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ZIRCONIUM OCTOATE

Zirconium octoate is used drier for alkyd coating.
Zirconium Octoate is widely used in various industries due to its unique properties and applications.
Zirconium octoate is used in paint media with Cobalt and other auxiliary driers to boost the performance of paints and varnishes.

CAS Number: 22464-99-9
EC Number: 245-018-1
Molecular Weight: 668.1 g/mol
Molecular Formula: C32H64O8Zr

SYNONYMS:
Zirconium octoate, Zirconium(IV) oxide 2-ethylhexanoatein, 2-ethylhexanoate,zirconium(2+), Zirconium octoate, Zirconium tetra(2-ethylhexanoate), Zirconium bis(2-ethylhexanoate), Zirconyl 2-ethylhexanoate, 2-Ethylhexanoic acid zirconium salt, Hexanoic acid, 2-ethyl-, zirconium salt, ZR-12, Zirconium(IV) 2-ethylhexanoate

Zirconium Octoate is a very efficient auxiliary drier.
Zirconium Octoate is the best replacement of Lead octoate when used in combination with Cerium or Calcium octoate in the lead free paint systems.

Zirconium Octoate is an organometallic compound that contains zirconium and octoate ligands.
Zirconium octoate is a clear, yellowish liquid with excellent solubility in various organic solvents.
Zirconium is a powerful through drier and is the most widely used.

Zirconium Octoate is a very efficient auxiliary drier.
Zirconium Octoate is the best replacement of Lead octoate when used in combination with Calcium or Cerium octoate in the lead-free paint systems.

Zirconium Octoate shows goods gloss retention and colour retention compared to Lead, but does not perform as well under adverse drying conditions of low temperature and high humidity.
Zirconium Octoate is the most useful drier for water resistant finishes due to its stabilizing effect on the ester linkages in the media.

Zirconium octoate is available in different types with 6%, 12%, 18%, and 24% metal ratios.
Zirconium octoate has a metal content of 18% (± 0.2) and a specific gravity of 1.1 at 300°C (± 3).
Lead octoate is not recommended in the white paint when Zirconium Octoate is used as an auxiliary drier.

Zirconium Octoate is a trace yellow liquid that is a very efficient auxiliary drier.
Zirconium is one of the most effective and efficient auxiliary driers.
Zirconium octoate is suitable for the use of 75% of lead drier.

Zirconium octoate is soluble in organic solvents and oils.
Zirconium Octoate, also known as Zirconium 2-ethylhexanoate, is a zirconium-based organometallic compound widely utilized in industrial applications, particularly as a catalyst in coatings and polymer production.

Zirconium Octoate is A Remarkable Catalyst for Diverse Reactions
In the realm of chemical catalysts, one compound that stands out for its versatility and efficacy is Zirconium Octoate.
This organometallic compound, consisting of zirconium linked to eight octoate ligands, has found widespread applications across various industries, making it a crucial player in the world of chemistry.

USES and APPLICATIONS of ZIRCONIUM OCTOATE:
Zirconium octoate is a metal complex used as a drier or catalyst in the preparation of alkyd paint.
Zirconium octoate boosts the drying and curing of paint films through increasing the rates of oxidation and polymerization of drying oils.
Catalysts: Zirconium Octoate is commonly used as a catalyst in polymerization reactions, specifically for the production of polyolefins and other synthetic polymers.

Coatings: Zirconium octoate is employed as a drying agent and cross-linking agent in the production of coatings, paints, and varnishes.
Zirconium Octoate enhances film formation and provides improved adhesion and durability.
Adhesives and Sealants: Zirconium octoate acts as a catalyst and cross-linking agent in the manufacturing of adhesives and sealants, enabling superior bonding strength and resistance to heat and chemicals.

Textiles: Zirconium Octoate is utilized in textile applications, such as dyeing and finishing processes, to improve color fastness, water repellency, and wrinkle resistance.
Fuel and Lubricant Additives: Zirconium octoate is employed as an additive in fuels and lubricants to enhance their performance, including anti-wear properties, oxidation resistance, and corrosion protection.

Zirconium octoate acts as a drier.
Zirconium octoate is a clean liquid without suspended matter.
Zirconium octoate improves brightness, elasticity, color retention and takes longer time to dry under high humidity or low temperature conditions as compared to lead.

In comparison to linoleate, phthalates and naphthenates, Zirconium octoate provides better color, odor, stability and viscosity.
Zirconium octoate shows lower price level in comparison to synthetic acids and metallic salts like those prepared with iso-acids as well as neo-acids.

Zirconium octoate enables high metal concentration with superior quality and reproducibility.
Zirconium octoate prevents lead-related inconveniences such as haze in varnishes, leafing losses on aluminum paints and sulfide stains on paints used in industrial environments.

