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TRIS(2-METHYLPROPYL) PHOSPHATE

Tris(2-methylpropyl) phosphate is a very strong polar solvent, sometimes known as Phosphoric acid triisobutyl ester. 
Tris(2-methylpropyl) phosphate is primarily used as an admixture for liquefying concrete, paper coating systems, and textile auxiliaries. 
Tris(2-methylpropyl) phosphate is mainly used as an antifoaming agent in various aqueous systems, where it can destroy foam and act as a foam inhibitor. 

CAS Number: 126-71-6
EC Number: 204-798-3
IUPAC Name: tris(2-methylpropyl) phosphate
Chemical Formula: C12H27O4P

Other names: 126-71-6, Tri-isobutylphosphate, Isobutyl phosphate, tris(2-methylpropyl) phosphate, UNII-6MKE1AR3GB, 6MKE1AR3GB, EINECS 204-798-3, NSC 62222, BRN 1710574, DTXSID8040698, AI3-07850, NSC-62222, DTXCID6020698, EC 204-798-3, 4-01-00-01598 (Beilstein Handbook Reference), Phosphoric acid, tris(2methylpropyl) ester, hrkamjbpfphcsd-uhfffaoysa-n, tri-isobutyl phosphate, Phosphoric acid, tris(2-methylpropyl) ester, Phosphoric acid, triisobutyl ester, tibp, Phosphoric acid triisobutyl ester, 2-methylpropyl di2-methylpropyl phosphate, Phosphoric Acid Tris(2-?methylpropyl) Ester, C12H27O4P, tri-iso-butyl phosphate, Phosphoric acid tris(2-methylpropyl) ester, MFCD00039849, NCIOpen2_002692, SCHEMBL133326, CHEMBL1887508, CHEBI:189140, Isobutyl phosphate, (C4H9O)3PO, NSC62222, Tox21_301244, SBB060664, AKOS015841700, CS-W023038, FI34259, NCGC00164020-01, NCGC00255412-01, AS-13612, CAS-126-71-6, NS00008118, ST50411046, D70387, Q15632813

Tris(2-methylpropyl) phosphate is also used to introduce solutions for synthetic resins and natural rubber. 
In both ellulose-based plastics and synthetic resins, Tris(2-methylpropyl) phosphate is used as a flame-retarding plasticizer. 
Tris(2-methylpropyl) phosphate is employed as a pasting agent for pigment pastes. 

Due to the limited influence of temperature on the viscosity of Tris(2-methylpropyl) phosphate, it also serves as an important component in the manufacture of hydraulic fluids for aircraft. 
As a very strong wetting agent, Tris(2-methylpropyl) phosphate is used in the textile industry and the field of adhesives.
Tris(2-methylpropyl) phosphate is a trialkyl phosphate.
Tris(2-methylpropyl) phosphate is a chemical that is used as an additive in gasoline. 

Tris(2-methylpropyl) phosphate has been shown to inhibit apoptosis by blocking the mitochondrial pathway of apoptosis. 
Tris(2-methylpropyl) phosphate can be found in urine samples, and can be detected using surface methodology on live cells. 

Tris(2-methylpropyl) phosphate also has chemical stability in organic solvents such as hydrochloric acid and inorganic acids such as sulfuric acid. 
The hydroxyl group on the molecule makes it an excellent solid catalyst for a variety of reactions, including the oxidation of fatty acids by hydrogen peroxide. 

The ester linkages make it possible for TBP to be analyzed by gas chromatography with mass spectrometry. 
This compound is also used as a reagent for preparation of fatty acids for analytical methods such as GC-MS or GC-FID analysis.
Tris(2-methylpropyl) phosphate is a hidden gem in industrial chemicals. 

Tris(2-methylpropyl) phosphate is a very strong solvent used for liquefying concrete, textile auxiliaries, paper coating compounds, glues, adhesives, plastic dispersions, drilling fluids and more.  
Tris(2-methylpropyl) phosphate is also used in the reduction of solutions of synthetic resins and natural rubber. 
In both cellulose-based plastics and synthetic resins, Tris(2-methylpropyl) phosphate is used as a flame-retarding plasticizer.

