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N-METHYLOL ACRYLAMIDE

N-Methylol Acrylamide is used in adhesives, binders, surface coatings, and resins.
N-Methylol Acrylamide is used as a starch modifier.
N-Methylol Acrylamide can be used as a cross-linking agent, widely used in fiber modified resin, processing dyes, plastic adhesives, soil stabilizers, etc


CAS Number: 924-42-5
EC Number: 213-103-2
MDL Number: MFCD00004597
CHEMICAL NAME: N-Methylolacrylamide
Molecular Formula: C4H7NO2
Molecular Weight: 101.104 g/mol

SYNONYMS:
n-methylolacrylamide, n-hydroxymethyl acrylamide, n-methanolacrylamide, monomethylolacrylamide, methylolacrylamide, n-methylol acrylamide, 2-propenamide, n-hydroxymethyl, acrylamide, n-hydroxymethyl, uramine t 80, n-hydroxymethyl-2-propenamide, N-(HYDROXYMETHYL)ACRYLAMIDE, METHYLOLACRYLAMIDE, N-MAN, N-MAN PC, NM-AMD, uraminet80, Rocagil BT, NCI-C60333, N-Methylol, Yuramin T 80, 2-Propenamide,N-(hydroxymethyl)-, Acrylamide, N-(hydroxymethyl)-, Monomethylolacrylamide, n-(hydroxymethyl)-2-propenamid, n-(hydroxymethyl)-acrylamid, NCI-C60333, NM-AMD, N-Methanolacrylamide, NMA, N-Methylolacrylamide, Acrylamide methylol derivative, Crosslinking monomer, Methanol-stabilized NMA, Flocculant enhancer, Polymer crosslinker, Functional acrylamide derivative, N-(hydroxymethyl)prop-2-enamide, N-(Hydroxymethyl)acrylamide, n-Methylolacrylamide, METHYLOLACRYLAMIDE 45%, MLAM 48%, Flocryl NMA 48, N-MAM 60 S (200), AEROTEX NMA LF, NMA monomer 48 % in water, N-Methylolacrylamide 48 (NMA 48), N-Methylolacrylamide, N-(Hydroxymethyl)acrylamide, NCI-C60333, N-MAM, NM-AMD, N-Methanolacrylamide, N-Methyloacrylamide, 2-Propenamide, N-(hydroxymethyl)-, Acrylamide, N-(hydroxymethyl)-, Methylolacrylamide, Monomethylolacrylamide, Monomethylolacrylamide NMA, N-(Hydroxymethyl) acrylamide, N-(Hydroxymethyl)-2-propenamide, NSC 553, Uramine T 80, Yuramin T 80, 2-Propenamide, N-(hydroxymethyl)-, Acrylamide, N-(hydroxymethyl)-, Hydroxymethylacrylamide, Methylolacrylamide, Monomethylolacrylamide, N-(Hydroxymethyl)-2-propenamide, N-(Hydroxymethyl)acrylamide, N-Hydroxymethyl acrylamide, N-Methanolacrylamide, Uramine T 80, Acrylamide, N-(hydroxymethyl)-, Monomethylolacrylamide, N-(Hydroxymethyl)acrylamide, N-Methanolacrylamide, N-Methylolacrylamide, Uramine T 80, Yuramin T 80, Methylolacrylamide, N-(Hydroxymethyl)-2-propenamide, NCI-C60333, N-Methyloacrylamide, NM-AMD, NSC 553, N-MAM, Acrylamide, N-(hydroxymethyl)- (6CI,8CI), N-(Hydroxymethyl)-2-propenamide, Cylink NMA, MH 100, MH 100 (amide), Monomethylolacrylamide, N-(Hydroxymethyl)acrylamide, N-MAM, N-MAM P, N-Methanolacrylamide, N-Methylolacrylamide, N-NBM, NMA 60, NSC 553, Rocagil BT, U-Ramin T, 80 METHYLOLACRYLAMIDE, n-(hydroxymethyl)-2-propenamide, N-(HYDROXYMETHYL)ACRYLAMIDE, N-METHYLOLACRYLAMIDE, 2-Propenamide,N-(hydroxymethyl)-, Acrylamide, N-(hydroxymethyl)-, Monomethylolacrylamide, n-(hydroxymethyl)-2-propenamid, n-(hydroxymethyl)-acrylamid, NCI-C60333, NM-AMD, N-Methanolacrylamide, N-Methyloacrylamide, n-methylolacrylamide(48%inwater), Uramine