Zirconium octoate is suitable for children's articles paints.
Recommended dosage of Zirconium octoate is 0.20-0.80 w/w% zirconium metal on resin NV.
Zirconium octoate which functions as a deep and highly effective auxiliary drier, is the most recognized alternative to lead-based driers.

When used in combination with cobalt driers in white paints, Zirconium octoate ensures the preservation of the film's color and prevents yellowing.
This combination also safeguards the film from weathering effects.

Unlike lead-based driers, zirconium octoate does not generate sulfides in sulfur-polluted atmospheres, eliminating the formation of black spots on the film.
In comparison to lead-based driers, films dried with zirconium octoate exhibit greater flexibility, shorter drying times, and lower hardness.

However, in lower temperatures and humid conditions, this trend may be reversed.
Industrial Applications of Zirconium octoate: Beyond organic synthesis, Zirconium Octoate finds applications in several industrial processes, contributing to advancements in materials science and manufacturing.

Zirconium octoate is effective auxiliary drier used in paint media along with cobalt and other auxiliary driers to boost up the performance of paints and varnishes.
Zirconium octoate is used most useful drier for water resistant finishes.

Zirconium octoate is used as a strong cross-linking agent.
Zirconium octoate is used as a secondary drier in conjunction with primary driers to ensure a balanced drying process of both the surface and body of the film.

Zirconium octoate is use in paint media with Cobalt and other auxiliary driers to boost up the performance of paints and varnishes.
Zirconium Octoate is the most useful drier for water resistant finishes due to its stabilizing effect on the ester linkages in the media.
Zirconium Octoate is primarily used as a drier in the coatings industry.

Paints and Varnishes: Zirconium octoate acts as a catalyst to accelerate the drying of alkyd-based coatings.
Inks: Zirconium octoate enhances drying times in printing inks.
Polymer Production: Zirconium octoate serves as a catalyst in polymerization processes.

Adhesives and Sealants: Zirconium octoate improves curing times and performance.
As a strong cross-linking agent, Zirconium improves the hardness and gives better adhesion.
Because of its abrasion resistant characteristics Zirconium octoate is used in wire enamels.

In alkyd amino combinations, Zirconium Octoate has been proved to be the best auxiliary drier, which resists absorption and improves the performance of other driers used in combination with it.
Zirconium octoate has a good effect in epoxy esters too.

But in the phenolic resin media, Zirconium has not shown any significant effect.
Zirconium octoate is used in paint media with Cobalt and other auxiliary driers to boost up the performance of paints and varnishes.

Zirconium Octoate is widely used in white paints in combination with Cobalt and Cerium octoate as it reduces the yellowing tendency of the white film and retains the whiteness by protecting the film from any weather effects.
Zirconium octoate can be utilized in paint media with Cobalt to help increase the performance of paints and varnishes.

Zirconium octoate can be used in white paints to reduce yellowing tendency of the white film and it helps to retain whiteness by protecting the film from weather effects.
Zirconium octoate is especially useful in water resistant finishes because it has a stabilizing effect on the ester linkages in the media.

Zirconium octoate is used as a base and intermediate layer drier in alkyd-based air-drying industrial paints and varnishes.
Zirconium octoate acts as a drier like lead and is usually used with cobalt, manganese, and calcium.
Unlike lead, zirconium is a weak pigment wetting and dispersing agent, but it is an active crosslinker; thus, it increases the hardness and adhesion of the hardened films.

When used with cobalt, Zirconium octoate can replace lead and is preferred to eliminate the ecological disadvantages of lead driers.
Zirconium Octoate is usually used with cobalt driers to form a hard film and can be used instead of lead driers.

Zirconium Octoate shows goods gloss retention, colour, and colour retention compared to Lead, but does not perform as well under adverse drying conditions of low temperature and high humidity.
Zirconium Octoate is the most useful drier for water resistant finishes due to its stabilizing effect on the ester linkages in the media.

-Adhesive Formulations uses of Zirconium octoate:
Zirconium Octoate is utilized in the formulation of adhesives and sealants.
Zirconium octoate's catalytic properties aid in the cross-linking of polymers, enhancing the strength and durability of adhesives in various applications.

-Coating and Surface Modification uses of Zirconium octoate:
Zirconium octoate is employed in the production of coatings for metals and other substrates.
Zirconium octoate's ability to catalyze cross-linking reactions enhances the adhesion and performance of coatings, providing protection against corrosion and wear.

APPLICATIONS OF ZIRCONIUM OCTOATE IN ORGANIC SYNTHESIS:
One of the primary applications of Zirconium Octoate is in organic synthesis reactions.
Its catalytic properties make Zirconium octoate a valuable tool for chemists engaged in the creation of complex organic molecules.
Some notable applications include:

*Polymerization Reactions
Zirconium Octoate is widely used as a catalyst in the polymerization of various monomers.
Zirconium octoate facilitates the formation of polymers with controlled molecular weights and structures, contributing to the development of advanced materials.

