PRODUCTS

N-METHYLOLACRYLAMIDE

N-Methylolacrylamide is used for the manufacture of: chemicals and textile, leather or fur.
N-Methylolacrylamide is used as a crosslinker or functional monomer in water treatment applications.
N-Methylolacrylamide is used in the following areas: agriculture, forestry and fishing and formulation of mixtures and/or re-packaging.

CAS Number: 924-42-5
EC Number: 213-103-2
MDL Number: MFCD00004597
IUPAC Name: N-(hydroxymethyl)prop-2-enamide
Molecular formula: C4H7NO2

SYNONYMS:
NMA, N-Methylolacrylamide, Acrylamide methylol derivative, Crosslinking monomer, Methanol-stabilized NMA, Flocculant enhancer, Polymer crosslinker, Functional acrylamide derivative, N-(hydroxymethyl)prop-2-enamide, N-(Hydroxymethyl)acrylamide, n-Methylolacrylamide, METHYLOLACRYLAMIDE 45%, MLAM 48%, Flocryl NMA 48, N-MAM 60 S (200), AEROTEX NMA LF, NMA monomer 48 % in water, N-Methylolacrylamide 48 (NMA 48), N-Methylolacrylamide, N-(Hydroxymethyl)acrylamide, NCI-C60333, N-MAM, NM-AMD, N-Methanolacrylamide, N-Methyloacrylamide, 2-Propenamide, N-(hydroxymethyl)-, Acrylamide, N-(hydroxymethyl)-, Methylolacrylamide, Monomethylolacrylamide, Monomethylolacrylamide NMA, N-(Hydroxymethyl) acrylamide, N-(Hydroxymethyl)-2-propenamide, NSC 553, Uramine T 80, Yuramin T 80, 2-Propenamide, N-(hydroxymethyl)-, Acrylamide, N-(hydroxymethyl)-, Hydroxymethylacrylamide, Methylolacrylamide, Monomethylolacrylamide, N-(Hydroxymethyl)-2-propenamide, N-(Hydroxymethyl)acrylamide, N-Hydroxymethyl acrylamide, N-Methanolacrylamide, Uramine T 80, Acrylamide, N-(hydroxymethyl)-, Monomethylolacrylamide, N-(Hydroxymethyl)acrylamide, N-Methanolacrylamide, N-Methylolacrylamide, Uramine T 80, Yuramin T 80, Methylolacrylamide, N-(Hydroxymethyl)-2-propenamide, NCI-C60333, N-Methyloacrylamide, NM-AMD, NSC 553, N-MAM, Acrylamide, N-(hydroxymethyl)- (6CI,8CI), N-(Hydroxymethyl)-2-propenamide, Cylink NMA, MH 100, MH 100 (amide), Monomethylolacrylamide, N-(Hydroxymethyl)acrylamide, N-MAM, N-MAM P, N-Methanolacrylamide, N-Methylolacrylamide, N-NBM, NMA 60, NSC 553, Rocagil BT, U-Ramin T, 80 METHYLOLACRYLAMIDE, n-(hydroxymethyl)-2-propenamide, N-(HYDROXYMETHYL)ACRYLAMIDE, N-METHYLOLACRYLAMIDE, 2-Propenamide,N-(hydroxymethyl)-, Acrylamide, N-(hydroxymethyl)-, Monomethylolacrylamide, n-(hydroxymethyl)-2-propenamid, n-(hydroxymethyl)-acrylamid, NCI-C60333, NM-AMD, N-Methanolacrylamide, N-Methyloacrylamide, n-methylolacrylamide(48%inwater), Uramine T 80, uraminet80, Yuramin T 80, Methylolacrylamidesolution, N-MAN, N-(HYDROXYMETHYL)ACRYLAMIDE SOLUTION, ST AB., ~48% IN H2O, 2-Propenamide,N-(hydroxymethyl)-, Acrylamide,N-(hydroxymethyl)-, N-(Hydroxymethyl)-2-propenamide, N-Methylolacrylamide, N-Methanolacrylamide, N-(Hydroxymethyl)acrylamide, Monomethylolacrylamide, NMA 