T 80, uraminet80, Yuramin T 80, Methylolacrylamidesolution, N-MAN, N-(HYDROXYMETHYL)ACRYLAMIDE SOLUTION, ST AB., ~48% IN H2O, 2-Propenamide,N-(hydroxymethyl)-, Acrylamide,N-(hydroxymethyl)-, N-(Hydroxymethyl)-2-propenamide, N-Methylolacrylamide, N-Methanolacrylamide, N-(Hydroxymethyl)acrylamide, Monomethylolacrylamide, NMA 60, MH 100 (amide), MH 100, N-MAM P, U-Ramin T 80, Rocagil BT, N-MAM, NSC 553, N-NBM, Cylink NMA, N-Methylol acrylamide, NMA 48, 90456-67-0, 160278-55-7, 176598-18-8, 194091-52-6, 211862-48-5, 211862-50-9, 2-Propenamide,N-(hydroxymethyl)-, Acrylamide,N-(hydroxymethyl)-, N-(Hydroxymethyl)-2-propenamide, N-Methylolacrylamide, N-Methanolacrylamide, N-(Hydroxymethyl)acrylamide, Monomethylolacrylamide, NMA 60, MH 100 (amide), MH 100, N-MAM P, U-Ramin T 80, Rocagil BT, N-MAM, NSC 553, N-NBM, Cylink NMA, N-Methylol acrylamide, NMA 48, 90456-67-0, 160278-55-7, 176598-18-8, 194091-52-6, 211862-48-5, 211862-50-9, N-(Hydroxymethyl)acrylamide, 2-Propenamide, N-(hydroxymethyl), N-(Hydroxymethyl)-2-propenamide, N-Methylol acrylamide, N-Methanolacrylamide, n-(hydroxymethyl)-2-propenamide, N-methanolacrylamide, Monomethylolacrylamide, NCI-C60333, Uramine T 80, N-(HYDROXYMETHYL)ACRYLAMIDE, N-Methylolacrylamide, 924-42-5, Methylolacrylamide, N-Methylol Acrylamide, N-Methanolacrylamide, Monomethylolacrylamide, 2-Propenamide, N-(hydroxymethyl)-, N-Hydroxymethyl acrylamide, Acrylamide, N-(hydroxymethyl)-, Uramine T 80, N-(hydroxymethyl)prop-2-enamide, N-(Hydroxymethyl)-2-propenamide, Hydroxymethylacrylamide, N-MAM, N-Methyloacrylamide, NCI-C60333, Yuramin T 80, CCRIS 2380, NM-AMD, HSDB 4361, NSC 553, EINECS 213-103-2, UNII-W8W68JL80Q, BRN 0506646, AI3-25447, NSC-553, METHYLOLACRYLAMIDE, N-, W8W68JL80Q, DTXSID3020885, CHEBI:82492, EC 213-103-2, N-METHYLOLACRYLAMIDE [IARC], MFCD00004597, N-(HYDROXYMETHYL)ACRYLAMIDE [HSDB], N-METHYLOLACRYLAMIDE (IARC), N-hydroxymethylacrylamide, NMethanolacrylamide, ROCAGIL BT, NHydroxymethyl acrylamide, N(Hydroxymethyl)acrylamide, N-MAM P, N(Hydroxymethyl)2propenamide, Acrylamide, N(hydroxymethyl), N-(hydroxymethyl) acrylamide, SCHEMBL25806, U-RAMIN T 80, DTXCID90885, 2Propenamide, N(hydroxymethyl), MH 100 (AMIDE), NMA 60, NSC553, CHEMBL1892361, N-(Hydroxymethyl)acrylamide 100 microg/mL in Acetonitrile, MH 100, AKOS006222324, CS-W013710, NCGC00163845-01, NCGC00163845-02, BS-17859, M0574, NS00008229, C19456, E78933, EN300-7474805, W-100289, Q26840808, uraminet80, Yuramin T 80, METHYLOLACRYLAMIDE, N-METHYLOLACRYLAMIDE, N-Methylol acrylamide, Methylolacrylamidesolution, N-(HYDROXYMETHYL)ACRYLAMIDE, N-(Hydroxymethyl)acrylamide, n-(hydroxymethyl)-2-propenamide, N-(Hydroxymethyl)acrylamide, N-(Hydroxymethyl)-2-propenamide, Monomethylolacrylamide, N-Methanolacrylamide, 2-Propenamide, N-(hydroxymethyl)-, Uramine T 80, uraminet80, Yuramin T 80, METHYLOLACRYLAMIDE, N-METHYLOLACRYLAMIDE, N-Methylol acrylamide, Methylolacrylamidesolution, N-(HYDROXYMETHYL)ACRYLAMIDE, N-(Hydroxymethyl)acrylamide, n-(hydroxymethyl)-2-propenamide

