Ferrous chloride (FeCl₂) is a well-known inorganic compound of iron and chlorine in its +2 oxidation state.
As a pale green solid or yellow-green solution, it is widely used in various industrial, chemical, and environmental applications.
This article aims to provide a comprehensive overview of its properties, synthesis, uses, environmental impact, and current research.
CAS Number: 7758-94-3
Synonyms: Iron(II) chloride, Iron dichloride, Ferrous dichloride, Iron monochloride, FeCl₂
Structural and Molecular Details
Ferrous chloride exists in both anhydrous and hydrated forms.
The most common hydrate is the tetrahydrate (FeCl₂·4H₂O), featuring octahedral coordination of iron by four water molecules and two chloride ions.
In the solid state, Fe²⁺ ions are coordinated in a distorted octahedral geometry.
Synthesis and Industrial Production
Industrial Synthesis:
From Iron and Hydrochloric Acid: