-dibromopropyl) phosphate is one of the chemicals covered by the Rotterdam Convention. 
In the United States, the Consumer Product Safety Commission banned the sale of children's garments containing tris in 1977.
Arlene Blum was one of those involved in getting tris banned.

Safety Profile of Tris(2,3-dibromopropyl) phosphate:
Confirmed carcinogen with experimental carcinogenic, neoplastigenic, tumorigenic, and teratogenic data. 
Poison by intraperitoneal route. Moderately toxic by ingestion, Experimental reproductive effects. 
Human mutation data reported. An eye and severe skin irritant. 

Can cause testicular atrophy and sterility. 
Once used as a flame retardant addtive to synthetic textiles and plastics, particularly in children's sleepwear. 
Use discontinued because Tris(2,3-dibromopropyl) phosphate can be absorbed by human skin, or chewed or sucked off sleepwear by infants, May be flammable when exposed to heat or flame. 
When heated to decomposition Tris(2,3-dibromopropyl) phosphate emits very toxic fumes of Brand POx.

First Aid of Tris(2,3-dibromopropyl) phosphate:    
EYES: First check the victim for contact lenses and remove if present. 
Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. 
Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. 
IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. 

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. 
Gently wash all affected skin areas thoroughly with soap and water. 
IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. 
IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas. 

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. 
IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop. 
Provide proper respiratory protection to rescuers entering an unknown atmosphere. 
Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. 

INGESTION: DO NOT INDUCE VOMITING. 
If the victim is conscious and not convulsing, administer a slurry of activated charcoal in water and simultaneously call a hospital or poison control center. 
IMMEDIATELY transport the victim to a hospital. 
If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. 
DO NOT INDUCE VOMITING. 
IMMEDIATELY transport the victim to a hospital. 

OTHER: Since this chemical is a known or suspected carcinogen you should contact a physician for advice regarding the possible long term health effects and potential recommendation for medical monitoring. 
Recommendations from the physician will depend upon the specific compound, Tris(2,3-dibromopropyl) phosphate chemical, physical and toxicity properties, the exposure level, length of exposure, and the route of exposure.

Fire Fighting of Tris(2,3-dibromopropyl) phosphate:    
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher.

Isolation and Evacuation of Tris(2,3-dibromopropyl) phosphate:    
As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. 

SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. 

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. 

Spillage Disposal of Tris(2,3-dibromopropyl) phosphate:
Personal protection: chemical protection suit and filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. 
Do NOT let this chemical enter the environment. 

Collect leaking and spilled liquid in sealable containers as far as possible. 
Absorb remaining liquid in sand or inert absorbent. 
Then store and dispose of according to local regulations.

Cleanup Methods of Tris(2,3-dibromopropyl) phosphate:    
A high-efficiency particulate arrestor (HEPA) or charcoal filters can be used to minimize amt of carcinogen in exhausted air, ventilated safety cabinets, lab hoods, glove boxes or animal rooms.
Filter housing that is designed so that used filters can be transferred into plastic bag without contaminating maintenance staff is avail commercially. 
Filters should be placed in plastic bags immediately after removal. 

The plastic bag should be sealed immediately.
The sealed bag should be labelled properly.
Waste liquids should be placed or collected in proper containers for disposal. 
The lid should be secured & the bottles properly labelled. 

Once filled, bottles should be placed in plastic bags, so that outer surface is not contaminated.
The plastic bag should also be sealed & labelled.
Broken glassware should be decontaminated by solvent extraction, by chemical destruction, or in specially designed incinerators. 

Disposal Methods of Tris(2,3-dibromopropyl) phosphate:
Generators of waste (equal to or greater than 100 kg/month) containing this contaminant, EPA hazardous waste number U235, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.

There is no universal method of disposal that has been proved satisfactory for all carcinogenic compounds, & specific methods of chem destruction published have not been tested on all kinds of carcinogen-containing waste.
Summary of avail methods & recommendations given must be treated as guide only. 

Incineration may be only feasible method for disposal of contaminated laboratory waste from biological expt. 
However, not all incinerators are suitable for this purpose. 
The most efficient type is probably the gas-fired type, in which a first stage combustion with a less than stoichiometric air:fuel ratio is followed by a second stage with excess air. 
Some are designed to accept aqueous & organic solvent solutions, otherwise Tris(2,3-dibromopropyl) phosphate is necessary to absorb soln onto suitable combustible material, such as sawdust. 
Alternatively, chem destruction may be used, esp when small quantities are to be destroyed in laboratory. 

HEPA (high-efficiency particulate arrestor) filters can be disposed of by incineration. 
For spent charcoal filters, the adsorbed material can be stripped off at high temp & carcinogenic wastes generated by this treatment conducted to & burned in an incinerator.

LIQUID WASTE: Disposal should be carried out by incineration at temp that ensure complete combustion. 

SOLID WASTE: Carcasses of lab animals, cage litter, & misc solid wastes should be disposed of by incineration at temp high enough to ensure destruction of chem carcinogens or their metabolites. 

Preventive Measures of Tris(2,3-dibromopropyl) phosphate:    
The scientific literature for the use of contact lenses by industrial workers is inconsistent. 
The benefits or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. 