N-Methylol Acrylamide is a white solid
N-Methylol Acrylamide is a secondary carboxamide.
N-Methylol Acrylamide is a colorless or yellow aqueous solution.


N-Methylol Acrylamide is soluble in water.
N-Methylol Acrylamide is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 1 000 to < 10 000 tonnes per annum.


N-Methylol Acrylamide is a functional monomer-acrylamide monomer. 
N-Methylol Acrylamide has a minimum solid content of 52% and a pH value of 6.0-8.0. 
N-Methylol Acrylamide is well suited for use in coatings.


N-Methylol Acrylamide is a self-bred active monomer. 
In the molecular structure, N-Methylol Acrylamide has a dual and active functional group conjugated with hydroxyl groups. 
N-Methylol Acrylamide is very soluble in water and alcohol, and is hardly soluble in chloroform and tetrachloride. 


Carbon, N-Methylol Acrylamide is easy to self-polymerize and cross-link into insoluble resin in humid air, especially under acidic conditions.
Molecular formula of N-Methylol Acrylamide is CH2CHCONH2, white flake crystal! 
N-Methylol Acrylamide is soluble in water, methanol, ethanol, propanol, slightly soluble in ethyl acetate, chloroform, slightly soluble in benzene, the molecule has two active centers, both weak alkali, weak acid reaction. 


N-Methylol Acrylamide because of its molecular structure contains two reactive groups, a polymerizable double bond and a condensable methylol Group, it therefore has the characteristics of a crosslinking agent monomer. 
The earliest synthetic method was to react acrylamide with formaldehyde to obtain crystalline N-Methylol Acrylamide. 


For example, foreign scholars use paraformaldehyde and acrylamide crystals, trichloroethylene as solvent, and metal sodium colloid as catalyst to produce N-Methylol Acrylamide. 
After the reaction is finished, the system naturally divides into two phases. 


When the temperature is lowered to room temperature, N-Methylol Acrylamide precipitates in a large amount.
N-Methylol Acrylamide product is obtained, but the obtained product needs to be recrystallized with acetone or ethyl acetate.

USES and APPLICATIONS of N-METHYLOL ACRYLAMIDE:
N-Methylol Acrylamide is a bifunctional monomer with reactive vinyl and hydroxymethyl groups. 
Thermoplastic polymers can be formed by copolymerization of N-Methylol Acrylamide with a variety of vinyl monomers by emulsion, solution and suspension techniques. 


The resulting products, which have pendant hydroxymethyl groups, can undergo cross-linking under moderate conditions, permitting conversion of thermoplastic backbone polymers to thermoset materials at the point of use in the absence of an external cross-linking agent. 
Conversely, the hydroxymethyl group can be reacted with a substrate like cellulose and subsequently cross-linked by free-radical polymerization.


