PRODUCTS

VP/VA COPOLYMER

VP/VA Copolymer is used in hair styling formulations, acting as a hair fixative.
VP/VA Copolymer is used in hair care like aerosol sprays, non-aerosol products, liquid hair setting products, gels and mousses.
VP/VA Copolymer acts as a film-forming agent and hair fixative.

CAS Number: 25086-89-9
EC Number: 607-540-1
MDL Number: MFCD00134018
INCI Name: VP/VA Copolymer
Molecular Formula: (C₆H₉NO)x (C₄H₆O₂)y
Typical Molecular Weight: 45,000 – 70,000 g/mol (can vary depending on the manufacturer and polymerization process).

SYNONYMS:
Acetic Acid Ethenyl Ester, Polymer with 1-Ethenyl-2-Pyrrolidinone, GAF-S 630, E 535, Vinyl Acetate-Vinylpyrrolidone Polymer, Poly(1-Vinylpyrrolidone - Vinyl Acetate) (Copolymer, 7:3) (50% in Ethanol), Poly(1-Vinylpyrrolidone-co-Vinyl Acetate); Polectron 845; Luviskol VA 28I, A817635, Acetic Acid Ethenyl Ester; 1-Ethenyl-2-Pyrrolidinone, Poly(1-Vinylpyrrolidone-co-Vinylacetate)(Copolymer, 3:7)(50% in Ethanol), Poly(1-Vinylpyrrolidone-co-Vinyl Acetate) (Copolymer, 3:7) (50% in Ethanol), Copovidone, PVP/VA Copolymer, VP/VA Copolymer, Poly(1-vinylpyrrolidone-co-vinyl acetate), Polyvinylpyrrolidone-vinyl acetate copolymer, Vinylpyrrolidone/Vinyl Acetate Copolymer, Vinylacetate-N-vinylpyrrolidinone copolymer, acetic acid ethenyl ester, polymer with 1-ethenyl-2-pyrrolidinone, ethenyl acetate, 1-ethenylpyrrolidin-2-one, poly(1-vinyl pyrrolidone-co-vinyl acetate), Vinylpyrrolidone/vinyl acetate copolymer, PVP/VA copolymer, Copovidone, Polyvinylpyrrolidone-vinyl acetate copolymer

VP/VA Copolymer has good compatibility with many modifiers, plasticizers, spray propellants and other cosmetic ingredients.
VP/VA Copolymer is a film forming ingredient that works well in both skin/hair care products and cosmetics.
VP/VA Copolymer forms a film on the surface to trap and retain moisture for longer durations.

VP/VA Copolymer is found primarily in most hair care products, mascaras, nail polishes and also some skin care products.
The full form of VP/VA Copolymer is vinylpyrrolidone/vinyl acetate copolymer, which appears as a white powder in its raw form.

VP/VA Copolymer is a white, free-flowing powder.
In cosmetics and personal care products, vp/va copolymer is used primarily in the formulation of hair care products but can also be found in skin and nail products.

VP/VA Copolymer belongs to the following substance groups:
*Binders
*Film-forming agents
*Hair setting polymers

VP/VA Copolymer is a white powder, It offers strong & stiff hold, enhanced high humidity curl retention and good propellant compatibility.
VP/VA Copolymer is a film-forming agent used in the formulation of hair spray, gel, mousse, hair wax and shampoo.
VP/VA Copolymer is a white powder

VP/VA Copolymer can be dissolved in water.
VP/VA Copolymer is a large molecule consisting of N-vinylpyrrolidone (PV) and vinyl acetate (VA) monomers.
This film-forming agent, VP/VA Copolymer, is mainly used in hair care, it helps the hair to maintain their style by preventing them from absorbing moisture.

When it dries, VP/VA Copolymer forms a thin layer on the skin, hair or nails.
VP/VA Copolymer is forbidden in organic.
VP/VA Copolymer is a 60:40 linear, random copolymer of N-vinyl-2-pyrolidone (PVP) and vinyl acetate.

