Dibasic ester(DBE)/High boiling point solvent; Hexanedioic acid, dimethyl ester, mixt. with dimethyl butanedioate and dimethyl pentanedioate; dimethyl butanedioate; dimethyl hexanedioate; dimethyl pentanedioate; DBE dibasic ester; Estasol, dimethyl butanedioate; Dibasic dimethyl esters of adipic acid, succinic acid glutaric acid; Dibasic ester; DBE dibasic ester; 95481-62-2; Estasol; RDPE; SCHEMBL4450294; Dibasic dimethyl esters of adipic acid, succinic acid & glutaric acid; DBA Dibasic acid (mixture of glutaric acid, succinic acid and adipic acid); Hexanedioic acid, dimethyl ester, mixt. with dimethyl butanedioate and dimethyl pentanedioate; Pentanedioic acid, dimethyl ester, mixt. with dimethyl butanedioate and dimethyl hexanedioate; 481D622; dimethyl adipate dimethyl glutarate dimethyl succinate; dimethyl butanedioate,dimethyl hexanedioate,dimethyl pentanedioate; dimethyl adipate compound with dimethyl glutarate and dimethyl succinate (1:1:1); Hexanedioic acid, dimethyl ester, mixt. with dimethyl butandedioate and dimethyl pentanedioate; Dimethyl hexanedioate; dbe-6 dibasic ester; C8H14O4; dimethyl adipate; DBE; Ester mixture (methyl esters) of diacids C4, C5 und C6; 2-Diazo-1-naphthol-4-sulfonate; 2-Diazo-1-naphthol-4-sulfonic acid; 1-Diazo-2-naphthol-4-sulfonic acid; 2-Diazo-1-naphthol-4-sulfonyl chloride; 2-Diazo-1-naphthol-5-sulfonyl chloride; (-)-[(1S)-3-Diazo-2-oxo-1-(phenylmethyl)propyl]carbamic acid 1,1-dimethylethyl ester; N-[(1S)-3-Diazo-2-oxo-1-(phenylmethyl)propyl]carbamic acid 9H-fluoren-9-ylmethyl ester; (3-Diazo-2-oxopropyl)carbamic acid 9H-fluoren-9-ylmethyl ester; Diazoxide; Dibanzyloxy phosphatecreatinine; Dibasic lead; metaphosphate; Dibasic Lead Phosphite; Dibasic lead stearate; Dibekacin; Dibekacin sulfate; Dibenz[b,f]azepine-5-carbonyl chloride; 5H-Dibenz[b,f]azepine-10,11-dione; 5H-Dibenz[b,e]azepine-6,11-dione; Dibenzenesulfonimide; Dibenzhydryl disulfide; DIMETHYL SUCCINATE; 106-65-0; Dimethyl butanedioate; Dimethylsuccinate; Methyl succinate; Butanedioic acid, dimethyl ester; Succinic acid, dimethyl ester; DBE-4 dibasic ester
DIBASIC ESTER
CAS NO: 95481-62-2
EC NO: 619-131-5
SYNONYMS:
Dibasic ester(DBE)/High boiling point solvent; Hexanedioic acid, dimethyl ester, mixt. with dimethyl butanedioate and dimethyl pentanedioate; dimethyl butanedioate; dimethyl hexanedioate; dimethyl pentanedioate; DBE dibasic ester; Estasol, dimethyl butanedioate; Dibasic dimethyl esters of adipic acid, succinic acid glutaric acid; Dibasic ester; DBE dibasic ester; 95481-62-2; Estasol; RDPE; SCHEMBL4450294; Dibasic dimethyl esters of adipic acid, succinic acid & glutaric acid; DBA Dibasic acid (mixture of glutaric acid, succinic acid and adipic acid); Hexanedioic acid, dimethyl ester, mixt. with dimethyl butanedioate and dimethyl pentanedioate; Pentanedioic acid, dimethyl ester, mixt. with dimethyl butanedioate and dimethyl