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PERACETIC ACID

CAS NUMBER: 79-21-0

MOLECULAR FORMULA: CH3CO3H

MOLECULAR WEIGHT: 76.05

 

Peracetic acid is a mixture of acetic acid (CH3COOH) and hydrogen peroxide (H2O2) in a watery solution. 
Peracetic acid is a bright, colorless liquid that has a piercing odor and a low pH value (2,8). Peracetic acid is produced by a reaction between hydrogen peroxide and acetic acid.

Peracetic Acid is a strong oxidizing compound.
When reacting, it releases water, oxygen and acetic acid which is ideal for cleaning applications for health area, food and beverage, or agriculture. 

Peracetic acid leaves no toxic residue and could be used for applications without rising. 
Excellent performance as bleaching agent at low temperature. 

Used as an alternative to chlorinated products as a bleaching agent. 
Peracetic acid avoids the presence of chlorinated pollutants in the waste effluents.

Peracetic acid is a colorless liquid with a strong, pungent acrid odor. 
Used as a bactericide and fungicide, especially in food processing; as a reagent in making caprolactam and glycerol; as an oxidant for preparing epoxy compounds; as a bleaching agent; a sterilizing agent; and as a polymerization catalyst for polyester resins. 

Peracetic acid is a peroxy acid that is acetic acid in which the OH group is substituted by a hydroperoxy group. 
Peracetic acid is a versatile oxidising agent that is used as a disinfectant. 

Peracetic acid has a role as an oxidising agent and a disinfectant. 
Peracetic acid derives from an acetic acid.

Peracetic acid, is an organic compound with the formula CH3CO3H. 
Peracetic acid is a colorless liquid with a characteristic acrid odor reminiscent of acetic acid. 

Peracetic acid can be highly corrosive.
Peracetic acid is a weaker acid than the parent acetic acid, with a pKa of 8.2.

As an alternative, Peracetic acid can be used to generate a solution of the acid with lower water content.
Peracetic acid is generated in situ by some laundry detergents. 

Peracetic acid involves the reaction of tetraacetylethylenediamine (TAED) in the presence of an alkaline hydrogen peroxide solution. 
The peracetic acid is a more effective bleaching agent than hydrogen peroxide itself.

Peracetic acid is also formed naturally in the environment through a series of photochemical reactions involving formaldehyde and photo-oxidant radicals.
Peracetic acid is always sold in solution as a mixture with acetic acid and hydrogen peroxide to maintain its stability. 

The concentration of the acid as the active ingredient can vary.
Peracetic acid is a highly biocidal oxidizer that maintains its efficacy in the presence of organic soil. 

Peracetic acid removes surface contaminants (primarily protein) on endoscopic tubing.
An automated machine using peracetic acid to sterilize medical, surgical, and dental instruments chemically (e.g., endoscopes, arthroscopes) was introduced in 1988. 

This microprocessor-controlled, low-temperature sterilization method is commonly used in the United States.
Peracetic acid and an anticorrosive agent are supplied in a single-dose container. 

The container is punctured at the time of use, immediately prior to closing the lid and initiating the cycle. 
The concentrated peracetic acid is diluted to 0.2% with filtered water (0.2 mm) at a temperature of approximately 50°C. 

The diluted peracetic acid is circulated within the chamber of the machine and pumped through the channels of the endoscope for 12 minutes, decontaminating exterior surfaces, lumens, and accessories. 
Interchangeable trays are available to permit the processing of up to three rigid endoscopes or one flexible endoscope. 

Connectors are available for most types of flexible endoscopes for the irrigation of all channels by directed flow. 
Rigid endoscopes are placed within a lidded container, and the sterilant fills the lumens either by immersion in the circulating sterilant or by use of channel connectors to direct flow into the lumen(s).

The peracetic acid is discarded via the sewer and the instrument rinsed four times with filtered water.
Peracetic acid, also known as peroxyacetic acid or PAA, is an organic chemical compound used in numerous applications, including chemical disinfectant in healthcare, sanitizer in the food industry, and disinfectant during water treatment. 

Peracetic acid has also previously been used during the manufacture of chemical intermediates for pharmaceuticals. 
Produced by reacting acetic acid and hydrogen peroxide with an acid catalyst, peracetic acid is always sold in stabilized solutions containing acetic acid, hydrogen peroxide, and water. For the food and healthcare industries, peracetic acid is typically sold in concentrates of 1 to 5 percent and is diluted before use.

Many users know peracetic acid to be versatile and effective, and professionals with environmental responsibilities consider Peracetic acid to be environmentally friendly due to Peracetic acids decomposition products, which include acetic acid, oxygen, and water. 
However, industrial hygienists recognize that Peracetic acid is also highly corrosive and a strong oxidizer, and exposure to peracetic acid can severely irritate the eyes, skin, and respiratory system.

Peracetic acid is an organic acid generated by reacting acetic acid and hydrogen peroxide. 
Several commercial formulations are available. 

In solution, peracetic acid dissolves and forms back acetic acid and hydrogen peroxide. 
Peracetic acid is used at concentrations of 150–200 ppm on various food-contact surfaces. 

Peracetic acid is efficient in removing biofilms and works well at colder temperatures. 
Peracetic acid is believed to function in a similar fashion as other oxidizing agents by reacting with cellular proteins and enzymes. 

In a recent study, peracetic acid at 30 mg l−1 was shown to be more efficient than 250 mg l−1 of sodium hypochlorite at removing biofilm cells of S. aureus from stainless steel and polypropylene surfaces. 
Another study suggests that peracetic acid sanitizers may have some sporocidal activity against suspended bacterial spores in an aqueous solution on stainless steel surfaces. 

However, sporocidal activity was minimal against spores adhering to stainless steel without the presence of an aqueous suspension.
Peracetic acid (C2H4O3) is a mixture of acetic acid (CH3COOH) and hydrogen peroxide (H2O2) in a watery solution. 

Peracetic acid is a bright, colorless liquid that has a piercing odor and a low pH value (2,8).
Peracetic acid can also be produced by oxidation of acethaldehyde. Peracetic acid is usually produced in concentrations of 5-15%.

When peracetic acid dissolves in water, Peracetic acid disintegrates to hydrogen peroxide and acetic acid, which will fall apart to water, oxygen and carbon dioxide. 
Peracetic acid degradation products are non-toxic and can easily dissolve in water.

Peracetic acid is a very powerful oxidant; the oxidation potential outranges that of chlorine and chlorine dioxide.
Peracetic acid can be applied for the deactivation of a large variety of pathogenic microorganisms. 

Peracetic acid also deactivates viruses and spores. 
Peracetic acid activity is hardly influenced by organic compounds that are present in the water.

However, pH and temperature do influence peractetic acid activity. 
Peracetic acid is more effective when the pH value is 7 than at a pH range between 8 and 9. 

At a temperature of 15 °C and a pH value of 7, five times more peracetic acid is required to affectively deactivate pathogens than at a pH value of 7 and a temperature of 35 °C.
Peracetic acid is an oxidant that is attracting greater interest in research and applications.

The applications of PAA have occurred in various industries, including food processing, medical, chemical.
Peracetic Acid is a disinfectant chemical used by hospitals and the food processing industry. 

Peracetic acid is very effective for killing microscopic organisms hiding in and on surfaces. 
Within minutes, Peracetic acid can wipe out bacteria, fungi, yeasts, spores and viruses.

Peroxyacetic Acid is a colorless liquid which is transported and stored in diluted solutions to prevent explosions. 
Peracetic acid is an Organic Peroxide used in bleaching textiles, paper, oils, waxes and starch, as a bactericide and fungicide in food processing, and as a catalyst for epoxy resins. 


Peracetic acid is a non-rinse sterilant, the product can be used in any application where the degree of soiling is light and a disinfecting action is required after cleaning.
Peracetic acid is a terminal disinfectant and provided that items are well drained after treatment, solutions need not be rinsed off. 
The product decomposes to acetic acid and oxygen, neither of which in such small quantities will have any adverse effects.

 

 

USES:

Peracetic acid as an antimicrobial in 1985 for indoor use on hard surfaces. Use sites include agricultural premises, food establishments, medical facilities, and home bathrooms. 
Peracetic acid is also registered for use in dairy and cheese processing plants, on food processing equipment, and in pasteurizers in breweries, wineries, and beverage plants.

Peracetic acid is also applied for the disinfection of medical supplies, to prevent biofilm formation in pulp industries, and as a water purifier and disinfectant. 
Peracetic acid can be used as a cooling tower water disinfectant, where Peracetic acid prevents biofilm formation and effectively controls Legionella bacteria. 

A trade name for peracetic acid as an antimicrobial is Nu-Cidex.
In the European Union, Peroxyacetic acid was reported by the EFSA after submission in 2013 by the US Department of Agriculture.

Decontamination kits for cleaning fentanyl analogues from surfaces (as used by many police forces, amongst others) often contain solid peracetyl borate, which mixes with water to produce peracetic acid.
Although less active than more acidic peracids (e.g., m-CPBA), peracetic acid in various forms is used for the epoxidation of various alkenes. 