However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. 
In those specific cases, contact lenses should not be worn. 
In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

Smoking, drinking, eating, storage of food or of food & beverage containers or utensils, & the application of cosmetics should be prohibited in any laboratory. 
All personnel should remove gloves, if worn, after completion of procedures in which carcinogens have been used. 
They should wash hands, preferably using dispensers of liq detergent, & rinse thoroughly. 

Consideration should be given to appropriate methods for cleaning the skin, depending on nature of the contaminant. 
No standard procedure can be recommended, but the use of organic solvents should be avoided. 
Safety pipettes should be used for all pipetting. 

In animal laboratory, personnel should remove their outdoor clothes & wear protective suits (preferably disposable, one-piece & close-fitting at ankles & wrists), gloves, hair covering, & overshoes.
Clothing should be changed daily but discarded immediately if obvious contamination occurs also workers should shower immediately. 
In chemical laboratory, gloves & gowns should always be worn however, gloves should not be assumed to provide full protection. 
Carefully fitted masks or respirators may be necessary when working with particulates or gases, & disposable plastic aprons might provide addnl protection. 
If gowns are of distinctive color, this is a reminder that they should not be worn outside of lab. 

Operations connected with synth & purification should be carried out under well-ventilated hood. 
Analytical procedures should be carried out with care & vapors evolved during procedures should be removed. 
Expert advice should be obtained before existing fume cupboards are used & when new fume cupboards are installed. 

Tris(2,3-dibromopropyl) phosphate is desirable that there be means for decreasing the rate of air extraction, so that carcinogenic powders can be handled without powder being blown around the hood. 
Glove boxes should be kept under negative air pressure. 
Air changes should be adequate, so that concn of vapors of volatile carcinogens will not occur.

Identifiers of Tris(2,3-dibromopropyl) phosphate:
CAS Number: 126-72-7 
ChemSpider: 29089
ECHA InfoCard: 100.004.364 
PubChem CID: 31356
UNII: X7O89N7ZY0 
CompTox Dashboard (EPA): DTXSID5021413 
InChI: InChI=1S/C9H15Br6O4P/c10-1-7(13)4-17-20(16,18-5-8(14)2-11)19-6-9(15)3-12/h7-9H,1-6H2
SMILES: BrCC(Br)COP(=O)(OCC(Br)CBr)OCC(Br)CBr

Properties of Tris(2,3-dibromopropyl) phosphate:
Chemical formula: C9H15Br6O4P
Molar mass: 697.613 g·mol−1
Density: 2.24 g/cm3
Solubility in water: Insoluble

Molecular Weight: 697.6    
XLogP3-AA: 4.3    
Hydrogen Bond Donor Count: 0    
Hydrogen Bond Acceptor Count: 4    
Rotatable Bond Count: 12    
Exact Mass: 697.57467    
Monoisotopic Mass: 691.58082    
Topological Polar Surface Area: 44.8 Ų    
Heavy Atom Count: 20    
Formal Charge: 0    
Complexity: 255    
Isotope Atom Count: 0    
Defined Atom Stereocenter Count: 0    
Undefined Atom Stereocenter Count: 3    
Defined Bond Stereocenter Count: 0    
Undefined Bond Stereocenter Count: 0    
Covalently-Bonded Unit Count: 1    
Compound Is Canonicalized: Yes

grade: analytical standard
CofA: current certificate can be downloaded
packaging: ampule of 1000 mg
technique(s):
HPLC: suitable
gas chromatography (GC): suitable
application(s): environmental
format: neat
storage temp.: 2-30°C
SMILES string: BrCC(Br)COP(=O)(OCC(Br)CBr)OCC(Br)CBr
InChI: 1S/C9H15Br6O4P/c10-1-7(13)4-17-20(16,18-5-8(14)2-11)19-6-9(15)3-12/h7-9H,1-6H2
InChI key: PQYJRMFWJJONBO-UHFFFAOYSA-N

Hazards of Tris(2,3-dibromopropyl) phosphate:
Flash point: > 110 °C (230 °F)

Names of Tris(2,3-dibromopropyl) phosphate:

Preferred IUPAC name of Tris(2,3-dibromopropyl) phosphate:
Tris(2,3-dibromopropyl) phosphate

