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Lithium monochloride's versatility extends from industrial applications like absorption refrigeration and air conditioning to its potential use in pharmaceuticals, dyeing processes, and even wood preservation treatments, highlighting its broad utility across various sectors.
With Lithium monochloride's unique properties, such as its high solubility in water, crimson flame color when burned, and role as a catalyst in chemical reactions, lithium monochloride stands out as a multifunctional compound with diverse applications in both scientific research and industrial processes.
Lithium monochloride's significance in alternative technologies, like magnetic refrigeration systems and molten salt batteries, underscores its potential to drive innovation in sustainable energy and environmental preservation, positioning lithium monochloride as a compound of interest for future advancements.
CAS Number: 7447-41-8
EC Number: 231-212-3
Molecular Formula: LiCl
Molecular Weight: 42.39
Synonyms: 7447-41-8, Lithium(1+) chloride, LiCl, Lithiumchloride, chlorure de lithium, Chlorku litu, chlorolithium, Lithiumchlorid, Lithium(1+) chloride (LiCl), lithium;chloride, CCRIS 5924, CHEBI:48607, lithii chloridum, HSDB 4281, Lithium Cholride, cloruro de litio, Lithium(1+) chloride (powder), EINECS 231-212-3, MFCD00011078, NSC 327172, UNII-G4962QA067, LITHIUM MURIATICUM, G4962QA067, NSC-327172, Lithium(1+) chloride, Anhydrous, LithiumChlorideGr(Anhydrous), CHEMBL69710, DTXSID2025509, EC 231-212-3, NSC327172, ClLi, Lithium(1+) chloride, ultra dry, Chlorku litu [Polish], Luthium chloride, Chloride, Lithium, Chlorure de lithium [French], 2M Lithium(1+) chloride Electrolyte, Electrode Filling Solution, Lithium(1+) chloride (2.3% in Tetrahydrofuran, ca. 0.5mol/L), lithim chloride, Lithium(1+) chloride, anhydrous, chunks, 99.99% trace metals basis, Lithium(1+) chloride anhydrous, Lopac-L-4408, LITHIUM MONOCHLORIDE, MolMap_000071, WLN: LI G, Lithium(1+) chloride, ACS grade, Lopac0_000604, Lithium(1+) chloride [MI], Lithium(1+) chloride battery grade, Lithium(1+) chloride, ACS reagent, DTXCID105509, Lithium(1+) chloride [HSDB], Lithium(1+) chloride [INCI], LITHIUM MURIATICUM [HPUS], KWGKDLIKAYFUFQ-UHFFFAOYSA-M, Lithium(1+) chloride [WHO-DD], Lithium(1+) chloride, 3-5% in THF, HMS3261J10, Tox21_500604, BDBM50494542, AKOS015902822, AKOS015950647, AKOS024438070, CCG-204693, Lithium(1+) chloride, gamma irradiated, 8m, LP00604, SDCCGSBI-0050586.P002, Lithium(1+) chloride, ACS reagent, >=99%, Lithium(1+) chloride, ReagentPlus(R), 99%, NCGC00015607-01, NCGC00015607-02, NCGC00015607-03, NCGC00015607-04, NCGC00015607-07, NCGC00093980-01, NCGC00093980-02, NCGC00261289-01, BP-13612, SY002997, Lithium(1+) chloride, Vetec(TM) reagent grade, EU-0100604, FT-0627896, L0204, L0222, Lithium(1+) chloride, Trace metals grade 99.9%, L 4408, Lithium(1+) chloride, SAJ first grade, >=98.0%, Lithium(1+) chloride, for molecular biology, >=99%, Lithium(1+) chloride, SAJ special grade, >=99.0%, A838146, Lithium(1+) chloride, BioXtra, >=99.0% (titration), Q422930, SR-01000076252, SR-01000076252-1, Lithium(1+) chloride, powder, >=99.99% trace metals basis, Lithium(1+) chloride, puriss. p.a., anhydrous, >=99.0% (AT), Lithium(1+) chloride, anhydrous, beads, -10 mesh, >=99.9% trace metals basis, Lithium(1+) chloride, anhydrous, beads, -10 mesh, 99.998% trace metals basis, Lithium(1+) chloride, puriss. p.a., ACS reagent, anhydrous, >=99.0% (AT), Lithium(1+) chloride, anhydrous, free-flowing, Redi-Dri(TM), ACS reagent, >=99%, Lithium(1+) chloride, anhydrous, free-flowing, Redi-Dri(TM), ReagentPlus(R), 99%, Lithium(1+) chloride, BioUltra, for molecular biology, anhydrous, >=99.0% (AT), 59217-69-5
Lithium monochloride is generally most soluble in alcohols in which the solubility decreases as the size of the organic radical increases.
