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SODIUM BROMIDE

Sodium bromide is a colorless cubic crystal or white granular powder, and belongs to isometric system. 
Sodium bromide is odorless, and has slightly bitter and briny taste but high toxicity. 
Sodium bromide is easily to absorb moisture and caking but without deliquescence. 

CAS Number: 7647-15-6
Molecular Formula: NaBr
Molecular Weight: 102.89
EINECS Number: 231-599-9

Synonyms: Sodium bromide, 7647-15-6, Sedoneural, Bromide salt of sodium, Bromnatrium, Sodium bromide NaBr, Trisodium tribromide, NaBr, Natrum bromatum, Caswell No. 750A, DTXSID3034903, LC1V549NOM, NSC-77384, DTXCID1014903, CHEBI:63004, Bromosodium, RefChem:6232, 231-599-9, Sodium bromide anhydrous, MFCD00003475, CHEMBL1644694, Sanibrom 40, BrNa, HSDB 5039, EINECS 231-599-9, UNII-LC1V549NOM, EC 231-599-9, SCHEMBL21364, SCHEMBL9670690, AKOS024438090, NATRUM BROMATUM HPUS, SODIUM BROMIDE MI, SODIUM BROMIDE HSDB, SODIUM BROMIDE MART, SODIUM BROMIDE USP-RS, SODIUM BROMIDE WHO-DD, SODIUM BROMIDE EP MONOGRAPH, SODIUM BROMIDE USP MONOGRAPH, CAS-7647-15-6, NS00075684, S0546, D02055, Q15768, bromuredesodium;Hydrobromic acid sodium salt;Sedoneural;Sodium bromide (NaBr);sodiumbromide(nabr);BROMIDE STANDARD SOLUTION;BROMIDE ION CHROMATOGRAPHY STANDARD;Bromide salt of sodium

Sodium bromide is slightly soluble in alcohol and easily soluble in water (at 100 °C, the solubility in 100ml water solubility is 121g), its aqueous solution is neutral with electronic conductivity. 
The anhydrous sodium bromide crystal will be precipitated out at 51°C with dihydrate compound forming at temperature lower than 51 °C. 
Sodium bromides bromide ion can be substituted by fluorine, and chlorine. 

Sodium bromide can be oxidized by oxygen and release free bromine; this process is taken advantage of by industry for producing bromine. 
Sodium bromide can have reaction with dilute sulfuric acid to produce hydrogen bromide. However, hydrobromic acid is a strong acid which can’t be produced through the reaction with dilute sulfuric acid and can only made through high-boiling point acid to make low-boiling point acid. 
However, we should avoid to use concentrated sulfuric acid which has strong oxidation effect and thus converting bromine (-1) into bromine element and release reddish-brown gas. 

This method can be used to identify sodium iodide (Heating sodium iodide and concentrated sulfuric acid together will release red-purple gases), Thereby, we can only take the concentrated phosphoric acid together with sodium bromine for heating to produce hydrogen bromine.
Sodium bromide is an inorganic compound with the formula NaBr. 
Sodium bromide is a high-melting white, crystalline solid that resembles sodium chloride. 

Sodium bromide is a widely used source of the bromide ion and has many applications.
In repeated doses it is toxic to humans, leading to bromism, which may include symptoms such as skin rashes, drowsiness, nausea, and hallucinations.
Sodium bromide is an inorganic salt, widely used as a source of bromide ions, reagent, and intermediate in chemical, pharmaceutical, and industrial applications.

Sodium bromides chemical formula is NaBr.
Sodium bromide belongs to the class of alkali metal halides.
Chemically, it consists of sodium ions (Na⁺) and bromide ions (Br⁻).

Sodium bromide forms a simple ionic lattice structure.
This gives it typical properties of ionic salts.
Physically, sodium bromide appears as a white crystalline solid.

Sodium bromide is highly soluble in water and forms clear solutions.
It is odorless and stable under normal conditions.
The compound exhibits neutral behavior in aqueous solution, as it is derived from a strong acid (HBr) and strong base (NaOH).

Sodium bromide does not significantly affect pH.
This makes it suitable for various applications.
Sodium bromide can act as a source of bromide ions in chemical reactions, including substitution and redox processes.