VP/VA Copolymer acts as a tablet binder in denture cleanser tablets.
VP/VA Copolymer is a big polymer (created from repeating subunits) molecule that works as a film former and hair fixative agent.

VP/VA Copolymer is a modified version of the first and classic hair fixative, PVP that alternates the water-loving VP (Vinyl Pyrrolidone) units with water-hating VA (Vinyl Acetate) units to create a film that is less brittle and less sensitive to air humidity.
VP/VA copolymer is a synthetic polymer, or large molecule, used in skin care and hair care preparations primarily as a film-forming agent.

This category of ingredients creates a coating over the area of application which helps reduce transepidermal water loss (TEWL) and creates a smooth feeling.
VP/VA Copolymer is an ingredient found in a lot of hair care products that provides the hold factor.

VP/VA Copolymer is a synthetic polymer composed of vinylpyrrolidone (VP) and vinyl acetate (VA) monomers in a 60:40 ratio.
VP/VA Copolymer is a powder form of this copolymer, widely utilized in industries for its versatility and effectiveness.
VP/VA copolymer is a synthetic polymer, or large molecule, used in skin care and hair care preparations primarily as a film-forming agent.

This category of ingredients creates a coating over the area of application which helps reduce transepidermal water loss (TEWL) and creates a smooth feeling.
VP/VA Copolymer is a copolymer of vinylpyrrolidone and vinyl acetate, i.e. a polymer composed of vinylpyrrolidone monomers and vinyl acetate monomers

VP/VA Copolymer is water-soluble (depending on grade), film-forming, and used widely as a binder, film former, and stabilizer in cosmetics, hair products, pharmaceuticals (tablet binder/coating), and industrial formulations.
Different VP:VA ratios and molecular weights give different properties (solubility, film strength, tack)

USES and APPLICATIONS of VP/VA COPOLYMER:
VP/VA Copolymer is used in hair styling formulations to help create a film hold on the hair and can be used in all types of hair styling products such as gels, mousses, creams, lotions and sprays.
Recommended usage rate of VP/VA Copolymer: Hair styling gel, cream, mousse, or lotion: 3-5%

VP/VA Copolymer emphasizes extra-hold styling, giving a hard texture, suitable for non-spray hair styling products.
VP/VA Copolymer balances firmness and naturalness.
VP/VA Copolymer is suitable for hair styling spray products.

VP/VA Copolymer possesses degreasing, good combing-out and washing-out properties.
Application/Recommended of VP/VA Copolymer for: Hair care (Shampoos, Conditioners & Styling), Decorative cosmetics/Make-up.
VP/VA copolymer is created through the combining of two smaller molecules, vinyl acetate and polyvinylpyrrolidone (PVP).

Hair care products commonly use VP/VA Copolymer to help fix hair into place, which is why it’s commonly incorporated into hair sprays.
Skin care and cosmetic products also use this ingredient, tapping into VP/VA copolymer’s ability to hinder TEWL and assist in the suspending and dispersing of ingredients (such as UV filters) in formulas.

In rinse off products, VP/VA Copolymer is used in percentages between 0.07-44%, whereas in leave on preparations, it’s utilized in percentages ranging from 0.001-10%.
The Cosmetic Ingredient Review (CIR) Expert Panel reviewed VP/VA copolymer and concluded that it’s safe for use in cosmetics at current usage percentages.

Use of VP/VA Copolymer: Filming agent, thickener, protective substance, antistatic effect, hair fixer.
VP/VA Copolymer is used for styling formulas.
To help create a film hold on hair, it can be used in all types of styling products such as gels, mousses, creams, lotions and sprays.

VP/VA Copolymer is commonly used in various applications, including cosmetics, pharmaceuticals, and adhesives, due to its excellent binding, film-forming, and stabilizing properties.
VP/VA copolymer is a large molecule consisting of N-vinylpyrrolidone (VP) and vinyl acetate (VA) monomers.

This film-forming agent, VP/VA Copolymer, is primarily used in hair care, helping hair retain its style by preventing moisture absorption.
When it dries, VP/VA Copolymer forms a thin layer on the skin, hair, or nails.
VP/VA Copolymer is prohibited in organic products.