The uses of N-Methylol Acrylamide range from adhesives and binders in papermaking and textiles to a variety of surface coatings and resins for varnishes, films and sizing agents. 
N-Methylol Acrylamide can be used in wet-strength and dry-strength agents for paper, in textile finishing agents for crease resistance, in antistatic agents, in dispersing agents, in cross-linking agents and in emulsion polymers.


Uses and Applications: N-Methylol Acrylamide is utilized in various industrial applications, including.
Polymerization: N-Methylol Acrylamide acts as a crosslinking agent in the production of polymers, enhancing properties such as adhesion, mechanical strength, and durability.


Adhesives and Binders: N-Methylol Acrylamide improves the performance of adhesives and binders used in coatings, paints, and sealants.
Textile Industry: N-Methylol Acrylamide is used to impart crease resistance and durability to fabrics.
Water Treatment: N-Methylol Acrylamide is employed in water treatment processes to improve flocculation and sedimentation.


Personal Care Products: N-Methylol Acrylamide is incorporated into formulations to enhance product stability and performance.
N-Methylol Acrylamide is used in formulation or re-packing, at industrial sites and in manufacturing.
Release to the environment of N-Methylol Acrylamide can occur from industrial use: formulation of mixtures.


N-Methylol Acrylamide is used in the following products: polymers. 
N-Methylol Acrylamide has an industrial use resulting in manufacture of another substance (use of intermediates). 
N-Methylol Acrylamide is used in the following areas: agriculture, forestry and fishing and formulation of mixtures and/or re-packaging. 


N-Methylol Acrylamide is used for the manufacture of: chemicals and textile, leather or fur. 
Release to the environment of N-Methylol Acrylamide can occur from industrial use: as an intermediate step in further manufacturing of another substance (use of intermediates), for thermoplastic manufacture and as processing aid.


Release to the environment of N-Methylol Acrylamide can occur from industrial use: manufacturing of the substance.
N-Methylol Acrylamide (NMA) is a versatile and widely used chemical compound in various industries. 
N-Methylol Acrylamide is a monomer that possesses unique crosslinking properties, making it valuable in different applications.. 


This versatile compound, N-Methylol Acrylamide, finds applications in the production of adhesives, coatings, and textiles, where its cross linking capabilities play a crucial role in improving product performance.
N-Methylol Acrylamide is used Polymerization, Adhesives and Binders, Water Treatment, Textile Industry, Personal Care Products, and Crosslinking Agent.


N-Methylol Acrylamide is mainly used to produce a variety of copolymers, homopolymers and modified polymers which are widely used in oil exploration, medicine, metallurgy, paper-making, paint, textile, water treatment and pesticide, etc.
N-Methylol Acrylamide is used in adhesives, binders, surface coatings, and resins.


N-Methylol Acrylamide is used as a starch modifier.
N-Methylol Acrylamide can be used as a cross-linking agent, widely used in fiber modified resin, processing dyes, plastic adhesives, soil stabilizers, etc


The applications of N-Methylol Acrylamide range from adhesives and binders in papermaking, textiles, and non-wovens to a variety of surface coating and resin for varnishes, films and sizing agents.


N-Methylol Acrylamide has two active groups in its molecular structure, which are polymerizable double bonds and condensable methylol groups, therefore, it has the characteristics of crosslinking agent monomer and is widely used in the fields of fiber modification, resin processing, coatings, plastics, adhesives, oil field additives and soil amendments. 


In addition, N-Methylol Acrylamide can also be polymerized with a variety of monomers in an aqueous system to prepare a polymer with excellent performance, which is a fine chemical widely used at present. 
Foreign research and application of this technology is relatively mature, the domestic application is still very limited, many applications still need further research and development, N-Methylol Acrylamide can also play a greater potential and value.    


N-Methylol Acrylamide molecule has double bond conjugated with carbonyl and reactive hydroxymethyl.
N-Methylol Acrylamide is a widely used cross-linking monomer for fiber modification, resin processing, adhesives and paper, leather, metal surface treatment agents, but also for soil amendments. 


N-Methylol Acrylamide can be used as crosslinking agent, widely used in fiber modification resin, processing dye, plastic adhesive, soil stabilizer, etc.
Organic synthetic monomer, N-Methylol Acrylamide, can be used to prepare a variety of copolymers.