Tris(2-methylpropyl) phosphate, pivotal in various applications, could be the key ingredient you need for enhanced efficiency and quality in your production processes.
Tris(2-methylpropyl) phosphate, or TIBP, is a versatile chemical used in multiple industries. 
Tris(2-methylpropyl) phosphate's unique properties make it invaluable for applications like defoaming in waterborne systems and as an aid in cement grinding.

Tris(2-methylpropyl) phosphate is a colorless, transparent liquid which has a slight odor. 
Tris(2-methylpropyl) phosphate has a density between 0.96 and .97 and a boiling point of 272 degrees Celsius. 
Tris(2-methylpropyl) phosphate acts as a defoamer and penetrant in inks.

Tris(2-methylpropyl) phosphate is mainly used as a defoaming agent in waterborne systems. 
In aqueous solution, Tris(2-methylpropyl) phosphate can assist with inhibition of freezing and the formation of foam. 
Tris(2-methylpropyl) phosphate is compatible for use with TIPA and DEIPA in the production of cement grinding aids (CGAs).

Tris(2-methylpropyl) phosphate Chemical Properties
Melting point: <-60°C
Boiling point: ~205 °C(lit.)
Density: 0.965 g/mL at 20 °C(lit.)
Vapor pressure: 0.002 hPa (20 °C)

Refractive index: n20/D 1.420
Fp: 150 °C
Storage temp.: Store below +30°C.
Solubility: 0.26g/l
Form: Oil

Color: Colourless
Water Solubility: 264mg/L at 25℃
InChI: InChI=1S/C12H27O4P/c1-10(2)7-14-17(13,15-8-11(3)4)16-9-12(5)6/h10-12H,7-9H2,1-6H3
InChIKey: HRKAMJBPFPHCSD-UHFFFAOYSA-N
LogP: 3.72 at 25℃
CAS DataBase Reference: 126-71-6(CAS DataBase Reference)
EPA Substance Registry System: Tris(2-methylpropyl) phosphate (126-71-6)

Uses    
Partition behavior in water, sediment, and soil
Phosphate ester flame retardants enter the environment from industrial sources and disposal of consumer products containing flame retardants. 
These anthropogenic compounds have been detected in water, soil, and air owing to widespread use following their fast emergence and popularization during 1970s. 
Occurrence of these phosphate ester flame retardants is widespread in surface water and groundwater because of the leaching of PVC plastics and polyurethane foams, effluent from industrial sources, and spills of hydraulic fluids. 

This primary contaminated water is then transported to a secondary source, such as drinking water. 
Hydrolysis, although slow because of poor solubility and pH dependence, is the most important abiotic elimination process. 
In soil and sediment, phosphate ester flame retardants are persistent because they have the tendency to adsorb strongly. 
Volatilization and biodegradation are potential elimination processes for phosphate esters adsorbed to soil.

Environmental persistency (degradation/speciation)
These retardants can change chemical composition in the environment. 
Generally, most phosphate esters are poorly soluble in water and adsorb strongly to soils. 
These compounds are considered emerging pollutants because of their prevalence and persistence in the environment. 
Particulate-phase phosphate esters are subject to wet and dry deposition, whereas semi-volatile phosphate esters have the potential to hydrolyze to diesters, monoesters, and phosphoric acid. 
There is no information available that suggests that selected phosphate ester flame retardants undergo transformation or degradation in the atmosphere.

Long-range transport
Tris(2-methylpropyl) phosphate is highly dependent on the specific compound.
Bioaccumulation and biomagnification
Phosphate esters are subject to biodegradation in aquatic and terrestrial environments.

Tris(2-methylpropyl) phosphate is found in the groundwater downgradient of a landfill. 
Tris(2-methylpropyl) phosphate is also a flame retardant and plasticizer.

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