VP/VA copolymer is created through the combining of two smaller molecules, vinyl acetate and polyvinylpyrrolidone (PVP).
Hair care products commonly use this multi-industry ingredient to help fix hair into place, which is why VP/VA Copolymer’s commonly incorporated into hair sprays.

Skin care and cosmetic products also use this ingredient, tapping into VP/VA copolymer’s ability to hinder TEWL and assist in the suspending and dispersing of ingredients (such as UV filters) in formulas.
In rinse off products, VP/VA Copolymer is used in percentages between 0.07-44%, whereas in leave on preparations, it’s utilized in percentages ranging from 0.001-10%.

The Cosmetic Ingredient Review (CIR) Expert Panel reviewed VP/VA copolymer and concluded that it’s safe for use in cosmetics at current usage percentages.
VP/VA Copolymer is used in hair care like aerosol sprays, non-aerosol products, liquid hair setting products, gels and mousses.

VP/VA Copolymer acts as a film-forming agent and hair fixative.
VP/VA Copolymer possesses degreasing, good combing-out and washing-out properties.
VP/VA Copolymer is a film former, most commonly found in hair care products.

VP/VA Copolymer is used in hairsprays, it helps to shape and hold hair in place.
Application/Recommended of VP/VA Copolymerfor: Hair care (Shampoos, Conditioners & Styling): Decorative cosmetics/Make-up
VP/VA Copolymer is a polymer is a polymer formed by the repeated bonding of multiple monomers to form a chain or network, and a polymer formed by the bonding of two or more types of monomers is called a copolymer.

VP/VA Copolymer is a synthetic copolymer made from the monomers vinylpyrrolidone (VP) and vinyl acetate (VA).
VP/VA Copolymer is available in powder form: Standard-hold balance between hardness and spontaneity.
VP/VA Copolymer is used Hairsprays, mousses, colouring products, mousses, gels, styling lotions and conditioners.

-Recommended Use Levels:
Aerosol hair spray: 2 – 6%
Pump spray: 3 – 7%
Setting lotions & mousse: 1 – 5%
Gels & hair waxes: 1 – 5%

COSMETIC USES of VP/VA COPOLYMER:
-When VP/VA Copolymer is added to cosmetics,
*Film formation
*Hairstyling
*join
VP/VA Copolymer is primarily used for these purposes in mascara, other makeup products, and hair styling products.

Below are the reasons for their intended use in cosmetics.
*Film formation
Regarding film formation, VP/VA Copolymer is used in mascara products and other cosmetic products for their film-forming properties, as they dry to a glossy, flexible, and adhesive film.

*Hairstyling
In hair styling, VP/VA Copolymer is primarily used in hair mousses, hair sprays, hair mists, and hair gels, as they dry to form a film with good adhesive properties that helps to set and maintain the shape of the hair.

*Joins
Regarding bonding, VP/VA Copolymer forms a highly adhesive film upon drying, which is why they are primarily used in powder makeup products to help the powders stick together when compressed into a dish, and to prevent the powder from scattering during use.

Number of products containing VP/VA Copolymer and range of amounts
The actual number of products containing VP/VA Copolymer and the amount of compounding are based on the results of overseas surveys conducted in 2002-2003 and 2017-2018, and are reported as follows

MAIN USES & FUNCTIONAL BENEFITS of VP/VA COPOLYMER:
*Cosmetics / Personal care:
film former and hair-fixative (hair sprays, gels, styling), improves hold, reduces flaking, enhances texture and adhesion of coatings.

*Pharmaceuticals:
VP/VA Copolymer is used binder and coating excipient (tablet binders, controlled release matrices, film coatings).
Copovidone grades are widely used in tablet formulations to improve compactibility and dissolution behaviour.

*Industrial / other:
VP/VA Copolymer is used adhesives, polishes, coatings, printing inks, spray films, and specialty applications where a water-compatible film former is needed.

PERFORMANCE CHARACTERISTICS / BENEFITS of VP/VA COPOLYMER:
Good film formation — clear, flexible films that provide hold and surface protection.
Adjustable properties of VP/VA Copolymer — by changing VP:VA ratio and molecular weight you control tack, stiffness, solubility and moisture uptake.
Less hygroscopic than PVP — the vinyl acetate comonomer decreases water uptake vs pure PVP, improving film stiffness and reducing stickiness.
Wide solvent compatibility of VP/VA Copolymer— available as powders or in alcohol/water solutions for easy formulation.

FUNCTION IN VP/VA COPOLYMER:
A rheology modifier affects the consistency of a cosmetic product by increasing its viscosity.
An emulsion stabilizer increases stability and extends the shelf life of an emulsion.
A binder ensures cohesion and binding of cosmetic product ingredients.
A film-forming agent and plasticizer for nail polish coatings.

COSMETIC EFFECT of VP/VA COPOLYMER:
VP/VA Copolymer is used in hair care products as a conditioning agent, it smooths and softens hair.
VP/VA Copolymer is also used in styling products, it sets hairstyles and conditions hair.
A film-forming agent, VP/VA Copolymer creates a film on the hair surface that limits water loss, thus providing moisturizing properties.
VP/VA Copolymer adds shine to hair.

SECURITY of VP/VA COPOLYMER:
Ingredient Safety:
VP/VA Copolymer is safe for use in cosmetic products.
Cosmetic Ingredient Review: CIR's 2018 report found VP/VA Copolymer to be a safe ingredient in cosmetic products.

FEATURES of VP/VA COPOLYMER:
*Excellent curl retention
*Stronghold
*Transparency
*Anti-static
*Binding
*Emulsion stabilizing
*Film-forming

FUNCTIONS (INCI) of VP/VA COPOLYMER:
*Fixing agent:
VP/VA Copolymer allows the cohesion of different cosmetic ingredients

-Film-forming agent:
VP/VA Copolymer produces a continuous film on the skin, hair or nails

-Hair Fixing Agent:
VP/VA Copolymer helps control hair style

VP/VA COPOLYMER IS PRESENT IN:
VP/VA Copolymer is present in 0.76% of cosmetics.
*Styling mousse (37.54%)
*Men's gel and hairspray (30.91%)
*Styling gel (27.12%)
*Patches (19.33%)
*Styling spray (19.1%)

FUNCTION IN COSMETICS of VP/VA COPOLYMER:
A rheological modifier – VP/VA Copolymer affects the consistency of a cosmetic product by increasing its viscosity.
VP/VA Copolymer is also used in skincare products (creams, balms) as a stabilizer for emulsions (e.g., creams) and suspensions (e.g., scrubs), among other things, preventing separation and extending the shelf life of cosmetics.
VP/VA Copolymer is a binder is a substance that binds ingredients in solid cosmetics.
VP/VA Copolymer is a film-forming agent and plasticizer for nail polish coatings.

VP/VA COPOLYMER AT A GLANCE:
A polymer, or large molecule, used in skin and hair care
Film-forming agent that can hinder moisture loss
Often used in hair care to keep hair in place
CIR Expert Panel deemed safe for use

COSMETIC BENEFITS of VP/VA COPOLYMER:
*Hair styling:
VP/VA Copolymer provides hold and structure to hairstyles.

*Film-forming:
VP/VA Copolymer creates a smooth, even film on skin or hair.

*Moisture retention:
VP/VA Copolymer helps retain moisture in skin and hair.

*Binding properties:
Effective in binding pigments and ingredients.

*Stability enhancement:
VP/VA Copolymer enhances stability and shelf life of cosmetic products.

*Texture improvement:
VP/VA Copolymer improves texture and feel of products.

QUICK FORMULATION TIPS of VP/VA COPOLYMER:
VP/VA Copolymer is used for hair sprays/hairstyling, choose grades with higher VA content for stronger films and reduced hygroscopicity.
For tablet binding / coatings, VP/VA Copolymer is used pharmacopeial/copovidone grades (EP/USP) and follow supplier solubility/viscosity instructions for the binder solution.