Lithium monochloride dehumidifies air for industrial drying and for air conditioning.
Lithium monochloride Formula is a typical ionic compound and a salt of lithium.
Due to the small size of the lithium-ion ( Li+ ), it gives rise to properties that we cannot see in other alkali metal chlorides.
During the year the 1940s for a short while they produce Lithium monochloride as a compound to replace common salt (Sodium Chloride NaCl).
Lithium monochloride is used in absorption refrigeration and air conditioning systems.
In these systems, Lithium monochloride absorbs water vapor, and the resulting solution is then subjected to temperature changes to release the absorbed water, thus providing a cooling effect.
Lithium monochloride has been used in the hydraulic fracturing (fracking) process in the oil and gas industry.
Lithium monochloride is sometimes employed as a component in fluids used to prevent clay swelling and control shale stability.
Lithium monochloride also absorbs up to four equivalents of ammonia/mol.
As with any other ionic chloride, solutions of Lithium monochloride can serve as a source of chloride ion, e.g., forming a precipitate upon treatment with silver nitrate: LiCl + AgNO3 → AgCl + LiNO3
Lithium monochloride reacts with an alkali (such as Sodium Hydroxide) to form Sodium Chloride and Lithium Hydroxide.
LiCl+NaOH→LiOH+NaCl
Like other metal chlorides, Lithium monochloride salt produces crystalline hydrates.
Besides, it can easily absorb four equivalents of ammonia per mol.
However, Lithium monochloride can mainly serve as a chloride ion source when combined with an ionic chloride.
Lithium monochloride has been explored for its potential use in magnetic resonance imaging (MRI) contrast agents, as lithium ions exhibit interesting magnetic properties.
Lithium monochloride is considered in some thermal energy storage systems, where it may be used as a component in phase change materials for storing and releasing thermal energy.
Lithium monochloride finds applications in the dye industry, where it may be used in certain dyeing processes.
In analytical chemistry, Lithium monochloride can be used as a reagent for specific tests and analyses, particularly in the determination of certain ions.
Lithium monochloride is used in the Kjeldahl method for the determination of nitrogen content in organic compounds.
Lithium monochloride can be involved in the synthesis of certain phosphors, which are materials that emit light when exposed to radiation.
Lithium monochloride has been studied for its potential use in cryopreservation processes, where it may contribute to the preservation of biological samples at very low temperatures.
In metallurgy, Lithium monochloride can be used in heat treatment processes for certain metals, contributing to desired changes in the material properties.
Lithium monochloride is known for producing a crimson flame color when burned.
This property is sometimes used in flame tests to identify the presence of lithium ions.
Lithium monochloride is utilized as a catalyst or co-catalyst in certain chemical reactions, particularly in organic synthesis and polymerization processes.
In the pharmaceutical industry, Lithium monochloride is used in the production of certain antibiotics and pharmaceutical compounds.
Lithium monochloride can be employed in metal surface treatment processes, where it may play a role in enhancing the corrosion resistance of certain metals.
In analytical chemistry, Lithium monochloride can be used as a reagent or standard in specific testing procedures.
Lithium monochloride is used as a drying agent for gases in some laboratory and industrial applications.
Lithium monochloride has been investigated for its potential use in magnetic refrigeration systems, which is an alternative refrigeration technology that relies on the magnetocaloric effect.