N-METHYLOL ACRYLAMIDE IS APPLIED IN THE PRODUCTION OF;
*Textile Industry
*Paper Industry
*Coatings and Paints
*Adhesives
*Personal Care and Cosmetics
*Polymer Industry

BENEFITS AND CHARACTERISTICS OF N-METHYLOL ACRYLAMIDE:
Crosslinking Properties: N-Methylol Acrylamide provides strong crosslink bonds in polymers, resulting in enhanced adhesion, mechanical strength, and durability.
Versatility: 
N-Methylol Acrylamide is applicable in various industries due to its ability to improve product performance.

PROPERTIES OF N-METHYLOL ACRYLAMIDE:
*strong crosslink bonds in polymers
*resulting in enhanced adhesion
*mechanical strength
*durability of the final products

PREPARATION OF N-METHYLOL ACRYLAMIDE:
(1), acrylamide is added to the reaction kettle filled with solvent acetone, raise the temperature to 42~45 ℃;
(2), add the catalyst sodium methoxide, adjust the pH value of the reaction solution to 8.88;
(3), add formaldehyde, adjust the pH value of the reaction solution to 8.5, the reaction was carried out at a constant temperature for 1 hour;
(4) phthalic acid was added to adjust the pH of the reaction solution to 7.2;
(5) the reaction solution was cooled, crystallized and filtered to obtain the finished N-Methylol Acrylamide.

PHYSICAL AND CHEMICAL PROPERTIES OF N-METHYLOL ACRYLAMIDE:
"character white powder, soluble in water or hydrophilic solvent, but insoluble in hydrocarbon halogenated hydrocarbon and other solvents, unstable in humid air or water, easy polymerization, when heated in the presence of acid in aqueous solution, N-Methylol Acrylamide will rapidly polymerize into insoluble resin

PROPERTIES OF N-METHYLOL ACRYLAMIDE:
White crystal. 
N-Methylol Acrylamide is a type of self-crosslink monomer with double bond and active function group. 
N-Methylol Acrylamide is unstable in humid air or water and easy to polymerize. 
In the presence of acid in aqueous solution, N-Methylol Acrylamide will quickly polymerize into insoluble resin.

PRODUCTION OF N-METHYLOL ACRYLAMIDE:
Acrylamide reacts readily with formaldehyde to form N-Methylol Acrylamide. 
Information available in 1991 indicated that N-Methylol Acrylamide was produced by two companies in Japan and one each in the Netherlands, the United Kingdom and the USA. 
In Japan, about 900 tonnes of N-Methylol Acrylamide were produced as powder and 250 tonnes as water solution in 1992.

REACTIVITY PROFILE OF N-METHYLOL ACRYLAMIDE:
N-Methylol Acrylamide may be sensitive to prolonged exposure to light. 
Polymerization and generation of heat and flames may occur on exposure to to heat or contaminants. 
N-Methylol Acrylamide is incompatible with strong oxidizers.

PHYSICAL and CHEMICAL PROPERTIES of N-METHYLOL ACRYLAMIDE:
Melting point: 74-75°C
Boiling point: 277°C (lit.)
Density: 1.082 g/mL at 20 °C
Vapor pressure: 31 hPa (25 °C)
Refractive index: n20/D 1.413
Flash point: 100°C
Storage temp.: Store at <= 20°C.
Solubility: Chloroform (Slightly), Methanol (Slightly)
pKa: 13.25±0.10 (Predicted)
Form: Solid
Specific Gravity: 1.074

Color: White to Off-White
pH: 6.0-7.0 (H2O, 20°C)
Water Solubility: <0.1 g/100 mL at 20.5 ºC
BRN: 506646
Stability: Light Sensitive, Moisture Sensitive
InChIKey: CNCOEDDPFOAUMB-UHFFFAOYSA-N
LogP: -1.81 at 20℃ and pH7
Indirect Additives used in Food Contact Substances: N-METHYLOLACRYLAMIDE
FDA 21 CFR: 175.105; 176.180; 177.1010
CAS DataBase Reference: 924-42-5 (CAS DataBase Reference)
EWG's Food Scores: 1