60, MH 100 (amide), MH 100, N-MAM P, U-Ramin T 80, Rocagil BT, N-MAM, NSC 553, N-NBM, Cylink NMA, N-Methylol acrylamide, NMA 48, 90456-67-0, 160278-55-7, 176598-18-8, 194091-52-6, 211862-48-5, 211862-50-9, 2-Propenamide,N-(hydroxymethyl)-, Acrylamide,N-(hydroxymethyl)-, N-(Hydroxymethyl)-2-propenamide, N-Methylolacrylamide, N-Methanolacrylamide, N-(Hydroxymethyl)acrylamide, Monomethylolacrylamide, NMA 60, MH 100 (amide), MH 100, N-MAM P, U-Ramin T 80, Rocagil BT, N-MAM, NSC 553, N-NBM, Cylink NMA, N-Methylol acrylamide, NMA 48, 90456-67-0, 160278-55-7, 176598-18-8, 194091-52-6, 211862-48-5, 211862-50-9, N-(Hydroxymethyl)acrylamide, 2-Propenamide, N-(hydroxymethyl), N-(Hydroxymethyl)-2-propenamide, N-Methylol acrylamide, N-Methanolacrylamide, n-(hydroxymethyl)-2-propenamide, N-methanolacrylamide, Monomethylolacrylamide, NCI-C60333, Uramine T 80, N-(HYDROXYMETHYL)ACRYLAMIDE, N-Methylolacrylamide, 924-42-5, Methylolacrylamide, N-Methylol Acrylamide, N-Methanolacrylamide, Monomethylolacrylamide, 2-Propenamide, N-(hydroxymethyl)-, N-Hydroxymethyl acrylamide, Acrylamide, N-(hydroxymethyl)-, Uramine T 80, N-(hydroxymethyl)prop-2-enamide, N-(Hydroxymethyl)-2-propenamide, Hydroxymethylacrylamide, N-MAM, N-Methyloacrylamide, NCI-C60333, Yuramin T 80, CCRIS 2380, NM-AMD, HSDB 4361, NSC 553, EINECS 213-103-2, UNII-W8W68JL80Q, BRN 0506646, AI3-25447, NSC-553, METHYLOLACRYLAMIDE, N-, W8W68JL80Q, DTXSID3020885, CHEBI:82492, EC 213-103-2, N-METHYLOLACRYLAMIDE [IARC], MFCD00004597, N-(HYDROXYMETHYL)ACRYLAMIDE [HSDB], N-METHYLOLACRYLAMIDE (IARC), N-hydroxymethylacrylamide, NMethanolacrylamide, ROCAGIL BT, NHydroxymethyl acrylamide, N(Hydroxymethyl)acrylamide, N-MAM P, N(Hydroxymethyl)2propenamide, Acrylamide, N(hydroxymethyl), N-(hydroxymethyl) acrylamide, SCHEMBL25806, U-RAMIN T 80, DTXCID90885, 2Propenamide, N(hydroxymethyl), MH 100 (AMIDE), NMA 60, NSC553, CHEMBL1892361, N-(Hydroxymethyl)acrylamide 100 microg/mL in Acetonitrile, MH 100, AKOS006222324, CS-W013710, NCGC00163845-01, NCGC00163845-02, BS-17859, M0574, NS00008229, C19456, E78933, EN300-7474805, W-100289, Q26840808, uraminet80, Yuramin T 80, METHYLOLACRYLAMIDE, N-METHYLOLACRYLAMIDE, N-Methylol acrylamide, Methylolacrylamidesolution, N-(HYDROXYMETHYL)ACRYLAMIDE, N-(Hydroxymethyl)acrylamide, n-(hydroxymethyl)-2-propenamide

N-Methylolacrylamide because of its molecular structure contains two reactive groups, a polymerizable double bond and a condensable methylol
Group, N-Methylolacrylamide therefore has the characteristics of a crosslinking agent monomer.
The earliest synthetic method was to react acrylamide with formaldehyde to obtain crystalline N-Methylolacrylamide.