hexanedioate; 481D622; dimethyl adipate dimethyl glutarate dimethyl succinate; dimethyl butanedioate,dimethyl hexanedioate,dimethyl pentanedioate; dimethyl adipate compound with dimethyl glutarate and dimethyl succinate (1:1:1); Hexanedioic acid, dimethyl ester, mixt. with dimethyl butandedioate and dimethyl pentanedioate; Dimethyl hexanedioate; dbe-6 dibasic ester; C8H14O4; dimethyl adipate; DBE; Ester mixture (methyl esters) of diacids C4, C5 und C6; 2-Diazo-1-naphthol-4-sulfonate; 2-Diazo-1-naphthol-4-sulfonic acid; 1-Diazo-2-naphthol-4-sulfonic acid; 2-Diazo-1-naphthol-4-sulfonyl chloride; 2-Diazo-1-naphthol-5-sulfonyl chloride; (-)-[(1S)-3-Diazo-2-oxo-1-(phenylmethyl)propyl]carbamic acid 1,1-dimethylethyl ester; N-[(1S)-3-Diazo-2-oxo-1-(phenylmethyl)propyl]carbamic acid 9H-fluoren-9-ylmethyl ester; (3-Diazo-2-oxopropyl)carbamic acid 9H-fluoren-9-ylmethyl ester; Diazoxide; Dibanzyloxy phosphatecreatinine; Dibasic lead; metaphosphate; Dibasic Lead Phosphite; Dibasic lead stearate; Dibekacin; Dibekacin sulfate; Dibenz[b,f]azepine-5-carbonyl chloride; 5H-Dibenz[b,f]azepine-10,11-dione; 5H-Dibenz[b,e]azepine-6,11-dione; Dibenzenesulfonimide; Dibenzhydryl disulfide; DIMETHYL SUCCINATE; 106-65-0; Dimethyl butanedioate; Dimethylsuccinate; Methyl succinate; Butanedioic acid, dimethyl ester; Succinic acid, dimethyl ester; DBE-4 dibasic ester; Succinic acid dimethyl ester; Methyl butanedioate; butanedioic acid dimethyl ester; FEMA No. 2396; CCRIS 4803; UNII-914I2127JR; HSDB 5370; EINECS 203-419-9; NSC 52209; Butanedioic acid, 1,4-dimethyl ester; DBE-4; AI3-02480; Dimethyl ester of succinic acid; CH3OC(O)CH2CH2C(O)OCH3; 914I2127JR; Dimethyl succinate, 99%; DSSTox_CID_5152; dimethyl butane-1,4-dioate; DSSTox_RID_77690; DSSTox_GSID_25152; CAS-106-65-0; Dibasic Esters; Dimethyl succinate.; Succinic acid dimethyl; Dimethylsuccinate (DMS); 1,4-dimethyl butanedioate; dimethyl 1,4-butanedioate; ACMC-2098lo; EC 203-419-9; Succinic acid-dimethyl ester; SCHEMBL10213; KSC179S9D; MLS002454400; DBE-4 dibasic ester, 98%; Dimethyl Succinate (Fragrance); CHEMBL556489; Dimethyl succinate, 98%, FG; Dimethyl succinate 106-65-0; DTXSID5025152; CTK0H9991; FEMA 2396; HMS2270G19; ACN-S002409; NSC52209; ZINC1683870; Tox21_202189; Tox21_300350; ANW-15418; LS-406; MFCD00008466; NSC-52209; SBB040934; STL481902; AKOS000269071; Dimethyl succinate, analytical standard; MCULE-1133524094; KS-000000A7; NCGC00091530-01; NCGC00091530-02; NCGC00091530-03; NCGC00254517-01; NCGC00259738-01; SMR001253742; DB-059497; CS-0015787; Dimethyl succinate, purum, >=98.0% (GC); FT-0621972; NS00007584; S0104; ST50214542; Dimethyl succinate, Vetec(TM) reagent grade, 98%; J-001620; Q27271375; F1905-7126; DIMETHYL GLUTARATE; 1119-40-0; Glutaric acid dimethyl ester; Dimethyl pentanedioate; Pentanedioic acid, dimethyl ester; Glutaric acid, dimethyl ester; Methyl glutarate; Pentanedioic acid, 1,5-dimethyl