Other names of Tris(2,3-dibromopropyl) phosphate:
Fyrol HB 32
Tris

Synonyms of Tris(2,3-dibromopropyl) phosphate:
Tris(2,3-dibromopropyl) phosphate
126-72-7
Tris(2,3-dibromopropyl)phosphate
TDBPP
Anfram 3PB
Flacavon R
Flammex AP
Zetofex ZN
Tris (flame retardant)
Tris-BP
Tdbp
Firemaster T23p-lv
Flammex T 23P
Zetifex zn
Flamex T 23P
Usaf do-41
Bromkal P 67-6HP
Firemaster T23P
Firemaster LV-T 23P
Phoscon UF-S
FireMaster T 23
Phoscon PE 60
Flammex LV-T 23P
Fyrol HB 32
Tris(dibromopropyl) phosphate
(2,3-Dibromopropyl) phosphate
3PBR
Rcra waste number U235
2,3-Dibromo-1-propanol phosphate
APEX 462-5
NCI-C03270
T 23P
FireMaster T 23P
NSC 3240
UNII-X7O89N7ZY0
1-Propanol, 2,3-dibromo-, phosphate (3:1)
Tris-(2,3-dibrompropyl)fosfat
Tris(2,3-dibromopropyl) phosphoric acid ester
ES 685
Phosphoric acid, tris(2,3-dibromopropyl) ester
Tris-2,3-dibrompropyl ester kyseliny fosforecne
X7O89N7ZY0
CHEBI:82282
1-Propanol,2,3-dibromo-, 1,1',1''-phosphate
1-Propanol, 2,3-dibromo-, 1,1',1''-phosphate
DSSTox_CID_1413
DSSTox_RID_76148
DSSTox_GSID_21413
Fyrol HB32
TDBP 
Tris (VAN)
Tris(dibromopropyl)phosphate
CAS-126-72-7
CCRIS 614
HSDB 2581
2,3-Dibromo-1-propanol phosphate (3:1)
ES685
EINECS 204-799-9
RCRA waste no. U235
BRN 1915153
Tris-(2,3-dibrompropyl)fosfat 
TRIS-(2,3-DIBROMOPROPYL)PHOSPHATE
AI3-19170
TRIS(2,3-DIBROMO-1-PROPYL) PHOSPHATE
Tris-2,3-dibrompropyl ester kyseliny fosforecne 
SCHEMBL26576
CHEMBL1904600
DTXSID5021413
tri-(2,3-dibromopropyl)phosate
PQYJRMFWJJONBO-UHFFFAOYSA-
NSC3240
NSC-3240
Tox21_201798
Tox21_302967
tris-(2,3-dibromopropyl) phosphate
AKOS015914154
1-Propanol, 2,3-dibromo-, phosphate
NCGC00163880-01
NCGC00163880-02
NCGC00256444-01
NCGC00259347-01
Phosphoric acid tris(2,3-dibromopropyl)
WLN: E1YE1OPO & O1YE1EO1YE1E
TBPP, PESTANAL(R), analytical standard
1-Propanol,3-dibromo-, phosphate (3:1)
DB-041837
FT-0631736
Phosphoric acid tri(2,3-dibromopropyl) ester
C19182
J-005427
Q2443865
Tris(2,3-dibromopropyl) phosphate, analytical standard
1-[bis(2,3-dibromopropoxy)phosphoryloxy]-2,3-dibromo-propane
Tris(2,3-dibromopropyl) phosphate 100 microg/mL in Acetone
126-72-7 [RN]
2,3-dibromo-1-propanol phosphate (3:1)
204-799-9 [EINECS]
FireMaster T 23P
Flam mex T 23P
Fyrol HB 32
MFCD00039191
Phosphate de tris(2,3-dibromopropyle) 
Phosphoric acid tris(2,3-dibromo propyl) ester
TBPP
TDBPP
TRIS [Wiki]
Tris(2,3-dibromopropyl) phosphate 
Tris(2,3-dibrompropyl)phosphat 
UB0350000
UNII:X7O89N7ZY0
(2,3-Dibromopropyl) phosphate
1867-14-7 
1-Propanol, 2,3-dibromo-, 1,1',1''-phosphate
1-Propanol, 2,3-dibromo-, phosphate
1-Propanol, 2,3-dibromo-, phosphate (3:1)
1-Propanol,2,3-dibromo-, 1,1',1''-phosphate
2,3-DIBROMO-1-PROPANOL PHOSPHATE
2,3-Dibromopropyl phosphate 
3PBR
55962-48-6 
68112-30-1 
anfram 3pb
apex 462-5
bromkal p 67-6hp
E1YE1OPO & O1YE1EO1YE1E
ES685
firemaster lv-t 23p
FireMaster T 23
firemaster t23p
Firemaster T23P-LV
flacavon r
flamex t 23p
flammex ap
flammex lv-t 23p
flammex t 23p
fyrol hb32
Phoscon PE 60
Phoscon UF-S
Phosphoric acid tri(2,3-dibromopropyl) ester
phosphoric acid tris-(2,3-dibromopropyl) ester
Phosphoric acid, tris(2, 3-dibromopropyl) ester
phosphoric acid, tris(2,3-dibromopropyl) ester
T 23P
Tdbp
tris (flame retardant)
Tris(2, 3-dibromopropyl) phosphate
Tris(2,3-dibromo-1-propyl) phosphate
Tris(2,3-dibromo-1-propyl)phosphate
Tris(2,3-dibromopropyl) phosphoric acid ester
TRIS(2,3-DIBROMOPROPYL)PHOSPHATE
Tris-(2,3-dibrompropyl)fosfat
Tris-(2,3-dibrompropyl)fosfat
Tris(dibromopropyl) phosphate
Tris(dibromopropyl)phosphate
Tris-2,3-dibrompropyl ester kyseliny fosforecne
TRIS-BP
Zetifex ZN
zetifex zn.
Zetofex ZN