Useful application are for unsaturated fats, synthetic and natural rubbers, and some natural products such as pinene. 
A variety of factors affect the amount of free acid or sulfuric acid.

 


-Small items can be left to soak overnight in a steeping tank using Peracetic Acid 5% diluted, 3-10mls PAA per litre of water.

-Beer mains and hoses may be filled after cleaning with a diluted solution of PAA, 3-5mls PAA per litre of water and left for several hours before draining off.

-Large vessels and plant are best treated by spray-ball using a dilute solution of PAA, 10-20ml in a litre of water. 

-Alternatively a fog gun may be used but particular attention must be paid to safety precautions if a fog spray is used, to avoid eye or skin contact or inhalation.

 

 


APPLICATIONS:

Peracetic acid is used mainly in the food industry, where it is applied as a cleanser and as a disinfectant. Since the early 1950’s, acetic acid was applied for bacteria and fungi removal from fruits and vegetables. 
Peracetic acid was also used for the disinfection of recicled rinsing water for foodstuffs.

Nowadays peracetic acid is applied for the disinfection of medical supplies and to prevent bio film formation in pulp industries. 
Peracetic acid can be applied during water purification as a disinfectant and for plumming disinfection.
Peracetic acid is suitable for cooling tower water disinfection; it affectively prevents bio film formation and controls Legionella bacteria.

 

 


BENEFITS:


-Fast acting

-Non-foaming

-Non-tainting

-Non polluting to the environment

-No need to rinse after use

 

 

PROPERTIES:


-Quality Level: 100

-vapor pressure: 20 mmHg ( 25 °C)

-assay: 29.0-35% (by sodium thiosulfate, titration)

-form: liquid

-composition: acetic acid, 40-45%

-reaction suitability: reagent type: oxidant

-concentration: 32 wt. % in dilute acetic acid

-impurities: <6.0% hydrogen peroxide

-refractive index: n20/D 1.3876

-pH: < 1

 

 

SPECIFICATIONS:


-Melting point: -44 °C

-Boiling point: 105 °C

-density: 1.19 g/mL at 20 °C

-vapor pressure: Low

-refractive index: n20/D 1.391

-Fp: 41 °C

-storage temp.: 2-8°C

-pka: 8.2(at 25℃)

-color: Colorless liquid

-Odor: Acrid odor

-Water Solubility: soluble, >=10 g/100 mL at 19 ºC

-Merck: 13,7229

-BRN: 1098464

 

 

CHARACTERISTICS:


Peracetic acid is a very strong oxidizing agent and has stronger oxidation potential than chlorine or chlorine dioxide. 
Liquid, clear, and

colorless with no foaming capability. 
Peracetic acid has a strong pungent acetic acid odor, and the pH is acid (2.8). 
Specific gravity is 1.114 and weighs 9.28 pounds per gallon. Stable upon transport. 

 

 

CHEMICAL PROPERTIES:


-Decomposes at >50°C

-Melting point: 0°C

-Relative density (water = 1): 1.2

-Solubility in water: miscible

-Vapour pressure, kPa at 20°C: 2.6

-Relative vapour density (air = 1): 2.6

-Relative density of the vapour/air-mixture at 20°C (air = 1): 1.04

-Flash point: 40.5°C o.c.

-Auto-ignition temperature: 200°C

 

 


STORAGE:

Fireproof. 
Provision to contain effluent from fire extinguishing. 

Separated from combustible substances and incompatible materials. 
Cool. 

Store only if stabilized. 
Store in an area without drain or sewer access. 

 

 

SYNONYM:

Peroxyacetic acid
Ethaneperoxoic acid
79-21-0
Estosteril
Acetic peroxide
Peroxoacetic acid
Monoperacetic acid
Osbon AC
Acetyl hydroperoxide
Proxitane 4002
Desoxon 1
Ethaneperoxic acid
Hydroperoxide, acetyl
Acide peracetique
Acido peroxiacetico
UNII-I6KPI2E1HD
I6KPI2E1HD
CHEMBL444965
NCGC00166305-01
Caswell No. 644
Acecide
Acide peracetique [French]
Acide peroxyacetique
F50
CCRIS 686
Acide peroxyacetique 
Acido peroxiacetico
Kyselina peroxyoctova
Kyselina peroxyoctova
LCAP
HSDB 1106
EINECS 201-186-8
EPA Pesticide Chemical Code 063201
BRN 1098464
Aceticperoxide
peractic acid
per-acetic acid
Peroxacetic acid
acetic acid oxide
Peroxy acetic acid
AcOOH
Acecide (TN)
ACMC-20egd0
CH3CO2OH

 

 

 

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