ester; DBE 5; pentanedioic acid dimethyl ester; HSDB 5789; UNII-1I9VFA346P; DBE-5 dibasic ester; EINECS 214-277-2; NSC 58578; AI3-06026; 1I9VFA346P; Glutaric acid, dimethyl ester (8CI); Dimethyl glutarate, 98%; DSSTox_CID_5122; DSSTox_RID_77674; dimethyl pentane-1,5-dioate; DSSTox_GSID_25122; CAS-1119-40-0; MFCD00008468; dbe-5; Glutaric acid dimethyl; Di - methyl glutarate; ACMC-1BTOV; dbe-5dibasicester(dimethyl); 1,5-dimethyl pentanedioate; EC 214-277-2; pentanedioicaciddimethylester; Glutaric acid-dimethyl ester; Pentanedioicacid,dimethylester; SCHEMBL50039; KSC176C8T; MLS002415727; DBE-5 dibasic ester, 99%; Dimethyl Glutarate (Fragrance); CHEMBL1609626; DTXSID3025122; CTK0H6189; Dimethyl glutarate 1119-40-0; HMS2267B23; ACN-S002414; dbe-5dibasicester(dimethylglutarate); KS-00000G2D; NSC58578; ZINC1689142; Tox21_201235; Tox21_300115; AC-357; ANW-16345; BBL011506; LS-547; NSC-58578; SBB058680; STL146619; AKOS005721178; DS-3336; MCULE-2878617545; NE10587; NCGC00091256-01; NCGC00091256-02; NCGC00091256-03; NCGC00253964-01; NCGC00258787-01; AK688453; M320; SC-79189; SMR001253878; DB-060134; CS-0130885; FT-0625080; G0185; NS00002707; ST50824773; EN300-93587; Q-200994; Q11074436; Dimethyl adipate; 627-93-0; Dimethyl hexanedioate; Dimethyladipate; Adipic acid dimethyl ester; HEXANEDIOIC ACID, DIMETHYL ESTER; Adipic acid, dimethyl ester; 1,6-Dimethylhexanedioate; hexanedioic acid dimethyl ester; Methyl adipate (VAN); 1,6-dimethyl hexanedioate; DBE 6; UNII-BY71RX0R62; HSDB 5021; EINECS 211-020-6; NSC 11213; BRN 1707443; AI3-00668; BY71RX0R62; CHEBI:34715; Hexanedioic acid, 1,6-dimethyl ester; Dimethyl adipate, 99+%; DSSTox_CID_5096; dimethyl hexane-1,6-dioate; DSSTox_RID_77664; DSSTox_GSID_25096; CAS-627-93-0; Adipic acid dimethyl; MFCD00008469; ACMC-1AUNC; Dimethyl adipate, 98%; Adipic acid-dimethyl ester; Dimethyl adipate; >99%; Dimethyl 1,6-hexanedioate; EC 211-020-6; adipinic acid dimethyl ester; Dimethyl adipate, >=99%; SCHEMBL14975; Dimethyl Adipate (Fragrance); 4-02-00-01959 (Beilstein Handbook Reference); KSC353K0D; MLS001065612; BIDD:ER0590; Dimethyl adipate 627-93-0; CHEMBL1566491; DTXSID8025096; CTK2F3501; KS-0000VGO; Dimethyl Adipate (Solvent Grade); Dimethyl ester of hexanedioic acid; HMS3039K04; ACN-S002408; NSC11213; ZINC1712794; Tox21_201912; Tox21_300363; ANW-34380; BBL011467; NSC-11213; SBB041006; STL146579; AKOS000120030; LS-1509; MCULE-2088809384; NCGC00091471-01; NCGC00091471-02; NCGC00091471-03; NCGC00091471-04; NCGC00164433-01; NCGC00254458-01; NCGC00259461-01; AK307514; SC-22453; SMR000568478; A0166; FT-0621919; NS00004584; ST50214655; C14570; J-660024; Q21994864; F0001-1687; Z955123674; HEXANEDIOIC ACID, DIMETHYL ESTER; ADIPIC ACID, DIMETHYL ESTER
DIBASIC ESTER
Dibasic ester or DBE is an ester of a dicarboxylic acid. Depending on the application, the alcohol may be methanol or higher molecular weight monoalcohols.