In the development of molten salt batteries, Lithium monochloride may be used as an electrolyte component in certain designs.
Lithium monochloride has historical significance in photography, where it was used in certain processes related to developing and fixing photographs.
Researchers may use Lithium monochloride in studies related to thermophysical properties, such as specific heat capacity and thermal conductivity.
Lithium monochloride is used in some wood preservation treatments to protect wood from decay and insect infestation.
In certain designs of nuclear reactors, Lithium monochloride may be considered as a potential coolant due to its high boiling point.
Lithium monochloride can be involved in hydrometallurgical processes for the extraction of metals from ores.
Lithium monochloride is used in the textile industry for certain dyeing and finishing processes.
The salt forms crystalline hydrates, unlike the other alkali metal chlorides.
Lithium monochloride bums with a chrims on flame and is used in pyrotechnics.
Lithium monochloride is also used as a pyrotechnic in welding and brazing fluxes.
Lithium monochloride is a metal chloride salt with a Li(+) counterion.
Lithium monochloride has a role as an antimanic drug and a geroprotector.
Lithium monochloride is an inorganic chloride and a lithium salt.
Lithium monochloride is a chemical compound that is extremely soluble in polar solvents and is used in order to obtain lithium metal.
In organic synthesis it is used as an additive in the Stille Reaction. Ungraded products supplied by Spectrum are indicative of a grade suitable for general industrial use or research purposes and typically are not suitable for consumption.
Lithium monochloride is a chemical compound with a chemical formula “LiCl”.
The salt is a normal ionic compound, although the Li+ ion is small in size, it produces unrecognized effects for other alkali metal chlorides, such as exceptional solubility in polar solvents and its hygroscopic properties.
Lithium monochloride is an excellent water soluble crystalline Lithium source for uses compatible with Chlorides.
Lithium monochloride is generally immediately available in most volumes.
Lithium monochloride compounds can conduct electricity when fused or dissolved in water.
Lithium monochloride materials can be decomposed by electrolysis to chlorine gas and the metal.
They are formed through various chlorination processes whereby at least one chlorine anion (Cl-) is covalently bonded to the relevant metal or cation.
Ultra high purity and proprietary formulations can be prepared.
The chloride ion controls fluid equilibrium and pH levels in metabolic systems.
They can form either inorganic or organic compounds.
The majority of compounds in this class are slightly soluble or insoluble in water.
For example, CO2, which is often regarded as chemically inert, vigorously oxidizes the strong reducing agent Mg if the two are heated together.
If soluble in water, then the solutions are usually neither strongly acidic nor strongly basic.
Lithium monochloride salts affect the central nervous system in a variety of ways.
While the citrate, carbonate, and orotate salts are currently used to treat bipolar disorder, other lithium salts including the chloride were used in the past.
For a short time in the 1940s Lithium monochloride was manufactured as a salt substitute for people with hypertension, but this was prohibited after the toxic effects of the compound (tremors, fatigue, nausea were recognized.
Lithium monochloride was, however, noted by J. H. Talbott that many symptoms attributed to Lithium monochloride toxicity may have also been attributable to sodium chloride deficiency, to the diuretics often administered to patients who were given Lithium monochloride, or to the patients' underlying conditions.
Lithium monochloride is a chemical compound with the formula LiCl.
The salt is a typical ionic compound, although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties.
Lithium monochloride has been investigated as a potential electrolyte material in certain types of fuel cells, where it could play a role in ion conduction.
Lithium monochloride is involved in the hydrometallurgical extraction of lithium from lithium-bearing ores, where it plays a role in separating lithium from other elements.
Lithium monochloride is used in the construction of heat pipes, which are devices that transfer heat efficiently from one point to another.
Lithium monochloride is utilized in some soldering flux formulations, aiding in the soldering process by removing oxides from metal surfaces.
Lithium monochloride has been studied for potential applications in photovoltaic cells and solar energy systems.