For example, foreign scholars use paraformaldehyde and acrylamide crystals, trichloroethylene as solvent, and metal sodium colloid as catalyst to produce N-Methylolacrylamide.
After the reaction is finished, the system naturally divides into two phases.

When the temperature is lowered to room temperature, N-Methylolacrylamide precipitates in a large amount, and N-Methylolacrylamideis obtained, but the obtained product needs to be recrystallized with acetone or ethyl acetate.
N-Methylolacrylamideis registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 1 000 to < 10 000 tonnes per annum.

N-Methylolacrylamide is a colorless or yellow liquid.
N-Methylolacrylamide is White solid.
N-Methylolacrylamide is a versatile and widely used chemical compound in various industries.

N-Methylolacrylamide is a monomer that possesses unique crosslinking properties, making it valuable in different applications.
N-Methylolacrylamide is a white solid
N-Methylolacrylamide appears as a colorless or yellow aqueous solution.

N-Methylolacrylamide appears as a colorless or yellow aqueous solution.
N-Methylolacrylamide is a secondary carboxamide.
N-Methylolacrylamide is a self-bred active monomer.

In the molecular structure, N-Methylolacrylamide has a dual and active functional group conjugated with hydroxyl groups.
N-Methylolacrylamide is very soluble in water and alcohol, and is hardly soluble in chloroform and tetrachloride.
Carbon, N-Methylolacrylamide is easy to self-polymerize and cross-link into insoluble resin in humid air, especially under acidic conditions.

N-Methylolacrylamide is an ideal raw material for a wide variety of applications.
N-Methylolacrylamide is especially suitable for the preparation of latex binders and of cross-linkable emulsion polymers used in.

N-Methylolacrylamide is used Adhesives, Antistatic agents, Chromatographic materials, Catalysts, Impregnation of non-woven fabrics, Inks, Paints, Paper coatings, Pasting agents, Plastics, Rubbers, Soil grouting systems, Textile finishes, Thermoplastics resins.

When properly copolymerised, N-Methylolacrylamide forms latices which have low viscosity and excellent shelf stability.
When the films, formed from these lattices, are cured, they develop excellent water resistance, organic solvent resistance, adhesion at
high humidity and flexibility.

N-Methylolacrylamide is a reactive monomer.
As with other such monomers, N-Methylolacrylamide must be stabilized to prevent polymerisation during shipping and storage.

N-Methylolacrylamide can be safely handled if inhibited with cupric ions and oxygen, and if temperature, pH, and contamination are controlled.
Air is usually an adequate source of oxygen.

USES and APPLICATIONS of N-METHYLOLACRYLAMIDE:
N-Methylolacrylamide molecule has double bond conjugated with carbonyl and reactive hydroxymethyl, it is a widely used cross-linking monomer for fiber modification, resin processing, adhesives and paper, leather, metal surface treatment agents, but also for soil amendments.

N-Methylolacrylamide can be used as crosslinking agent, widely used in fiber modification resin, processing dye, plastic adhesive, soil stabilizer, etc.
Organic synthetic monomer, N-Methylolacrylamide, can be used to prepare a variety of copolymers.

N-Methylolacrylamide has two active groups in its molecular structure, which are polymerizable double bonds and condensable methylol groups, therefore, it has the characteristics of crosslinking agent monomer and is widely used in the fields of fiber modification, resin processing, coatings, plastics, adhesives, oil field additives and soil amendments.

In addition, N-Methylolacrylamide can also be polymerized with a variety of monomers in an aqueous system to prepare a polymer with excellent performance, which is a fine chemical widely used at present.
Foreign research and application of this technology is relatively mature, the domestic application is still very limited, many applications still need further research and development, N-Methylolacrylamide can also play a greater potential and value.

When the temperature is lowered to room temperature, N-Methylolacrylamide precipitates in a large amount, and N-Methylolacrylamide is obtained, but the obtained product needs to be recrystallized with acetone or ethyl acetate.
N-Methylolacrylamide is used in formulation or re-packing, at industrial sites and in manufacturing.