Dibasic Ester (DBE) and its fractions serve as raw materials for plasticizers, polymers.
Dibasic ester (DBE) and its fractions serve as raw materials for plasticizers, polymers. wet strength paper resins and other specialty chemicals. These applications are growing rapidly as new uses are found for DBEs as building blocks.
Applications:
Plasticizers- Certain esters of adipic, glutaric, and succinic acids (as mixtures or individually) are excellent plasticizers for various polymer systems including polyvinyl chloride resins.
Polymer Intermediate- As a source of adipic, glutaric and succinic acids and their mixtures, Diabasic Esters provide unique polymer structures. By the selection of the proper DBE fraction, properties, such as low temperature flexibility, can be tailored to meet specific needs.
Polyester Polyols for Urethanes- Polyols based on DBE are used to make polyurethane elastomers, coatings and both flexible and rigid foams.
Wet-Strength Paper Resins- DBE-2, DBE-5, and DBE-9 are particularly useful in the preparation of long-chain water soluble polyamides of the type which can be reacted with epichlorohydrin to form wet-strength paper resins.
Polyester Resins- DBEs are used extensively in the manufacture of saturated and unsaturated polyester resins.
Specialty Chemical Intermediate- Dimethyl succinate (DBE-4), dimethyl glutarate (DBE-5) and dimethyl adipate (DBE-6) are abundant and economical sources of the adipic, glutarate and succinic moieties for organic synthesis.
Mixtures of different methyl dibasic esters are commercially produced from short-chain acids such as adipic acid, glutaric acid, and succinic acid. They are non-flammable, readily biodegradable, non-corrosive, and have a mild, fruity odour.
Dibasic esters of phthalates, adipates, and azelates with C8 - C10 alcohols have found commercial use as lubricants, spin finishes, and additives.
Dibasic esters are used in paints, coil coatings, paint strippers, coatings, plasticisers, resins, binders, solvents, polyols, soil stabilization, chemical grouting, oilfield drilling fluids, crop protection products, cedar spray, and adhesives.
Dibasic ester is a solvent that is obtained from blending of dimethyl glutarate, dimethyl succinate and dimethyl adipate and that is a strong solvent for polyester resins. Blending ratio of three esters differs according to the producer. Typical composition and some properties of a widely used product of Invista, named DBE, are given below:
Typical chemical composition:
59% Dimethyl glutarate
20% Dimethyl succinate
21% Dimethyl adipate
Boiling range: 196-225°C
Evaporation number relative to ether: >100
Specific gravity: 1,092
Refractive index: 1,423
Flash point: 103°C
Dibasic esters are excellent solvent substitutes in many parts cleaning and stripping applications.
Commercial acceptance and use of dimethyl esters and dibasic esters continues to increase due to their positive economic, environmental and performance characteristics.
Dimethyl esters and dibasic esters can be used alone or in customized ester and co-solvent blends to replace more conventional and increasingly regulated materials and industrial solvents, including, but not limited to:
N-methyl-2-pyrrolidone (NMP)
MEK
methylene chloride
isophorone
certain glycol ethers and their acetates
acetone
cresylic acid
Because of their low vapor pressure, dibasic esters will evaporate very slowly and can be recycled for repeated application.
The low vapor pressure also allows formulators and end-users to remain compliant with applicable VOC regulations.
For instance, certain DME blends under the Sta-Sol® ESS label qualify for LVP-VOC consumer product exemptions due to a vapor pressure of less than .1 mm Hg @ 20 °C.
A dibasic ester based formulation can be the perfect alternative for dissolving polar substances such as polyurethane, polyester, and acrylate resins, plus a wide range of coatings and inks.
Dibasic ester technology is used in a wide variety of applications, including:
Coil and Can Coatings
Polyester and Epoxy Sealing Coat
Automotive Coatings
Industrial Paint
Wire Enamel Coatings
Formulations
HI&I Cleaning
Liquid detergents
Pesticides and insecticides
Textile lubricants
Corrosion inhibitors
Printing inks
Foundry Core Resin Binder
Soil Stabilization
Wet Strength Paper Resins
Depending on the application, the combination of dimethyl glutarate, dimethyl adipate and dimethyl succinate can be custom tailored as a slowly evaporating cleaning and stripping solvent.