FDA UNII: W8W68JL80Q
Proposition 65 List: n-Methylolacrylamide
NIST Chemistry Reference: 2-Propenamide, n-(hydroxymethyl)- (924-42-5)
IARC: 3 (Vol. 60) 1994
EPA Substance Registry System: N-Methylolacrylamide (924-42-5)
UNSPSC Code: 12352111
NACRES: NA.23
Appearance: White to Almost white powder to crystal
Purity (HPLC): min. 97.0 area%
Purity (Bromination Method): min. 98.0%

Melting point: 75.0 to 79.0 °C
Solubility in Water: almost transparent
Features (reference)
Melting Point: 76 °C
Boiling Point: 277 °C
Solubility in water: Completely soluble
Degree of solubility in water: 1,880 g/l 20 °C
Solubility (soluble in): Alcohol
Density: 1.074
Boiling Point: 318.1±34.0 °C at 760 mmHg
Melting Point: 74-75°C

Molecular Formula: C4H7NO2
Molecular Weight: 101.104
Flash Point: 146.2±25.7 °C
Exact Mass: 101.047676
PSA: 49.33000
LogP: -1.48
Vapor Pressure: 0.0±1.5 mmHg at 25°C
Index of Refraction: 1.459
Storage condition: Refrigerator
Water Solubility: <0.1 g/100 mL at 20.5 ºC
IUPAC Name: N-(hydroxymethyl)prop-2-enamide

Solubility: less than 1 mg/mL at 68.9 °F
Storage: Refrigerator
CAS: 924-42-5
EINECS: 213-103-2
InChI: InChI=1/C4H7NO2/c1-3(2-6)4(5)7/h6H,1-2H2,(H2,5,7)
InChIKey: CNCOEDDPFOAUMB-UHFFFAOYSA-N
Molecular Formula: C4H7NO2
Molar Mass: 101.1
Density: 1.082 g/mL at 20°C
Melting Point: 74-75°C

Boiling Point: 277°C (lit.)
Flash Point: 100°C
Water Solubility: <0.1 g/100 mL at 20.5 ºC
Solubility: Chloroform (Slightly), Methanol (Slightly)
Vapor Pressure: 31 hPa (25 °C)
Appearance: Solid
Specific Gravity: 1.074
Color: White to Off-White
BRN: 506646
pKa: 13.25±0.10 (Predicted)
pH: 6.0-7.0 (H2O, 20°C)

Storage Condition: Store at <= 20°C.
Stability: Light Sensitive, Moisture Sensitive
Sensitive: Sensitive to light
Refractive Index: n20/D 1.413
MDL: MFCD00004597
Chemical Nature: Polymer or monomer-based product, typically containing N-methylolacrylamide.
Appearance: Clear or slightly cloudy liquid or solid, depending on formulation.
Molecular Formula (NMA): C4H7NO2
Molecular Weight (NMA): 101.1 g/mol
Density: Approx. 1.1 g/cm³ (may vary with composition).

Solubility: Soluble in water.
Thermal Stability: Decomposes at elevated temperatures.
pH: Dependent on formulation, typically 4–8.
Appearance: Clear to slightly yellowish solution
Molecular weight (g.mol-1): 101.10
Active content (%): 48.0
Refractive index (%): 1.412
Heat of polymerisation (Kcal/mole): 20.0
Specific gravity at 25°C: 1.08

Cristallization point (°C): -10
Molecular Weight: 101.10 g/mol
XLogP3-AA: -0.5
Hydrogen Bond Donor Count: 2
Hydrogen Bond Acceptor Count: 2
Rotatable Bond Count: 2
Exact Mass: 101.047678466 g/mol
Monoisotopic Mass: 101.047678466 g/mol
Topological Polar Surface Area: 49.3Ų

Heavy Atom Count: 7
Formal Charge: 0
Complexity: 79.8
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes
Product Name: N-Methylolacrylamide

