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TRIETHYLENE GLYCOL (TEG)

TRIETHYLENE GLYCOL (TEG)

Triethylene glycol, TEG, or triglycol is a colorless odorless viscous liquid with molecular formula HOCH2CH2OCH2CH2OCH2CH2OH. 
Triethylene glycol is used as a plasticizer for vinyl polymers. 
Triethylene glycol is also used in air sanitizer products.
When aerosolized Triethylene glycol acts as a disinfectant. 
Glycols are also used as liquid desiccants for natural gas and in air conditioning systems. 
Triethylene glycol is an additive for hydraulic fluids and brake fluids and is used as a base for "smoke machine" fluid in the entertainment industry.

CAS: 112-27-6
European Community (EC) Number: 203-953-2

IUPAC Name: 2-[2-(2-hydroxyethoxy)ethoxy]ethanol

Molecular Formula: C6H14O4
HOCH2(CH2CH2O)2CH2OH
Molecular Weight: 150.17 g/mol


Color / Form: Colorless liquid
Odor: Practically odorless
Boiling Point: 545 °F at 760 mmHg
Melting Point: 24.3 °F 
Flash Point: 330 °F 
Solubility: greater than or equal to 100 mg/mL at 68 °F 
Density: 1.125 at 68 °F 
Vapor Density: 5.17 
Vapor Pressure: less than 0.001 mmHg at 68 °F ; 1 mmHg at 237 °F
Autoignition Temperature: 700 °F
Viscosity: 47.8 cP at 20 °C
Heat of Vaporization: 61.04 kJ/mol at 101.3 kPa /=760 mm Hg/
Index of refraction: 1.4531 at 15 °C/D


Triethylene glycol is a poly(ethylene glycol) that is octane-1,8-diol in which the carbon atoms at positions 3 and 6 have been replaced by oxygen atoms. 
Triethylene glycol has a role as a plasticiser. 
Triethylene glycol is a poly(ethylene glycol), a diol and a primary alcohol.

Triethylene glycol is a member of a homologous series of dihydroxy alcohols. 
Triethylene glycol is a colorless, odorless and stable liquid with high viscosity and a high boiling point. 
Apart from its use as a raw material in the manufacture and synthesis of other products, Triethylene glycol is known for its hygroscopic quality and its ability to dehumidify fluids. 
This liquid is miscible with water, and at standard atmospheric pressure (101.325 kPa) has a boiling point of 286.5 °C and a freezing point of −7 °C. 
Triethylene glycol is also soluble in ethanol, acetone, acetic acid, glycerine, pyridine, aldehydes; slightly soluble in diethyl ether; and insoluble in oil, fat and most hydrocarbons.


Triethylene glycol, TEG, or triglycol is a colorless odorless viscous liquid with molecular formula HOCH2CH2OCH2CH2OCH2CH2OH. 
Triethylene glycol is used as a plasticizer for vinyl polymers. 
Triethylene glycol is also used in air sanitizer products.
When aerosolized Triethylene glycol acts as a disinfectant. 
Glycols are also used as liquid desiccants for natural gas and in air conditioning systems. 
Triethylene glycol is an additive for hydraulic fluids and brake fluids and is used as a base for "smoke machine" fluid in the entertainment industry.


Triethylene glycol (also known as TEG, triglycol and trigen) is a colourless, viscous, non-volatile liquid with the formula C6H14O4.  
Triethylene glycol is well known for its hygroscopic quality and its ability to dehumidify fluids.


Triethylene glycol is prepared commercially as a co-product of the oxidation of ethylene at high temperature, in the presence of a silver oxide catalyst.  
The ethylene oxide is then hydrated to yield mono, di, tri, and tetra ethylene glycols.

It is estimated that the total world consumption of Triethylene glycol is in excess of 175 metric tonnes annually.


Triethylene glycol is the next higher molecular weight polymer after diethylene glycol in the series of polyethylene glycols. 
This series consists of subunits of ethylene glycol joined by an ether link. 
As the number of subunits increases, the polyethylene glycols are typically a mixture of varying chain lengths and are described by a number (e.g., PEG-3350).


Triethylene glycol is a transparent, colorless, low volatility, moderate-viscosity, water-soluble liquid. 
Under normal conditions, there is no detectable odor; under high vapor concentrations, a slightly sweet odor may be detected. 
Triethylene glycol is completely miscible with water and many organic liquids. 
Triethylene glycol has properties similar to other glycols and may be used preferentially in applications requiring a higher boiling point, higher molecular weight or lower volatility than diethylene glycol. 


The hydroxyl groups on triethylene glycol undergo the usual alcohol chemistry giving a wide variety of possible derivatives. 
Hydroxyls can be converted to aldehydes, alkyl halides, amines, azides, carboxylic acids, ethers, mercaptans, nitrate esters, nitriles, nitrite esters, organic esters, peroxides, phosphate esters and sulfate esters.

Triethylene glycol is the most used means in the oil and gas industry for dehydration of water from natural gas.