Lithium monochloride has a high melting point of about 605 degrees Celsius (1,121 degrees Fahrenheit).
Lithium monochloride is highly soluble in water, and its aqueous solution conducts electricity.
Lithium monochloride is a White cubic crystals; granules or powder; hygroscopic; sharp salt-like taste; melts at 605°C; vaporizes around 1360°C, It has an unusually high water solubility when compared to the other alkali metal chlorides; readily dissolves in water (64g/100mL at 0°C); also highly soluble in alcohol and pyridine; moderately soluble in acetone (4.1 g/100mL at 25°C).
The following hydrates are known: LiCl·H2O, LiCl-3H20 and LiCl- 5H2O. The higher hydrates are stable at progressively lower temperatures.
Lithium monochloride is an ionic compound or salt that is highly polar and soluble in water.
Lithium monochloride is more soluble in organic solvents such as acetone and methanol than potassium chloride or sodium chloride.
Lithium monochloride is deliquescent under normal atmospheric conditions.
Lithium monochloride is soluble to a significant extent in many polar organic liquids.
In historical photography processes, Lithium monochloride was used in certain developing solutions.
Lithium monochloride has been investigated for its potential use in hydrogen storage systems, which is crucial for various hydrogen-based energy applications.
Lithium monochloride is used in some antifreeze mixtures, contributing to the lowering of the freezing point of solutions.
Lithium monochloride can be used in certain formulations in the cement and concrete industry to improve certain properties of the materials.
In the production of magnesium metal, Lithium monochloride may be used as a flux to remove impurities during the refining process.
Lithium monochloride is employed as a catalyst or co-catalyst in various organic synthesis reactions, facilitating specific chemical transformations.
In some water treatment processes, Lithium monochloride is used for specific applications, such as controlling algae growth in water systems.
Lithium monochloride has been studied for its potential use in nuclear waste treatment processes, particularly in separating certain elements from radioactive waste streams.
Lithium monochloride is used in some surface treatment processes in metalworking to enhance the properties of metal surfaces.
In semiconductor manufacturing, Lithium monochloride may be used in specific processes related to the production of electronic components.
Lithium monochloride has been considered in the development of lithium-air batteries, a type of battery technology with high energy density.
Lithium monochloride is used in chlorination reactions, where it may act as a source of chlorine atoms for specific chemical transformations.
Lithium metal is produced by electrolysis of Lithium monochloride and potassium chloride, which melts at 450°C.
High-purity Lithium monochloride is used as the feedstock in the process and makes about 99.5% pure lithium metal.
Molten Lithium monochloride is contained in a carbon steel pot, while the chlorine gas is collected in a stainless steel or glass pipe for applications in other processes.
The molten lithium flows into a collecting tank and is later cast into ingots.
A mesh or stainless-steel screen separates the two compartments to prevent the products from mixing.
Lithium monochloride is not used directly as a food additive, but lithium compounds are sometimes used in trace amounts in certain food and beverage products.
Lithium monochloride can be used in the synthesis of certain metal hydrides, which are compounds of metal and hydrogen.
In the glass industry, Lithium monochloride may be used in specific glass formulations to impart certain properties.
Lithium monochloride is utilized as a component in some welding flux formulations, aiding in the removal of impurities during welding processes.
Lithium monochloride is sometimes used in the oil and gas industry for applications such as drilling fluids and well completion fluids.
Lithium monochloride is used in dental alginate impression materials, which are commonly used in dentistry to create molds of teeth and surrounding structures.
Lithium monochloride is employed in some studies and experiments related to seed germination and plant growth.
Lithium monochloride may influence the germination process under certain conditions.
Lithium monochloride is a precursor in the production of metallic lithium.
Through processes like electrolysis, lithium metal can be obtained from Lithium monochloride.
Lithium monochlorides are not water-reactive.
Lithium monochloride is a typical ionic compound (with certain covalent characteristics), although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties.
Lithium monochloride is produced by treatment of lithium carbonate with hydrochloric acid.
Anhydrous Lithium monochloride is prepared from the hydrate by heating in a stream of hydrogen chloride.