CAS No.: 924-42-5
Molecular Formula: C4H7NO2
InChIKeys: InChIKey=CNCOEDDPFOAUMB-UHFFFAOYSA-N
Molecular Weight: 101.10400
Exact Mass: 101.10
EC Number: 213-103-2
UNII: W8W68JL80Q
ICSC Number: 1637
NSC Number: 553
PSA: 49.33000
XLogP3: -0.37070

Appearance: N-methylolacrylamide appears as a colorless or 
yellow aqueous solution.
Density: 1.074
Melting Point: 74.5 °C
Boiling Point: 318.1ºC at 760mmHg
Flash Point: 146.2ºC
Refractive Index: n20/D 1.413
Water Solubility: Solubility in water, g/100ml at 20°C: 188
Storage Conditions: Refrigerator
Vapor Pressure: Vapour pressure, Pa at 25°C: 0.03 (negligible)
Air and Water Reactions: Soluble in water.

Reactive Group: Alcohols and Polyols
Reactivity Alerts: Polymerizable
Molecular weight (g.mol-1 ): 101.10
Active content (%): 48.0
Refractive index (%): 1.412
Heat of polymerisation (Kcal/mole): 20.0
Specific gravity at 25°C: 1.08
Cristallization point (°C): -10
Product Number: M0574

Purity / Analysis Method: >98.0%(T)
Molecular Formula / Molecular Weight: C4H7NO2 = 101.11 
Physical State (20 deg.C): Solid
Storage Temperature: 0-10°C
Condition to Avoid: Light Sensitive,Heat Sensitive
CAS RN: 924-42-5
Reaxys Registry Number: 506646
PubChem Substance ID: 87572604
SDBS (AIST Spectral DB): 1581
MDL Number: MFCD00004597
Physical state: liquid

Color: colorless, yellow
Odor: formaldehyde-like
Melting point/freezing point:
Melting point/range: -10 °C
Initial boiling point and boiling range: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Flash point: > 93 °C - closed cup
Autoignition temperature: Not applicable
Decomposition temperature: No data available

pH: 6,0 - 7,0
Viscosity 
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Water solubility at 20 °C soluble
Partition coefficient: n-octanol/water: No data available
Vapor pressure: 31,68 hPa at 25 °C
Density: 1,074 g/cm3 at 25 °C
Relative density: No data available
Relative vapor density: No data available
Particle characteristics: No data available

Explosive properties: Not classified as explosive.
Oxidizing properties: none
Other safety information: No data available
Solubility: 1880 g/l (20 °C)
Melting Point: -10 °C
Boiling Point: 100 °C (1013 hPa)
Vapor Pressure: 31 hPa (25 °C)
Flash Point: 93 °C
Density: 1.08 g/cm3 (20 °C)
pH: 6.0 - 7.0 (H2O, 20 °C)

Assay (ex N): 48 - 50%
Identity (IR): Passes test
Storage temperature: 15 °C
Molecular Weight: 101.10400
Exact Mass: 101.10
EC Number: 213-103-2
UNII: W8W68JL80Q
ICSC Number: 1637
NSC Number: 553
DSSTox ID: DTXSID3020885
HScode: 2924199090
PSA: 49.33000
XLogP3: -0.37070

Appearance: N-methylolacrylamide appears as a colorless or 
yellow aqueous solution.
Density: 1.074
Melting Point: 74.5 °C
Boiling Point: 318.1ºC at 760mmHg
Flash Point: 146.2ºC
Refractive Index: n20/D 1.413
Water Solubility: Solubility in water, g/100ml at 20°C: 188
Storage Conditions: Refrigerator
Vapor Pressure: Vapour pressure, Pa at 25°C: 0.03 (negligible)

Air and Water Reactions: Soluble in water.
Reactive Group: Alcohols and Polyols
Reactivity Alerts: Polymerizable
CAS: 924-42-5
EINECS: 213-103-2
InChI: InChI=1/C4H7NO2/c1-3(2-6)4(5)7/h6H,1-2H2,(H2,5,7)
InChIKey: CNCOEDDPFOAUMB-UHFFFAOYSA-N
Molecular Formula: C4H7NO2
Molar Mass: 101.1
Density: 1.082g/mL at 20°C
Melting Point: 74-75°C