Release to the environment of N-Methylolacrylamide can occur from industrial use: formulation of mixtures.
N-Methylolacrylamide is used in the following products: polymers.
N-Methylolacrylamide has an industrial use resulting in manufacture of another substance (use of intermediates).

N-Methylolacrylamide is used in the following areas: agriculture, forestry and fishing and formulation of mixtures and/or re-packaging.
N-Methylolacrylamide is used for the manufacture of: chemicals and textile, leather or fur.
Release to the environment of N-Methylolacrylamide can occur from industrial use: as an intermediate step in further manufacturing of another substance (use of intermediates), for thermoplastic manufacture and as processing aid.

Release to the environment of N-Methylolacrylamide can occur from industrial use: manufacturing of the substance.
N-Methylolacrylamide is used as a crosslinker or functional monomer in water treatment applications.
N-Methylolacrylamide enhances the performance of flocculants in industrial and municipal wastewater treatment.

N-Methylolacrylamide is applied in paper manufacturing to improve retention and drainage.
N-Methylolacrylamide is used in adhesives, coatings, and textiles for crosslinking purposes.
This versatile compound, N-Methylolacrylamide, finds applications in the production of adhesives, coatings, and textiles, where its cross linking capabilities play a crucial role in improving product performance.

N-Methylolacrylamide is used Textile Industry, Paper Industry, Coatings and Paints, Adhesives, Personal Care and Cosmetics, and Polymer Industry.
N-Methylolacrylamide is used in adhesives, binders, surface coatings, and resins.
N-Methylolacrylamide is used as a starch modifier.

N-Methylolacrylamide uses and applications include: Starch modifier; reactive comonomer for vinyl acetate, SB resins.
Suggested storage of N-Methylolacrylamide: Light-sensitive
The Applications of N-Methylolacrylamide rabge from adhesives and binders in papermaking,textile,and non-wovens to a variety of surface coating and resin for varnishes,films and sizing agents.

N-Methylolacrylamide can be used as a cross-linking agent, widely used in fiber modified resin, processing dyes, plastic adhesives, soil stabilizers, etc
N-Methylolacrylamide is used chemical intermediate, reactive comonomer; production of polymers for coatings, varnishes, and adhesion; crease resistance in cotton material.

PHYSICAL AND CHEMICAL PROPERTIES OF N-METHYLOLACRYLAMIDE:
N-Methylolacrylamide is character white powder, soluble in water or hydrophilic solvent, but insoluble in hydrocarbon halogenated hydrocarbon and other solvents, unstable in humid air or water, easy polymerization, when heated in the presence of acid in aqueous solution, it will rapidly polymerize into insoluble resin

PROPERTIES OF N-METHYLOLACRYLAMIDE:
*strong crosslink bonds in polymers
*resulting in enhanced adhesion
*mechanical strength
*durability of the final products

APPLIATION AREAS OF N-METHYLOLACRYLAMIDE:
*Polymerization
*Adhesives and Binders
*Water Treatment
*Textile Industry
*Personal Care Products
*Crosslinking Agent

BENEFITS OF N-METHYLOLACRYLAMIDE:
*N-Methylolacrylamide improves flocculation efficiency in wastewater and industrial applications.
*N-Methylolacrylamide enhances the mechanical strength and durability of treated products.
*Versatile across a range of applications, including adhesives and coatings.

PRODUCTION METHOD OF N-METHYLOLACRYLAMIDE:
under weak alkaline conditions, acrylamide is prepared by reacting with 37% formaldehyde in water.

PREPARATION OF N-METHYLOLACRYLAMIDE:
(1), acrylamide is added to the reaction kettle filled with solvent acetone, raise the temperature to 42~45 ℃;
(2), add the catalyst sodium methoxide, adjust the pH value of the reaction solution to 8.88;
(3), add formaldehyde, adjust the pH value of the reaction solution to 8.5, the reaction was carried out at a constant temperature for 1 hour;
(4) phthalic acid was added to adjust the pH of the reaction solution to 7.2;
(5) the reaction solution was cooled, crystallized and filtered to obtain the finished N-Methylolacrylamide.