*Olefin Metathesis
In olefin metathesis reactions, Zirconium Octoate plays a key role in breaking and forming carbon-carbon double bonds.
This process is essential in the synthesis of pharmaceuticals, plastics, and other industrially relevant compounds.

*Hydroamination
The catalytic activity of Zirconium Octoate extends to hydroamination reactions, where it promotes the addition of an amino group to an unsaturated carbon-carbon bond.
This is a crucial step in the synthesis of various nitrogen-containing organic compounds.

✅ BENEFITS AND CHARACTERISTICS OF ZIRCONIUM OCTOATE:
Efficient Catalyst:
Zirconium octoate enhances drying and curing times in various applications.

Thermal Stability:
Zirconium octoate maintains performance under elevated temperatures.

Compatibility:
Zirconium octoate works well with a range of solvents and resins.

Improved Film Properties:
Zirconium octoate contributes to hardness and durability in coatings.

FEATURES OF ZIRCONIUM OCTOATE:
Zirconium octoate is a coordinated drying agent that can form high molecular weight functional complexes with hydroxyl groups or other polar genes in the resin.
Combining with cobalt can effectively improve the drying ability of cobalt.

The promoting dryness of Zirconium octoate is not as fast as that of lead, but the toughness and hardness performance of the system after actual drying are significantly better than that of the lead drying system.

The combination of zirconium drying agent and cobalt in white alkyd self drying system has good color retention performance and the paint film is not prone to yellowing.
Zirconium octoate is mainly used as a drying agent for paint systems with less impact on color.

CHEMICAL STRUCTURE AND PROPERTIES OF ZIRCONIUM OCTOATE:
Zirconium Octoate is a coordination complex, featuring a central zirconium atom surrounded by eight octoate ligands.
Zirconium octoate ligand typically refers to the octanoate ion, which is a carboxylate group derived from octanoic acid.
This structure imparts unique characteristics to Zirconium Octoate, making it a valuable catalyst in various chemical processes.

*Stability:
Zirconium Octoate is known for its stability, allowing it to endure harsh chemical environments and high temperatures.
This stability is a result of the strong coordination bonds formed between the zirconium atom and the octoate ligands.

*Solubility:
Zirconium Octoate exhibits good solubility in organic solvents, enhancing its applicability in organic synthesis reactions.
This solubility profile contributes to Zirconium octoate's ease of use in various catalytic processes.

KEY FEATURES OF ZIRCONIUM OCTOATE:
*Excellent solubility in organic solvents
*High catalytic activity in polymerization reactions
*Zirconium octoate enhances film formation and adhesion in coatings
*Zirconium octoate provides cross-linking and bonding strength in adhesives
*Zirconium octoate improves color fastness and water repellency in textiles
*Zirconium octoate enhances performance and protection in fuel and lubricants

PHYSICAL and CHEMICAL PROPERTIES of ZIRCONIUM OCTOATE:
Chemical Name: Zirconium 2-ethylhexanoate,
CAS Number: 22464-99-9,
EC Number: 245-018-1,
Molecular Formula: C₃₂H₆₀O₈Zr,
Molecular Weight: Approximately 664.04 g/mol,
PubChem CID: 6451377,
Appearance: Amber-colored viscous liquid,
Density: Approximately 1.27 g/cm³,
Boiling Point: 167–178 °C at 760 mmHg,
Flash Point: 65 °C,
Refractive Index: n²⁰/D 1.446,
Solubility: Insoluble in water; soluble in organic solvents such as mineral spirits,

Vapor Pressure: 0.54 mm Hg,
Autoignition Temperature: 200 °C,
Chemical Formula: C₁₆H₃₆O₈Zr,
Molecular Weight: 455.84 g/mol,
Appearance: Clear yellowish liquid,
Density: 1.135 g/cm³,
Boiling Point: 275–300 °C,
Flash Point: 137 °C,
Solubility: Soluble in organic solvents,
Purity: ≥99%,
Storage: Store in a cool, dry place away from direct sunlight.

FIRST AID MEASURES of ZIRCONIUM OCTOATE:
-Description of first-aid measures
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with
water/ shower.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed.
No data available

ACCIDENTAL RELEASE MEASURES of ZIRCONIUM OCTOATE:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up dry.
Dispose of properly.
Clean up affected area.

FIRE FIGHTING MEASURES of ZIRCONIUM OCTOATE:
-Extinguishing media:
*Suitable extinguishing media:
Carbon dioxide (CO2)
Foam
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.

EXPOSURE CONTROLS/PERSONAL PROTECTION of ZIRCONIUM OCTOATE:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Safety glasses
*Body Protection:
protective clothing
*Respiratory protection:
Recommended Filter type: Filter A
-Control of environmental exposure:
Do not let product enter drains.

HANDLING and STORAGE of ZIRCONIUM OCTOATE:
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Dry.

STABILITY and REACTIVITY of ZIRCONIUM OCTOATE:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature).
-Possibility of hazardous reactions:
No data available