Lithium monochloride is mainly used for the production of lithium metal by electrolysis of a LiCl/KCl melt at 450 °C (842 °F).
Lithium monochloride is also used as a brazing flux for aluminium in automobile parts.
Lithium monochloride is used as a desiccant for drying air streams.
In more specialized applications, Lithium monochloride finds some use in organic synthesis, e.g., as an additive in the Stille reaction.
Also, in biochemical applications, Lithium monochloride can be used to precipitate RNA from cellular extracts.
Lithium monochloride is also used as a flame colorant to produce dark red flames.
Lithium monochloride has many applications.
Lithium monochloride is extremely hygroscopic, and is widely used in dehumidification systems to remove moisture from the air in industries such as food processing and horticulture.
Lithium monochloride is also used as a tracer for waste water, as a brazing flux, and as an electrolyte component for the manufacture of speciality batteries.
Lithium monochloride is a white solid hygroscopic soluble in water, alcohol and ether.
The chemical formula for Lithium monochloride is Lithium monochloride.
Lithium monochloride is made by the action of hydrochloric acid on lithium hydroxide. The resulting solution is evaporated to get a mixture of saturated solution and Lithium monochloride crystals.
The solid and the solution is separated and the supernatant solution is recycled for further evaporation.
Lithium monochloride is a solid which absorbs water to form a hydrate, LiCl.H2O
Lithium monochloride is a white, crystalline solid at room temperature.
Uses of Lithium monochloride:
Lithium monochloride is commonly used as a desiccant in air conditioning systems to absorb moisture and control humidity.
Lithium monochloride is utilized in absorption refrigeration systems where it helps absorb water vapor, contributing to the cooling process.
Lithium monochloride is employed in dental alginate impression materials, crucial in dentistry for creating molds of teeth and oral structures.
Lithium monochloride is used in scientific studies and experiments related to seed germination and plant growth.
Lithium monochloride applied in drilling fluids and well completion fluids in the oil and gas industry.
Lithium monochloride used in chemical and pharmaceutical processes, including the synthesis of lithium compounds and pharmaceutical products.
Precursor in the production of metallic lithium through processes like electrolysis.
Employed as a catalyst or co-catalyst in various organic synthesis reactions.
Lithium monochloride is used in molecular biology for the precipitation of DNA and RNA from solution.
Involved in the extraction of metals from ores through hydrometallurgical processes.
Lithium monochloride is used in certain formulations to improve properties of cement and concrete.
Lithium monochloride is used in some antifreeze mixtures to lower the freezing point of solutions.
Lithium monochloride applied in certain water treatment processes for controlling algae growth.
Lithium monochloride is used in metal surface treatment processes to enhance corrosion resistance.
Lithium monochloride produces a crimson flame color when burned, used in flame tests for identifying lithium ions.
Investigated for potential use in lithium-air batteries, a high-energy-density battery technology.
Lithium monochloride is used as a relative humidity standard in the calibration of hygrometers.
Additionally, Lithium monochloride can be used as a hygrometer.
This deliquescent salt forms a self-solution when exposed to air.
The equilibrium LiCl concentration in the resulting solution is directly related to the relative humidity of the air.
The percent relative humidity at 25 °C (77 °F) can be estimated, with minimal error in the range 10–30 °C (50–86 °F), from the following first-order equation: RH=107.93-2.11C, where C is solution LiCl concentration, percent by mass.
Lithium monochloride is used for the preparation of carbon nanotubes, graphene[10] and lithium niobate.
Lithium monochloride has been shown to have strong acaricidal properties, being effective against Varroa destructor in populations of honey bees.
Lithium monochloride is used as an aversive agent in lab animals to study conditioned place preference and aversion.
Lithium monochloride is used in the following products: laboratory chemicals, pH regulators and water treatment products, metal working fluids, pharmaceuticals, polymers, water treatment chemicals and welding & soldering products.
Lithium monochloride is used in the following areas: scientific research and development and health services.