REACTIVITY OF N-METHYLOLACRYLAMIDE:
N-Methylolacrylamide is supplied as a 48% solution in water.
N-Methylolacrylamide's reactivity is due to the presence in the molecule of both an unsaturated vinyl group and a hydroxymethyl group which can be reacted separately and/or independently simply by varying the reaction conditions.

*Reaction of the vinyl group
N-Methylolacrylamide can be used in the preparation of a wide range of polymers and copolymers.
The main is free radical polymerisation with other vinyl monomers such as acrylonitrile, acrylamide, acrylic and methacrylic
esters, vinyl chloride, and styrene which leaves the hydroxymethyl group available.

Additionally, the double bond in N-Methylolacrylamide can be reacted with both halogens and alcohols under alkaline conditions and
with thiol in the presence of alcoholate.

*Reaction of the hydroxymethyl group
The hydroxymethyl group has a tendency to undergo condensation or substitution reactions.
N-Methylolacrylamide containing polymers can be crosslinked either with themselves or with other reactive monomers, by heating and/or by the presence of an acid catalyst

STORAGE OF N-METHYLOLACRYLAMIDE:
tanks should include temperature monitoring and an independent temperature alarm system for early detection of polymerisation.

OXYGEN
Dissolved oxygen is necessary to inhibit polymerisation of N-Methylolacrylamide.
The dissolved oxygen level together with the air present is quite adequate stabilization during storage.
Controlled intermittent air flow or continuous sparging at 0.09 Nm3/hr per m3 of N-Methylolacrylamide (0.2 SCFM per thousand gallons) is sufficient for inhibition purposes.

TEMPERATURE
N-Methylolacrylamide should be controlled to between 0°C (32°F) and 30°C (86°F).
At temperatures below –10°C (14°F), N-methylolacrylamide will crystallize and separate from the solution.
Warming the product to 0°C (32°F) will re-dissolve the crystals.

In storage tanks, railcars and tank trucks, introduce tempered water
(maximum temperature 40°C (104°F)) into the heating coils.
Packaged material should be moved to a warm environment until crystals are redissolved.

Do not apply steam to heating coils or direct heat to packaged material.
Hot spots must be avoided.

An air sparge should be employed, and agitation will increase the rate of dissolution.
At temperatures above 50°C (120°F), polymerisation could be initiated over time.

*pH
As supplied, N-Methylolacrylamide has a pH of 6.0 to 7.0.
Any modification of the pH, above or below these specifications can reduce the stability significantly.
Periodic monitoring of pH is recommended and, if necessary,
the pH should be adjusted with either dilute sodium hydroxide or dilute sulfuric acid, or any other appropriate acids or bases.

*CONTAMINATION
As with other reactive monomers, contamination of N-Methylolacrylamide solutions with known initiators such as peroxides and azo compounds must be avoided.
Strong oxidizing agents such as persulfates can also initiate polymerisation of N-Methylolacrylamide.
Reducing agents such as sulfites and bisulfites under certain conditions, can cause polymerisation.

*EFFECT OF LIGHT
N-Methylolacrylamide is UV (ultra violet) sensitive.
Therefore, N-Methylolacrylamide should not be exposed to direct sunlight or polymerisation may occur.

OPERATIONAL NOTES OF N-METHYLOLACRYLAMIDE:
*Storage
N-Methylolacrylamide is a reactive monomer which can polymerise spontaneously with the possible generation of heat and pressure, in the presence of certain contaminants, or as a result of improper handling or storage.

As with any toxic or reactive material, thorough training of all employees is imperative.
Knowledge of the toxicological properties, strict provisions for safe handling procedures and appropriate storage and handling
practices are necessary for ensuring the safe use of this monomer.

It is recommended that N-Methylolacrylamide be used before six months after the date of manufacturing.
Do not sparge or blanket

N-Methylolacrylamide with an inert gas.
Shelf life may be reduced if these storage conditions are not observed.