Sodium bromide participates in halogen chemistry.
This supports synthesis applications.
It is chemically stable under normal conditions, but may react with strong oxidizing agents to form bromine.

Sodium bromide should be kept away from oxidizers.
The compound is used in pharmaceuticals, water treatment, and chemical manufacturing.
It plays roles in synthesis and disinfection systems.

Sodium bromide is best described as a stable, water-soluble inorganic halide salt used as a bromide source and chemical intermediate, widely applied in industrial and laboratory processes.
Sodium bromide is widely used for the preparation of other bromides in organic synthesis and other areas. 

Sodium bromide is a source of the bromide nucleophile to convert alkyl chlorides to more reactive alkyl bromides by the Finkelstein reaction: NaBr + RCl → RBr + NaCl (R = alkyl)
Once a large need in photography, but now shrinking, the photosensitive salt silver bromide is prepared using NaBr.

Melting point: 755 °C (lit.)
Boiling point: 1390 °C
Density: 3.203 g/cm³
bulk density: 1750 kg/m³
vapor pressure: 1 mm Hg (806 °C)
refractive index: 1.6412
Flash point: 1390°C
storage temp.: Store at room temperature
solubility: H2O: 1 M at 20 °C, clear, colorless
form: Powder
Specific Gravity: 3.21
color: White
pH: 5.74 (430 g/L, H2O, 22.5℃)
Water Solubility: 905 g/L (20 ºC)
Thermal Conductivity: 2.51 W/(m·K)
λmax: λ: 260 nm Amax: 0.01; λ: 280 nm Amax: 0.01
Sensitive: Hygroscopic
Merck: 14,8594
BRN: 3587179
Dielectric constant: 6.34
Stability: Stable. Incompatible with strong acids. Hygroscopic
InChI: 1S/BrH.Na/h1H;/q;+1/p-1
InChIKey: JHJLBTNAGRQEKS-UHFFFAOYSA-M
SMILES: [Na+].[Br-]
LogP: 0 at 25℃

Sodium bromide occurs in seawater at an average concentration of 0.008%. 
Sodium bromide also is found naturally in some salt deposits. 
Sodium bromide is used in photography for preparing light-sensitive silver bromide emulsions. 

The salt also is used as a bleaching and disinfecting agent for water treatement in swimming pools, health spas, and hot tubs. Other uses are as a catalyst for partial oxidation of hydrocarbons, for increasing density of aqueous drillng fluids for oil wells, as an electrolyte component in sodium-halogen batteries, as a brominating agent in organic synthesis, in preparing bromide salts, and as a laboratory reagent. 
Sodium bromide is used in medicine as a sedative and hypnotic.

Sodium bromide forms a crystalline lattice similar to sodium chloride (NaCl), with a cubic structure.
This arrangement provides high stability.
Sodium bromide is typical of alkali halides.

Sodium bromide exhibits high solubility in water, dissociating completely into Na⁺ and Br⁻ ions.
This makes it an effective electrolyte.
Sodium bromide is widely used in aqueous systems.

Sodium bromide shows strong ionic conductivity in solution, allowing it to carry electrical current.
This is important in electrochemical processes.
Sodium bromide supports industrial applications.

Sodium bromide can participate in redox reactions, where bromide ions may be oxidized to bromine (Br₂).
This occurs in the presence of strong oxidizing agents.
This is relevant in chemical synthesis.

The compound is often used in bromination reactions, serving as a bromide source.
Sodium bromide helps generate reactive bromine species in situ.
This supports organic chemistry.

Sodium bromide has hygroscopic tendencies, meaning it can absorb moisture from the air.
This can affect storage conditions.
It should be kept in sealed containers.

Sodium bromide demonstrates compatibility with many solvents and systems, especially aqueous and polar environments.
Sodium bromide integrates well into formulations.
This increases versatility.

The compound is also used in density control of fluids, as concentrated solutions have high density.
Sodium bromide supports specialized applications.
Sodium bromideis a highly soluble, stable ionic compound with strong electrolyte behavior and reactivity in halogen chemistry, making it valuable in chemical, industrial, and electrochemical applications.

Uses Of Sodium bromide:    
Sodium bromide can be used as raw material in the preparation of liquid photographic film; medically as sedative, the brominating agent in printing and dyeing; it can also be used in synthetic fragrances and other chemicals.
Photographic industry applies it for the preparation of liquid photosensitive film. 
Sodium bromide is medically used for the production of diuretics and sedatives. 