Lithium monochloride is used for the manufacture of: chemicals and plastic products.
Other release to the environment of Lithium monochloride is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners), outdoor use, indoor use in close systems with minimal release (e.g. cooling liquids in refrigerators, oil-based electric heaters), outdoor use in close systems with minimal release (e.g. hydraulic liquids in automotive suspension, lubricants in motor oil and break fluids), outdoor use in long-life materials with low release rate (e.g. metal, wooden and plastic construction and building materials) and indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment).
Lithium monochloride is used in the following products: pharmaceuticals, air care products, inks and toners, laboratory chemicals, metal working fluids, paper chemicals and dyes, polymers, water treatment chemicals and welding & soldering products.
Release to the environment of Lithium monochloride can occur from industrial use: formulation of mixtures and formulation in materials.
Lithium monochloride is used in the following products: welding & soldering products, laboratory chemicals, air care products, inks and toners, pH regulators and water treatment products, metal working fluids, pharmaceuticals, polymers and water treatment chemicals.
Lithium monochloride is used as a tracer element in soil science to study water movement in soil profiles.
Lithium monochloride is used in heat treatment processes for certain metals to achieve desired material properties.
Lithium monochloride utilized in some welding flux formulations to aid in the soldering process.
Lithium monochloride is used as a reagent in analytical chemistry for specific tests and analyses.
Explored for potential use in MRI contrast agents due to interesting magnetic properties.
Lithium monochloride is used for several soldering and welding techniques and salt bath heat treatment at low temperatures.
Lithium monochloride is used in massive dehumidification systems in the AC industry.
This depends on the low equilibrium pressure of vapor above Lithium monochloride solutions.
Lithium monochloride is used as a component in fluids for hydraulic fracturing processes.
Lithium monochloride utilized in the construction of heat pipes for efficient heat transfer.
Lithium monochloride is useful for the production of lithium metal, and for the generation of Mn(0) species which can be used in free radical cyclizations.
Lithium monochloride can serve as a flame colorant to generate dark red flames, a brazing flux for aluminum in automobiles, a hygrometer, and a desiccant for drying air streams.
On exposure to air, it becomes a solution with the concentration directly related to relative humidity of the atmosphere, and hence serves as a relative humidity standard in calibrating hygrometers.
Apart from being a source of Lithium monochloride, it serves as an additive in the Stille reaction in organic synthesis, and to precipitate RNA from cellular extracts.
Lithium monochloride is used in the following areas: scientific research and development and health services.
Lithium monochloride is used for the manufacture of: chemicals, plastic products and pulp, paper and paper products.
Release to the environment of Lithium monochloride can occur from industrial use: in processing aids at industrial sites, as an intermediate step in further manufacturing of another substance (use of intermediates), as processing aid, of substances in closed systems with minimal release and in the production of articles.
Lithium monochloride is used as a flux in the production of magnesium metal to remove impurities during the refining process.
Studied for potential use in cryopreservation processes, contributing to the preservation of biological samples at very low temperatures.
Investigated as a potential electrolyte material in certain types of fuel cells, contributing to ion conduction.
Studied for potential use in nuclear waste treatment processes, particularly in separating certain elements from radioactive waste streams.
Lithium monochloride is used in surface treatment processes in metalworking to enhance the properties of metal surfaces.
Lithium monochloride is used in semiconductor manufacturing for specific processes related to the production of electronic components.
Lithium monochloride is used in chlorination reactions, where it may act as a source of chlorine atoms for specific chemical transformations.
Historically used in certain developing solutions in photography processes.
Lithium monochloride is used in the heat treatment of certain alloys to achieve specific material properties.
Employed in metal plating processes to improve the surface properties of metals.
Studied for potential agricultural applications, including the enhancement of plant growth under specific conditions.
Lithium monochloride is used in certain formulations in the glass industry to improve certain properties of the materials.
While Lithium monochloride itself is not typically used in lithium-ion batteries, it is part of the broader lithium supply chain, contributing to lithium compounds used in battery manufacturing.