A dibasic ester based solvent blend may be considered a “greener” or environmentally preferable and safer product due to several safety and regulatory attributes, including:
-Environmental:
Low VOC (may qualify for LVP-VOC consumer product exemptions)
Readily Biodegradable
Not included CERCLA/SARA hazardous substances list
Not considered a hazardous waste under RCRA (waste status may change depending on spent resins and substances included in waste stream)
Not included on the CWA list of hazardous substances
Used in EPA Safer Choice formulations
-Health:
Not considered a carcinogen or reproductive toxin
Low levels of toxicity
Low Odor
Main components not subject to Proposition 65
Included on EPA list of safer chemicals for use in Safer Choice formulations
-Safety:
Non Flammable
Non Corrosive
Non Hazardous DOT
High Flash Point
High Boiling Point
Slowly Evaporating Solvents
Dibasic esters are generally defined as dialkyl esters of dicarboxylic acids capable of undergoing reactions at the ester group, including both hydrolysis and saponification. The acid portion of the dibasic ester may be derived from such dibasic acids as oxalic, malonic, pimelic, suberic and azelaic acids, as well as mixtures thereof.
Examples of suitable dibasic esters for use in the present invention include, but are not limited to, dimethyladipate, dimethyl glutarate, dimethyl succinate, and mixtures thereof.
A particularly preferred dibasic ester is a mixture of dimethyl adipate, dimethyl glutarate, and dimethyl succinate in varying weight ratios.
The surfactant component aids in both emulsifying the dibasic ester plus antioxidant emulsion and facilitates the enhanced uptake of the composition onto the surface of the synthetic textile substrate. Suitable surfactants which may be employed include, but are not limited to, nonionics, anionics, cationics, amphoterics and zwitterionics.
Dibasic Esters (DBE), also known as DMEs (dimethyl esters), are chemical compounds composed of a mixture of three dibasic esters namely: dimethyl adipate (DMA), dimethyl glutarate(DMG) and dimethyl succinate (DMS). DBE is used in a variety of solvent applications both as a standalone solvent and in formulations; however, it can be used as a chemical intermediate. It has been considered as green solvent to replace toxic and highly volatile solvents such as methylene chloride. ,
There are six DBE blends based on different fractions of the pure esters for specialty applications (DBE2, DBE-3, DBE-4, DBE-5, DBE-6, DBE-9). The most popular DBE blends used in paint stripping formulas contain about 90 percent DMA. Also, DBEs have applications in coating industry to clean adhesives, polyurethane foams and unsaturated polyester resins.
Dibasic esters are generally produced by catalytic esterification of dicarboxylic acids. Adipic acid, glutaric acid and succinic acid react with methanol in presence of an acidic catalyst (homogeneous or heterogeneous) with the following two stage cascade reactions:
Diacid + Methanol <---------> Monomethyl Ester + water
Monomethyl Ester + Methanol <---------> Dimethyl Ester + water
Since it is an equilibrium reaction, removing water from the system causes the reaction to shift towards formation of the desired product according to Le Chatelier’s principle. By studying phase equilibrium, it is possible to find any potential azeotrope and figure out the best way to separate water from the system. Also, boiling range of the components is extremely important in design of process.
DMA, DMG and DMS are the dimethyl esters of six, four and five carbon dicarboxylic acids respectively. They are very similar in structure differing by just one alkyl carbon.
DBE blend is a clear, colorless liquid, with mild odor. It is an excellent alternative to other traditional solvents because of some of its properties such as; Low (negligible) toxicity, Low vapor pressure (high boiling point), slow evaporation, high flash point, high miscibility with most organic solvents, low miscibility with water, biodegradability.
Dibasic esters are produced from esterification reaction of dicarboxylic acids of adipic, glutaric and succinic acids with methanol in presence of acidic homogeneous or heterogeneous catalysts. These valuable carboxylic acids are available in waste streams of adipic acid and caprolactam manufacturing plants which have been incinerated mostly in order to remove impurities. The idea for recovery of adipic acid along with glutaric and succinic acids from the waste streams into diesters have been investigated since 1960’s. The process waste streams were esterified in presence of methanol in continuous reaction, extraction and distillation columns which yielded high purity of diesters. The final product is a mixture of diesters which is separated from the solvent by distillation.