PHYSICAL and CHEMICAL PROPERTIES of N-METHYLOLACRYLAMIDE:
Chemical Nature: Polymer or monomer-based product, typically containing N-methylolacrylamide.
Appearance: Clear or slightly cloudy liquid or solid, depending on formulation.
Molecular Formula (NMA): C4H7NO2
Molecular Weight (NMA): 101.1 g/mol
Density: Approx. 1.1 g/cm³ (may vary with composition).
Solubility: Soluble in water.
Thermal Stability: Decomposes at elevated temperatures.
pH: Dependent on formulation, typically 4–8.
Appearance: Clear to slightly yellowish solution
Molecular weight (g.mol-1): 101.10
Active content (%): 48.0
Refractive index (%): 1.412

Heat of polymerisation (Kcal/mole): 20.0
Specific gravity at 25°C: 1.08
Cristallization point (°C): -10
Molecular Weight: 101.10 g/mol
XLogP3-AA: -0.5
Hydrogen Bond Donor Count: 2
Hydrogen Bond Acceptor Count: 2
Rotatable Bond Count: 2
Exact Mass: 101.047678466 g/mol
Monoisotopic Mass: 101.047678466 g/mol
Topological Polar Surface Area: 49.3Å²

Heavy Atom Count: 7
Formal Charge: 0
Complexity: 79.8
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes

Product Name: N-Methylolacrylamide
CAS No.: 924-42-5
Molecular Formula: C4H7NO2
InChIKeys: InChIKey=CNCOEDDPFOAUMB-UHFFFAOYSA-N
Molecular Weight: 101.10400
Exact Mass: 101.10
EC Number: 213-103-2
UNII: W8W68JL80Q
ICSC Number: 1637
NSC Number: 553
PSA: 49.33000
XLogP3: -0.37070
Appearance: N-methylolacrylamide appears as a colorless or
yellow aqueous solution.

Density: 1.074
Melting Point: 74.5 °C
Boiling Point: 318.1ºC at 760mmHg
Flash Point: 146.2ºC
Refractive Index: n20/D 1.413
Water Solubility: Solubility in water, g/100ml at 20°C: 188
Storage Conditions: Refrigerator
Vapor Pressure: Vapour pressure, Pa at 25°C: 0.03 (negligible)
Air and Water Reactions: Soluble in water.
Reactive Group: Alcohols and Polyols
Reactivity Alerts: Polymerizable

Molecular weight (g.mol-1 ): 101.10
Active content (%): 48.0
Refractive index (%): 1.412
Heat of polymerisation (Kcal/mole): 20.0
Specific gravity at 25°C: 1.08
Cristallization point (°C): -10
Product Number: M0574
Purity / Analysis Method: >98.0%(T)
Molecular Formula / Molecular Weight: C4H7NO2 = 101.11
Physical State (20 deg.C): Solid
Storage Temperature: 0-10°C

Condition to Avoid: Light Sensitive,Heat Sensitive
CAS RN: 924-42-5
Reaxys Registry Number: 506646
PubChem Substance ID: 87572604
SDBS (AIST Spectral DB): 1581
MDL Number: MFCD00004597
Physical state: liquid
Color: colorless, yellow
Odor: formaldehyde-like
Melting point/freezing point:
Melting point/range: -10 °C
Initial boiling point and boiling range: No data available
Flammability (solid, gas): No data available

Upper/lower flammability or explosive limits: No data available
Flash point: > 93 °C - closed cup
Autoignition temperature: Not applicable
Decomposition temperature: No data available
pH: 6,0 - 7,0
Viscosity
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Water solubility at 20 °C soluble
Partition coefficient: n-octanol/water: No data available
Vapor pressure: 31,68 hPa at 25 °C

Density: 1,074 g/cm3 at 25 °C
Relative density: No data available
Relative vapor density: No data available
Particle characteristics: No data available
Explosive properties: Not classified as explosive.
Oxidizing properties: none
Other safety information: No data available
Solubility: 1880 g/l (20 °C)
Melting Point: -10 °C
Boiling Point: 100 °C (1013 hPa)
Vapor Pressure: 31 hPa (25 °C)
Flash Point: 93 °C
Density: 1.08 g/cm3 (20 °C)
pH: 6.0 - 7.0 (H2O, 20 °C)