Investigated for potential use in molten salt batteries, where it may contribute to the electrolyte formulation.
Lithium monochloride is used in geochemical studies for specific chemical analyses and experiments.
Studied for potential use in magnetic refrigeration systems, which rely on the magnetocaloric effect for cooling.
Lithium monochloride is used in the synthesis of certain metal hydrides, compounds of metal and hydrogen.
Lithium monochloride utilized as a catalyst in amidation reactions, contributing to the formation of amide bonds.
Investigated for potential use as an electrolyte component in lithium-air batteries.
Lithium monochloride is used in gas absorption systems for selective removal of gases from mixtures.
Lithium monochloride applied in crystal growth processes for specific applications in materials science.
Explored for potential use in the growth of certain laser crystals.
Involved in the hydrometallurgical recovery of certain metals from various sources.
Considered for potential use in lithium-ion capacitors, an energy storage technology.
Lithium monochloride utilized in the production of certain ion exchange resins used in water treatment.
Lithium monochloride is used as an electrolyte for low temperature dry battery cells and as an oxidation catalyst.
Lithium monochloride is a solubilizer for polyamides and cellulose when used with amide solvents, and is a chlorinating agent for steroid substrates.
Lithium monochloride is used in large dehumidification systems in the air conditioning industry.
Lithium monochloride depends on the low equilibrium pressure of water vapour above solutions of Lithium monochloride.
Lithium monochloride is used in a number of salt mixtures exist low melting points allowing the material to be used in brazing fluxes and brazing baths.
Lithium monochloride is used as an electrolyte for the production of lithium metal and used as an electrolyte in voltaic cells.
Lithium monochloride is used for the production of lithium metal, by electrolysis of a LiCl/KCl melt at 450 °C.
Lithium monochloride is also used as a brazing flux for aluminium in automobile parts.
Lithium monochloride can be used to improve the efficiency of the Stille reaction. Its desiccant properties can be used to generate potable water by absorbing moisture from the air, which is then released by heating the salt.
For a short time in the 1940s Lithium monochloride was manufactured as a substitute for salt, but this was prohibited after the toxic effects of the compound were recognised.
Lithium monochloride is often used as a desiccant (drying agent) in air conditioning systems and industrial drying processes.
Lithium monochloride has a high affinity for water and can absorb moisture from the air.
Lithium monochloride is used in certain chemical and pharmaceutical processes, including the synthesis of lithium compounds and pharmaceutical products.
Lithium monochloride is considered as a potential material for use in molten salt reactors, which are a type of advanced nuclear reactor design.
Lithium monochloride is a key starting material in the production of metallic lithium through processes such as electrolysis.
While Lithium monochloride is not commonly used as an electrolyte in batteries, it is a source of lithium, a crucial component in lithium-ion batteries.
Lithium monochloride is used in laboratories as a reagent in certain chemical reactions and experiments.
In molecular biology, Lithium monochloride is used for the precipitation of DNA and RNA from solution, aiding in their isolation and purification.
Lithium monochloride is used as a flux in metallurgical processes, helping to lower the melting point of metal oxides during the production of certain metals.
Lithium monochloride is used in some types of fire extinguishing agents.
Due to its hygroscopic nature (ability to absorb moisture), Lithium monochloride is used in humidity control systems and certain industrial processes where water needs to be removed.
Being biologically significant, it finds applications in a wide variety of assays to study cell-fate and neurobiology.
Lithium monochloride has been found to inhibit virus infection.
Lithium monochloride solutions are used in large dehumidification systems in the air-conditioning industry.
This use depends on the low equilibrium pressure of water vapor above solutions of Lithium monochloride.
After the solutions have absorbed water, they are regenerated by heating.
Lithium monochloride is used in a number of salt mixtures.
Such salt mixtures have low melting points allowing the material to be used in brazing fluxes and brazing baths.
The molten Lithium monochloride-potassium chloride eutectic mixture can be used as an electrolyte.
The mixture is electrolyzed for the production of lithium metal and is used as an electrolyte in voltaic cells.