Use of extracting solvent introduces some disadvantages to the system such as the need for solvent recovery in the final product stream which makes the process less economical. Besides, as a result of esterification of a mixture of diacids (adipic, glutaric, succinic), there is a mixture of diesters (DMA, DMG, DMS) in the product stream which have different solubility values with a particular solvent.
Composition:
Material Cas No. %
Dimethyl succinate Cas No.: 106-65-0 15-25
Dimethyl glutarate Cas No.: 1119-40-0 55-65
Dimethyl adipate Cas No.: 627-93-0 10-25
Hazards identification
Potential Health Effects
DBE may irritate skin,eyes,nose and throat.May cause blurry vision.
Human health Effects:
Skin contact may cause skin irritation with discomfort or rash.Eye contact may cause eye irritation with discomfort,tearing,or blurring of vision.Inhalation may cause irritation of the upper respiratory passages,with coughing and discomfort.Some individuals who have been overexposed by inhalation or skin contact experienced blurry vision.
The mechanism of blurred vision in humans is unknown.
Based on observed effects from animal studies,we believe that some symptoms of pre-existing eye disease could be aggravated by overexposure to this material.
Carcinoogenicity Information
None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC,NTP,OSHA or Acgih as a carcinogen.
First-aid measures
Inhalation
If inhaled,immediately remove to fresh air.If not breathing,give artificial respiration.if breathing is difficult,give oxygen.Call a physician.
Skin contact
Flush skin with water after contact.Wash contaminated clothing before reuse.
Eye contact
In case of contact,immediately flush eyes with plenty of water for at least 15 minutes.Call a physician.
Ingestion
If swllowed,do not induce vomiting.Immediately give 2 glassed of water.Never give anything by mouth to an unconscious person.Call a physician.
Notes to Physicians
Activated charcoal mixture may be beneficial.Suspend 50 g activated charcoal in 400 ml water and mix well.Administer 5 ml/kg ,or 350ml for an averae adult.
Fire - fighting measures
Flammable properties
Flash Point : 100 c (212 F)
Method : TCC
Flammable limits in air,% by volume
LEL : 0.9
UEL :8.0
Autoignition :370 C (698 F)
Actual autoignition temperature (AIT) can be affected by the concentration of vapors and oxygen,vapor/air contact time,pressure,volume,catalytic impurities,etc.Process conditions should be analyzed to determine if the AIT’s may be higher or lower.
Vapor forms explosive mixture with air. hazardous gases/vapors produced in fire are carbon monoxide.
Extinguishing Media
Water Spray,Foam,Dry Chemical,CO2.
Fire Fighting Instructions
Keep personnel removed and upwind of fire. Wear self-contained breathing apparatus.Wear full protective equipment. Cool tank/container with water spray.
Accidental release measures
Safeguards (personnel)
NOTE: Review fire fighting measures and handling (personnel)
Sections before proceeding with clean-up.Use appropriate personal protective equipment during clean-up. Initial Containment
Remove source of heat,sparks,flame,impact,friction or electricity.Dike spill.Prevent material from entering sewers,waterways,or low areas.
Spill clean up
Recover free liquid for reuse or reclamation.Recover undamaged and minimally contaminated material for reuse and reclamation.Soak up with sawdust,sand,oil dry or other absorbent material.
Handling and storage
HANDLING (Personnel)
Avoid breathing vapors or mist.Avoid contact with eyes,skin,or clothing.Wash thoroughly after handing.
STORAGE
Do not mix with strong oxidants,acids,or alkalies.Store in a well ventilated place.Keep container tightly closed.
Exposure controls / personal protection
Engineering Controls
Use sufficient ventilation to keep employee exposure below recommended limits.
Personal Protective Equipment
Eye/face protection
Wear safety glasses.Wear coverall chemical splash goggles when possibility exists for eye and face contact due to splashing or spraying material.