VP/VA Copolymeris a film-forming agent that offers a strong, stiff hold in hair care.
VP/VA Copolymer offers curl retention in high humidity.
VP/VA Copolymer forms transparent, flexible, and breathable films

THE SCIENCE of VP/VA COPOLYMER:
VP/VA Copolymer is a big polymer (created from repeating subunits) molecule that works as a film former and hair fixative agent.
VP/VA Copolymer is a modified version of the first and classic hair fixative, PVP, that alternates the water-loving VP (Vinyl Pyrrolidone) units with water-hating VA (Vinyl Acetate) units to create a film that is less brittle and less sensitive to air humidity.

*Benefits for your hair
Promotes styling ability
VP/VA copolymer helps hair hold its style by inhibiting the hair's ability to absorb moisture.
VP/VA copolymer dries to form a thin coating, which prevents moisture entering.

*TLDR
VP/VA copolymer is a great ingredient for helping hair to hold its style by forming a thin layer which prevents moisture from being absorbed.

*Gives Formulas a Smooth And Luxurious Feel
VP/VA copolymer is a viscosity builder, which is a fancy word for making cosmetic formulas feel nice.
We want you to have a self-care moment when applying our products, so the application experience is top of mind when working with our cosmetic chemists to create new products.
Hence, we use VP/VA copolymer to elevate our formulas and ensure a luxurious experience for the ultimate self-care indulgence.

*self care logoImproved Alternative To PVP
Before VP/VA copolymer, PVP was often used in setting sprays to help hold makeup in place.
However, if you ever noticed your skin feeling dry or cracked after using a setting spray, it may be because PVP can be a bit drying.
Luckily, cosmetic chemists discovered that VP/VA copolymer provides all of the same makeup holding capabilities, but is less brittle and less sensitive to air humidity, so your skin stays soft and supple.

FUNCTION(S) of VP/VA COPOLYMER IN COSMETIC PRODUCTS
*BINDING
VP/VA Copolymer ensures the cohesion of powder and powder-containing products

*FILM-FORMING
VP/VA Copolymer forms a film on skin, hair or nails

*HAIR FIXING
VP/VA Copolymer allows for durable shaping and styling of hairstyles

WHAT IS VP/VA COPOLYMER USED FOR?
VP/VA Copolymer has a number of benefits to offer in the world of cosmetics and personal care.
VP/VA Copolymer can mainly be found in hair care products, followed by cosmetics and a few skin care products.

*Skin care:
VP/VA Copolymer is responsible for forming a thin layer on the skin that feels smooth to the touch and makes the surface look flawless.
VP/VA Copolymer also retains moisture on the skin and doesn't allow it to run dry for longer durations of time.

*Hair care:
VP/VA Copolymer is mainly used in hair care products for hair setting.
VP/VA Copolymer does not allow the shafts to absorb any further moisture and thus lose any styling done on them.
VP/VA Copolymer also forms a thin coat on hair that helps them retain its shape.

*Decorative cosmetics:
VP/VA Copolymer is also added to cosmetic products like nail polish and mascara because it dries up to form a film that inhibits the surface from absorbing any moisture and thus keeps it styled impeccably.

ORIGIN of VP/VA COPOLYMER:
VP/VA Copolymer is made by the monomers of vinylpyrrolidone and vinyl acetate.
VP/VA Copolymer appears as a white free-flowing powder and is the result of very small chemical compounds combining to form a large molecule.

WHAT DOES VP/VA COPOLYMER DO IN A FORMULATION?
*FILM FORMING
*HAIR FIXING
*MOISTURISING

VP/VA Copolymer has been termed safe for use under the prescribed concentrations - any higher than that can cause side effects like irritation to the skin and scalp.
A patch test should be done before full usage.
Further, VP/VA Copolymer is vegan.

ALTERNATIVES of VP/VA COPOLYMER:
ACRYLATES/DIMETHICONE COPOLYMER
VP/VA Copolymer is a synthetic vinyl polymer composed of vinyl acetate and vinylpyrrolidone.