Boling Point: 277°C(lit.)
Flash Point: 100°C
Water Solubility: <0.1 g/100 mL at 20.5 ºC
Solubility: Chloroform (Slightly), Methanol (Slightly)
Vapor Pressure: 31 hPa (25 °C)
Appearance: Solid
Specific Gravity: 1.074
Color: White to Off-White
BRN: 506646
pKa: 13.25±0.10 (Predicted)
PH: 6.0-7.0 (H2O, 20°C)

Storage Condition: Store at <= 20°C.
Stability: Light Sensitive, Moisture Sensitive
Sensitive: Sensitive to light
Refractive Index: n20/D 1.413
MDL: MFCD00004597
CAS Number: 924-42-5
EC Number: 213-103-2
Molecular Formula: C₄H₇NO₂
Molecular Weight: 101.10 g/mol
Physical and Chemical Properties:
Appearance: White to almost white powder or crystals
Melting Point: 75-79°C

Boiling Point: 277°C
Solubility: Highly soluble in water (1,880 g/L at 20°C)
Molecular Formula / Molecular Weight: C4H7NO2 = 101.11
Physical State (20 deg.C): Solid
Storage Temperature: Refrigerated (0-10°C)
Condition to Avoid: Light Sensitive, Heat Sensitive
CAS RN: 924-42-5
Reaxys Registry Number: 506646
PubChem Substance ID: 87572604
SDBS (AIST Spectral DB): 1581

MDL Number: MFCD00004597
CAS: 924-42-5
Color: White
MDL Number: MFCD00004597
UN Number: 3531
InChI Key: CNCOEDDPFOAUMB-UHFFFAOYSA-N
IUPAC Name: N-(hydroxymethyl)prop-2-enamide
PubChem CID: 13543
Formula Weight: 101.11
Physical Form: Crystalline Powder
Melting Point: 76°C

Molecular Formula: C4H7NO2
SMILES: C=CC(=O)NCO
Molecular Weight (g/mol): 101.105
ChEBI: CHEBI:82492
Percent Purity: ≥98.0% (T)
Chemical Name or Material: N-(Hydroxymethyl)acrylamide
CBNumber: CB3182194
Molecular Formula: C4H7NO2
Molecular Weight: 101.1
MDL Number: MFCD00004597
MOL File: 924-42-5.mol

FIRST AID MEASURES of N-METHYLOL ACRYLAMIDE:
-Description of first-aid measures
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation: 
Fresh air.
*In case of skin contact: 
Take off immediately all contaminated clothing. 
Rinse skin with
water/ shower.
*In case of eye contact:
After eye contact: 
Rinse out with plenty of water. 
Call in ophthalmologist. 
Remove contact lenses.
*If swallowed:
After swallowing: 
Immediately make victim drink water (two glasses at most). 
Consult a physician.
-Indication of any immediate medical attention and special treatment needed.
No data available

ACCIDENTAL RELEASE MEASURES of N-METHYLOL ACRYLAMIDE:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains. 
Collect, bind, and pump off spills. 
Observe possible material restrictions. 
Take up dry. 
Dispose of properly. 
Clean up affected area.

FIRE FIGHTING MEASURES of N-METHYLOL ACRYLAMIDE:
-Extinguishing media:
*Suitable extinguishing media:
Carbon dioxide (CO2) 
Foam 
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.

EXPOSURE CONTROLS/PERSONAL PROTECTION of N-METHYLOL ACRYLAMIDE:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection. 
Safety glasses
*Body Protection:
protective clothing
*Respiratory protection:
Recommended Filter type: Filter A 
-Control of environmental exposure:
Do not let product enter drains.

HANDLING and STORAGE of N-METHYLOL ACRYLAMIDE:
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed. 
Dry.

STABILITY and REACTIVITY of N-METHYLOL ACRYLAMIDE:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .
-Possibility of hazardous reactions:
No data available


 

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