Respirator
A NIOSH approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.Protection provided by air-purifying respirators is limited.Use a NIOSH approved positive pressure air-supplied respirator if there is any potential for an uncontrolled release.exposure levels are not known,or any other circumstances where air-purifying respirators may not provide adequate protection.
Protective Clothing
Wear impervious clothing,such as gloves,apron,boots,or whole bodysuit as appropriate.
Recommended glove and clothing material:Butyl Rubber.
Exposure guidelines
Exposure Limits
DBE
PEL (OSHA): None established
TLV (ACGIH):None Established
AEL : 1.5PPM,10 mg/m3,8 Hr.TWA
This limit is for DBE.
Physical and chemical properties
Boiling Point : 195-230
Vapor Pressure : 0.2 mm Hg @20 C (68 F)
Melting Point : ~-20 C (~-4 F)
% Volatiles : 100 WT% @ 20 C (68 F)
Evaporation Rate : <0.1 (Butyl Acetate=1.0)
Solubility in water : 5.3 WT % @ 20 C (68 F)
Odor : Sweet
Odor Threshold : 0.1ppm 100% detection
0.01 ppm 50% detection
Form : Liquid
Color : Colorless
Specific Gravity : 1.076-1.096 @ 20 C (68F)
Stability and reactivity
Chemical Stability: Stable
Incompatibility with Other Materials
Incompatible or can react with strong oxidizers,acids,alkalies.
Decomposition: Decomposes with heat.
Polymerization
Toxicological information
Animal Data
Inhalation 4-hour LC50: >11 mg/L in rats
Inhalation 1-hour LC50: >10.7 mg/L in rats
Skin absorption LD50 : >2,250 mg/kg in rabbits
Oral LD50 : 8,191 mg/kg in rats
The mixsture is a mild to severe skin irritant and a moderate eye irritant, but is not a skin sensitizer in animals.Toxic effects described in animals from exposure by inhalation include upper respiratory tract irritation. A single 4-four exposure to 60 ppm caused transient corneal opacity and transient increases in the distance from the cornea to the anterior surface of the lens of the eye. Toxity described in animals from repeated exposure by inhalation include decreased weight gain, absolute and relative liver weight decrease, and degeneration of olfactory epithelium(nasal tissue).
Toxicity described in animals from repeated exposure by ingestion include weight loss, but there were no pathological abnormalities noted.
A single application of 10 ul to the eye caused corneal opacity. The administration of 1o-100 ul of a similar mixture caused corneal opacity, transient increases in corneal thickness, and transient corneal anesthesia. A single application of approximately 60 mg/kg to the skin caused transient increases in the distance from the cornea to the anterior surface of the lens of the eye.
The mixture does not produce genetic damage in animals, or in bacterial cell cultures, but it was positive in one study with cultures, but it was positive in one study with cultured mammalian cells. Animal testing indicates that this mixture does not have developmental, or reproductive effects.
Ecological information
DIBASIC ESTER
96 hour LC50 - Fathead minnows: 18-24 mg/L. Moderately toxic.
48 hour LC50 – Daphnia magna: 112-150 mg/L.
Biodegradation Information:
The DIBASIC ESTER components, dimethyl succinate, dimethyl glutarate, and dimethyl adipate were tested for biodegradability using the 28-day closed bottle test. A minimum of 60% biodegradation must be reached in a 14 day window after exceeding the 10% level in order to pass this test and be rated as readily biodegradable. All of the components of DBE pass this test and, therefore, DBE is considered readily biodegradable.
Dimethyl succinate - 67% biodegradability in day 7
Dimethyl glutarate - 70% biodegradability in day 7
Dimethyl adipate - 58% biodegradability in day 7
- 84% biodegradability in day 14
Disposal considerations
Waste Disposal
Treatement, storage, transportation and disposal must be in accordance with applicable Federal, State/provincial and local regulations.
Recover unusable free liquid and dispose into either an approved and permitted incinerator or approved and permitted biological treatment system.
Recover any DBE contaminated water and dispose of into an approved and permitted biological treatment system.
Do not flush any water or solids into surface water drains or sanitary sewer system..
Remove unusable solid material or contaminated soil for disposal into an approved and permitted landfill.