Lithium monochloride is also used in manufacture of mineral waters; in pyrotechnics; soldering aluminum; in refrigerating machines.
Lithium monochloride is used as a flame colorant to form dark crimson flames.
Lithium monochloride is used in the precipitation of RNA in biological applications.
Lithium monochloride is an aluminum blazing flux in automobile parts.
Preparation of Lithium monochloride:
Lithium monochloride may be prepared by reaction of lithium carbonate or lithium hydroxide with hydrochloric acid followed by crystallization:
Li2CO3+ 2HCl →2LiCl + CO2+ H2O
LiOH + HCl →LiCl + H2O
Crystallization above 95°C yields anhydrous salt.
Hot solution upon cooling forms crystals of monohydrate, LiCl.H2O.
The solid and solution are separated and the supernatant solution is recycled for further evaporation.
The crystals are dried to yield anhydrous Lithium monochloride.
Lithium monochloride can be synthesized from its elements by heating lithium metal with chlorine gas.
Lithium monochloride also may be obtained from natural brine.
Safety Profile of Lithium monochloride:
Lithium monochloride moderately toxic by subcutaneous and intraperitoneal routes.
Experimental teratogenic and reproductive effects.
Human systemic effects by ingestion: somnolence, tremors, nausea or vomiting.
Human poison by ingestion.
Lithium monochloride experimental poison by intravenous and intracerebral routes.
An eye and severe skin irritant.
Questionable carcinogen with experimental neoplastigenic data.
Lithium monochloride is used for dehumidification in the air conditioning industry.
This material has been recommended and used as a substitute for sodwm chloride in "saltfree" diets, but cases have been reported in which the ingestion of Lithium monochloride has produced dminess, ringing in the ears, visual disturbances, tremors, and mental confusion.
In most cases, the symptoms disappeared when use was discontinued.
Prolonged absorption may cause disturbed electrolyte balance, impaired renal function.
When heated to decomposition it emits toxic fumes of Cl-.
Identifiers of Lithium monochloride:
Chemical Formula: LiCl
CAS Registry Number: 7447-41-8
PubChem CID: 2783
ChemSpider ID: 2679
UNII: 3J18WZH4PB
EC Number: 231-212-3
RTECS Number: OJ5950000
InChI (International Chemical Identifier): InChI=1S/ClH.Li/h1H;/q;+1/p-1
SMILES (Simplified Molecular Input Line Entry System): [Li+].[Cl-]
Properties of Lithium monochloride:
Melting point: 605 °C (lit.)
Boiling point: 1383 °C/1 atm (lit.)
Density: 2.06
vapor pressure: 1.33 hPa (547 °C)
refractive index: n20/D 1.381
Flash point: -4 °F
storage temp.: 2-8°C
solubility: H2O: soluble
form: beads
pka: 2.256[at 20 ℃]
Specific Gravity: 2.068
color: White to gray
PH: 5.5-7.5 (25℃, 50mg/mL in H2O)
Odor: Odorless
PH Range: 6
Water Solubility: 832 g/L (20 ºC)
Sensitive: Hygroscopic
λmax.λ: 260 nm Amax: 0.01
λ: 280 nm Amax: 0.01
Merck: 14,5528
Stability: Stable. Incompatible with strong oxidizing agents, strong acids, bromine trichloride, bromine trifluoride. Very hygroscopic. Protect from moisture.
InChIKey: KWGKDLIKAYFUFQ-UHFFFAOYSA-M
LogP: -1
Specifications of Lithium monochloride:
Purity: Typically ≥ 99%
Appearance: White crystalline solid
Molecular Weight: Approximately 42.39 g/mol
Melting Point: Approximately 605 °C (1121 °F)
Boiling Point: Approximately 1382 °C (2520 °F)
Density: Approximately 2.07 g/cm³
Solubility: Highly soluble in water, soluble in ethanol and acetone
Moisture Content: Typically ≤ 0.5%
Impurities: Low levels of other alkali metal chlorides and other impurities