WHY IS VP/VA COPOLYMER USED?
VP/VA copolymer helps hair hold its style by inhibiting the hair’s ability to absorb moisture.
VP/VA copolymer dries to form a thin coating on the skin, hair or nails.
VP/VA Copolymer is also used to hold together the ingredients of a compressed tablet or cake and helps to distribute or to suspend an insoluble solid in a liquid.

PHYSICAL and CHEMICAL PROPERTIES of VP/VA COPOLYMER:
Boiling Point: 217°C
Solubility: Soluble in water
CAS NUM: 25086-89-9
INCI Name:VP/VA Copolymer
Percentage Purity : 98%
Color & Appearance: white to slightly yellowish, fine to coarse grained powder
Appearance: white to yellowish-white powder or solutions (many commercial grades sold as solutions in alcohols/isopropanol).
Representative repeat-unit formula / monomer stoichiometry: repeat-unit formula often shown as C₁₀H₁₅NO₃ for the combined repeat units (this reflects the chemical fragments, while the actual polymer is a high-MW mixture). Note: polymer MW is variable by grade — suppliers list average Mw (e.g., ~13,000–50,000 g·mol⁻¹ depending on grade).

Molecular weight: highly grade-dependent (suppliers publish average Mw for each grade).
Glass transition (Tg): supplier data report Tg values in the polymer range (example listings show Tg around ~108 °C for certain compositions/grades — treat as approximate, grade dependent).
Density: supplier/customer data give values in the ~1.2–1.3 g·mL⁻¹ range for some solutions/solid references (this varies with formulation and water/alcohol content).
Solubility: soluble or dispersible in water and many polar organic solvents (ethanol, isopropanol); solubility and solution viscosity depend on grade and concentration.
Film-forming / mechanical: produces strong, clear films; films are less hygroscopic than pure PVP (because of the VA units) and typically give better stiffness/hold in hair products.
Short technical note: because it’s a polymer, many “properties” (exact MW, viscosity, Tg, solubility, residual monomer content) are supplied per product/grade by the manufacturer

CAS Number: 25086-89-9
EC Number: 200-001-8
Assigned by the European Chemicals Agency (ECHA) for the polymer.
Molecular Formula: (C₆H₉NO)n·(C₄H₆O₂)m
This reflects the repeating units of vinylpyrrolidone (VP) and vinyl acetate (VA) in the copolymer chain.
Molecular Weight: Varies depending on the polymerization degree and monomer ratio. For a 7:3 VP/VA ratio, the molecular weight is approximately 181.24 g/mol
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity: 0.95800 @ 25.00 °C.

Boiling Point: 217.60 °C. @ 760.00 mm Hg (est)
Vapor Pressure: 0.132000 mmHg @ 25.00 °C. (est)
Flash Point: 72.00 °F. TCC ( 22.22 °C. )
logP (o/w): 0.370 (est)
INCI Name: VP/VA Copolymer
CAS Number: 25086-89-9
Appearance: Clear, colorless to pale yellow liquid
Solubility: Soluble in water and ethanol
pH: Typically ranges from 4 to 7
Viscosity: Dependent on concentration and molecular weight
Film Properties: Forms transparent, hard, glossy, and water-removable films

FIRST AID MEASURES of VP/VA COPOLYMER:
-Description of first-aid measures
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with
water/ shower.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed.
No data available

ACCIDENTAL RELEASE MEASURES of VP/VA COPOLYMER:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up dry.
Dispose of properly.
Clean up affected area.

FIRE FIGHTING MEASURES of VP/VA COPOLYMER:
-Extinguishing media:
*Suitable extinguishing media:
Carbon dioxide (CO2)
Foam
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.

EXPOSURE CONTROLS/PERSONAL PROTECTION of VP/VA COPOLYMER:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Safety glasses
*Body Protection:
protective clothing
*Respiratory protection:
Recommended Filter type: Filter A
-Control of environmental exposure:
Do not let product enter drains.

HANDLING and STORAGE of VP/VA COPOLYMER:
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Dry.

STABILITY and REACTIVITY of VP/VA COPOLYMER:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .
-Possibility of hazardous reactions:
No data available