Perfume industry uses it for the production of synthetic fragrances. 
Printing and dyeing industry use it as a brominating agent. 
In addition, it can be also be used for organic synthesis and so on.

Sodium bromide is used for the photographic industry, spices, pharmaceutical and printing industries.
It is used for the reagents for analysis, and can also be used for the synthesis of inorganic and organic compounds and pharmaceutical industry.
Sodium bromide is sued for photographic film, medicines, perfumes, dyes and other industries.

Sodium bromide can be applied to determination of trace cadmium and Manufacturing of bromide. 
Sodium bromide can also be applied to inorganic and organic synthesis, photogravure and pharmaceuticals.

Sodium Bromide is a high-tonnage chemical and one of the most important of the bromide salts (NaBr2). 
High-purity grades are required in the formulation of silver bromide emulsions for photography. 
Sodium bromide, usually in combination with hypochlorites, is used as a bleach, notably for cellulosics. 

The production of sodium bromide simply involves the neutralization of HBr with NaOH or with sodium carbonate or bicarbonate.
Sodium Bromide is an inorganic compoiund used as a catalyst in the photoinduced polymerization of acrylates.

Sodium bromide is widely used in the oil and gas industry as a component of high-density drilling and completion fluids.
Its solutions help control pressure in wells.
This improves operational safety.

In water treatment systems, it serves as a source of bromide ions for disinfectant generation.
Sodium bromide is used to produce bromine-based biocides.
This helps control microbial growth.

Sodium bromide is used in pharmaceutical applications, historically as a sedative and anticonvulsant.
Sodium bromide is still used in some veterinary medicines.
This supports medical use.

In chemical synthesis, it acts as a bromide source and intermediate.
Sodium bromide is used in bromination and other reactions.
This supports organic chemistry processes.

Sodium bromide is applied in photographic chemicals as a component in film processing.
It helps control development reactions.
This supports imaging technologies.

In textile and dye industries, it is used in dyeing and finishing processes.
It helps control reaction conditions.
This improves product quality.

Sodium bromide is used in laboratory and analytical chemistry as a reagent.
Sodium bromide participates in various chemical reactions and tests.
This supports research work.

Sodium bromide is applied in sanitizing systems for swimming pools and spas, where it helps generate bromine disinfectants.
It controls bacteria and algae.
This improves water hygiene.

In industrial cleaning and biocide formulations, it is used as a precursor for active disinfecting agents.
Sodium bromide enhances antimicrobial effectiveness.
Sodium bromide is used wherever bromide ion supply, density control, disinfection, and chemical reactivity are required, especially in oil and gas, water treatment, pharmaceuticals, and chemical industries.

Safety Profile Of Sodium bromide:
Moderately toxic by ingestion, experimental reproductive effects. 
Incompatible with acids, alkaloidal and heavy-metal salts. 
When heated to decomposition it emits toxic fumes of Brand NazO. 

Sodium bromide presents low to moderate hazards, mainly related to irritation and effects from excessive exposure, particularly ingestion.
Sodium bromide is generally considered safe under controlled use.
However, proper handling is still required.

Skin contact is typically low risk, but prolonged exposure may cause mild irritation or dryness.
Sensitive individuals may experience slight redness.
Protective gloves are recommended in industrial settings.

Eye contact may cause mild irritation.
Symptoms include redness and discomfort.
Eyes should be rinsed thoroughly with water if exposure occurs.

Inhalation of dust may cause respiratory irritation.
Symptoms can include coughing or throat discomfort.
Adequate ventilation and dust control are important.

Ingestion of large amounts is harmful, as bromide ions can affect the central nervous system.
Symptoms may include drowsiness, confusion, or bromism (chronic toxicity).
Medical attention should be sought if swallowed in significant quantities.

Sodium bromide is not flammable, but it may decompose under extreme heat.
Thermal decomposition can produce bromine-containing fumes.
Standard fire safety precautions should be followed.

Sodium bromide is chemically stable under normal conditions, but reacts with strong oxidizing agents to form bromine.
Sodium bromide should be stored away from oxidizers.
From an environmental perspective, it is moderately hazardous in high concentrations, particularly in aquatic systems.

 

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