Assay (ex N): 48 - 50%
Identity (IR): Passes test
Storage temperature: 15 °C
Molecular Weight: 101.10400
Exact Mass: 101.10
EC Number: 213-103-2
UNII: W8W68JL80Q
ICSC Number: 1637
NSC Number: 553
DSSTox ID: DTXSID3020885
HScode: 2924199090
PSA: 49.33000
XLogP3: -0.37070

Appearance: N-methylolacrylamide appears as a colorless or
yellow aqueous solution.
Density: 1.074
Melting Point: 74.5 °C
Boiling Point: 318.1ºC at 760mmHg
Flash Point: 146.2ºC
Refractive Index: n20/D 1.413
Water Solubility: Solubility in water, g/100ml at 20°C: 188
Storage Conditions: Refrigerator
Vapor Pressure: Vapour pressure, Pa at 25°C: 0.03 (negligible)
Air and Water Reactions: Soluble in water.

Reactive Group: Alcohols and Polyols
Reactivity Alerts: Polymerizable
CAS: 924-42-5
EINECS: 213-103-2
InChI: InChI=1/C4H7NO2/c1-3(2-6)4(5)7/h6H,1-2H2,(H2,5,7)
InChIKey: CNCOEDDPFOAUMB-UHFFFAOYSA-N
Molecular Formula: C4H7NO2
Molar Mass: 101.1
Density: 1.082g/mL at 20°C
Melting Point: 74-75°C
Boling Point: 277°C(lit.)
Flash Point: 100°C
Water Solubility: <0.1 g/100 mL at 20.5 ºC

Solubility: Chloroform (Slightly), Methanol (Slightly)
Vapor Pressure: 31 hPa (25 °C)
Appearance: Solid
Specific Gravity: 1.074
Color: White to Off-White
BRN: 506646
pKa: 13.25±0.10 (Predicted)
PH: 6.0-7.0 (H2O, 20°C)
Storage Condition: Store at <= 20°C.
Stability: Light Sensitive, Moisture Sensitive
Sensitive: Sensitive to light
Refractive Index: n20/D 1.413
MDL: MFCD00004597

FIRST AID MEASURES of N-METHYLOLACRYLAMIDE:
-Description of first-aid measures:
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
Call in physician.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
Consult a physician.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.
*If swallowed:
Give water to drink (two glasses at most).
Seek medical advice immediately.
-Indication of any immediate medical attention and special treatment needed:
No data available

ACCIDENTAL RELEASE MEASURES of N-METHYLOLACRYLAMIDE:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions
Take up carefully with liquid-absorbent material.
Dispose of properly.
Clean up affected area.

FIRE FIGHTING MEASURES of N-METHYLOLACRYLAMIDE:
-Extinguishing media:
*Suitable extinguishing media:
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Suppress (knock down) gases/vapors/mists with a water spray jet.
Prevent fire extinguishing water from contaminating surface water or the ground water system.

EXPOSURE CONTROLS/PERSONAL PROTECTION of N-METHYLOLACRYLAMIDE:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Safety glasses
*Skin protection:
required
*Body Protection:
protective clothing
*Respiratory protection:
Recommended Filter type: Filter type ABEK
-Control of environmental exposure:
Do not let product enter drains.

HANDLING and STORAGE of N-METHYLOLACRYLAMIDE:
-Precautions for safe handling:
*Advice on safe handling:
Work under hood.
*Hygiene measures:
Immediately change contaminated clothing.
Apply preventive skin protection.
Wash hands and face after working with substance.
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Keep in a well-ventilated place.
Keep locked up or in an area accessible only to qualified or authorized persons.
Light sensitive.
*Storage class:
Storage class (TRGS 510): 6.1D:
Non-combustible

STABILITY and REACTIVITY of N-METHYLOLACRYLAMIDE:
-Reactivity:
No data available
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .
-Conditions to avoid:
no information available