Triethylene glycol (TEG) is a colorless, viscous liquid with a slight odor. 
Triethylene glycol is non-flammable, mildly toxic, and considered non-hazardous. 
Triethylene glycol is a member of a homologous series of dihydroxy alcohols. 
Triethylene glycol is used as a plasticizer for vinyl polymers as well as in the manufacture of air sanitizer and other consumer products.


Triethylene Glycol (TEG) is a liquid chemical compound with the molecular formula C6H14O4 or HOCH2CH2CH2O2CH2OH. 
Triethylene glycol's CAS number is 112-27-6. 
Triethylene glycol is recognized for its hygroscopic quality and ability to dehumidify fluids. 
Triethylene glycol is miscible with water and soluble in ethanol, acetone, acetic acid, glycerine, pyridine, and aldehydes. 
Triethylene glycol is slightly soluble in diethyl ether, and insoluble in oil, fat, and most hydrocarbons.

Triethylene glycol is commercially produced as a co-product of the oxidation of ethylene at a high temperature in the presence of silver oxide catalyst, followed by hydration of ethylene oxide to yield mono, di, tri, and tetraethylene glycols.

The oil and gas industries use Triethylene glycol to dehydrate natural gas as well as other gases including CO2, H2S, and other oxygenated gases. 
Industrial uses include adsorbents and absorbents, functional fluids in both closed and open systems, Intermediates, petroleum production processing aids, and solvents. Triethylene glycol is used in the manufacture of a host of consumer products that include anti-freeze, automotive care products, building and construction materials, cleaning and furnishing care products, fabric, textile, and leather products, fuels and related products, lubricants and greases, paints and coatings, personal care products, and plastic and rubber products.


Triethylene glycol is a colorless and odorless, organic compound. 
Triethylene glycol's complete miscibility with water and many other organic solvents make its use important in a wide range of industrial applications. 
Industrial Grade Triethylene glycol is used primarily as a drying agent for natural gas.

General Applications:  Adhesives, Coatings, Emulsifiers, Lubricants, Plasticizers, Polyurethane foams, Solvents, Silicone compounds, Thermoplastics, Unsaturated polyester resins


Triethylene glycol is used in a variety of applications and is only available in one single high purity grade. 
The markets for Triethylene glycol products are plasticiser for polymer fibres, coolants in automobile antifreeze, and resins. 
The excellent humectant (hygroscopicity) property of TEG also makes it ideal for use in fibres treatment, paper, adhesives, printing inks, leather and cellophane. 
In the oil and gas industry, the main use is to dehydrate gases.


Triethylene glycol is an important non-volatile industrial solvent. 
Triethylene glycol is also useful in the dehydration of gases, manufacture of insecticides and in the synthesis of some organic derivatives. 
Pure Triethylene glycol is useful in the production of plasticizers for cellophane, glue, cork, powdered ceramics and some plastics. 
Triethylene glycol is a component in the formulation of some pigments, printing dyes, inks and pastes. 
Triethylene glycol is also used for air fumigation.


Triethylene Glycol (TEG) is a larger molecule than MEG, DEG and has two ether groups. 
Triethylene glycol is less clear and less hygroscopic than DEG, but has a higher boiling point, density and viscosity.


Triethylene glycol is most commonly used for natural gas dehydration to strip the water out of the gas. 
Triethylene glycol is wildly used in applications which require higher boiling point, higher molecular weight with low volatility such as plasticizer, unsaturated polyester resin, emulsifiers, lubricants, heat transfer fluids and solvent for equipment cleaning, printing ink.


Obtained by oxidizing ethylene at high temperatures using an oxide catalyst.
Triethylene glycol is a colourless, odourless, liquid at room temperature with a melting point around -7 ºC.
Industrial uses coating products, inks and toners, heat transfer fluids, lubricants, greases and hydraulic fluids.
Cosmetic uses: fragrance, perfuming, and viscosity controlling functions.


Triethylene Glycol, also known by the names TEG, Triglycol, and Trigen, is a sweet-tasting, viscous, colorless liquid with the chemical formula of C6H14O4.

Triethylene Glycol (TEG) is composed of six carbon atoms, fourteen hydrogen atoms, and four oxygen atoms.

Triethylene Glycol (TEG) is one of the most useful products in the chemical and petrochemical industry and it’s famous for its hygroscopic ability and its dehumidify feature to absorb moisture from different types of fluids.

Triethylene Glycol (TEG) is one of the by-products of the chemical reaction between Ethylene Oxide and water at high temperatures with silver oxide as the catalyst

The highest Triethylene Glycol (TEG) grade is achieved when the chemical reaction occurs in neutral or acid-based environments

Based on the latest market information, it’s estimated that world consumption for Triethylene Glycol (TEG) is above 175 metric tons per year

Triethylene Glycol (TEG) is used widely in the industry and due to its less toxic feature, it’s often used instead of Diethylene Glycol (DEG) in different industries.


The main Triethylene Glycol (TEG) usage and application is in the oil and gas industry, TEG is used widely in the oil and gas pipelines as a dehydrating agent that removes water from the gas and oil and avoids freezing, making the transfer of gas and oil very easier and more smooth

Triethylene Glycol (TEG) is used as the plasticizer for the production of the Vinyl Polymer which is used for the manufacturing of PVC Resin, one of the most used products in different industries especially for producing different pipelines uses for transferring a diverse range of fluids

One of the most popular and growing uses of Triethylene Glycol (TEG) is as an air sanitizer and cleaner, with the issues such as global warming and more pollution across the world, this application of the TEG will grow dramatically in the short-term and long-term future

The other uses and application of Triethylene Glycol (TEG) is as a mild disinfectant and as a dehumidifying agent in different air conditioning systems because of its low toxicity, low odor, and antimicrobial properties

Also, Triethylene Glycol (TEG) is used as a solvent for many products and as an intermediate in the production of diverse chemical and petrochemical substances and products.


What is Triethylene Glycol used for?

Oil & Gas Industry
The main uses for triethylene glycol are based upon its hygroscopic quality. 
This means that it can absorb moisture from the air through absorption or adsorption. 
Triethylene glycol is used as a dehydrating agent for natural gas pipelines where it removes the water from the gas before being condensed. 
The triethylene glycol can then be continually reused, although the by-product of benzene needs to be disposed of carefully. 
This process is useful as it prevents the gas from freezing making the gas easier to transport and manage for end consumers.


Mild Disinfectant
Triethylene glycol can also be used as a mild disinfectant. 
Due to its low toxicity, antimicrobial properties, and low odour, it is commonly used for air disinfection in occupied areas where more aggressive disinfectants cannot be used. 
Due to these disinfectant properties and the dehydrating properties, it is an ideal dehumidifying agent in air-conditioning units.

Preparation
Triethylene glycol is prepared commercially as a co-product of the oxidation of ethylene at high temperature in the presence of silver oxide catalyst, followed by hydration of ethylene oxide to yield mono(one)-, di(two)-, tri(three)- and tetraethylene glycols.

Applications:

Triethylene glycol is used by the oil and gas industry to "dehydrate" natural gas. 
Triethylene glycol may also be used to dehydrate other gases, including CO2, H2S, and other oxygenated gases.
It is necessary to dry natural gas to a certain point, as humidity in natural gas can cause pipelines to freeze, and create other problems for end users of the natural gas. 
Triethylene glycol is placed into contact with natural gas, and strips the water out of the gas. 
Triethylene glycol is heated to a high temperature and put through a condensing system, which removes the water as waste and reclaims the TEG for continuous reuse within the system. 
The waste Triethylene glycol produced by this process has been found to contain enough benzene to be classified as hazardous waste (benzene concentration greater than 0.5 mg/L).

Triethylene glycol is well established as a relatively mild disinfectant toward a variety of bacteria, influenza A viruses and spores of Penicillium notatum fungi. However, its exceptionally low toxicity, broad materials compatibility, and low odor combined with its antimicrobial properties indicates that it approaches the ideal for air disinfection purposes in occupied spaces.
Much of the scientific work with triethylene glycol was done in the 1940s and 1950s, however that work has ably demonstrated the antimicrobial activity against airborne, solution suspension, and surface bound microbes. 
The ability of triethylene glycol to inactivate Streptococcus pneumoniae (original citation: pneumococcus Type I), Streptococcus pyogenes (original citation: Beta hemolytic streptococcus group A) and Influenza A virus in the air was first reported in 1943.
Since the first report the following microorganisms have been reported in the literature to be inactivated in the air: Penicillium notatum spores, Chlamydophila psittaci (original citation: meningopneumonitis virus strain Cal 10 and psittacosis virus strain 6BC), Group C streptococcus, type 1 pneumococcus, Staphylococcus albus, Escherichia coli, and Serratia marcescens Bizio (ATCC 274).
Solutions of triethylene glycol are known to be antimicrobial toward suspensions of Penicillium notatum spores, Streptococcus pyogenes (original citation: Beta hemolytic streptococcus Group A ), Streptococcus pneumoniae (original citation: pneumococcus Type I), Streptococcus viridans, and Mycobacterium bovis (original citation: tubercle bacilli Ravenel bovine-type).
Further, the inactivation of H1N1 influenza A virus on surfaces has been demonstrated.
The latter investigation suggests that triethylene glycol may prove to be a potent weapon against future influenza epidemics and pandemics. 
However, at least some viruses, including Pseudomonas phage phi6 become more infectious when treated with triethylene glycol.

Consumer Uses

-Diluent
-Functional fluids (closed systems)
-Hydraulic fluids
-Insulators
-Intermediates
-Pigments
-Plasticizer
-Processing aids not otherwise specified
-Refrigerants
-Solvent

Industry Uses

-Absorbent
-Catalyst
-Dehydrating agent (desiccant)
-Diluent
-Functional fluids (closed systems)
-Heat transferring agent
-Hydraulic fluids
-Intermediates
-Pigments
-Plasticizer
-Processing aids, not otherwise listed
-Processing aids, specific to petroleum production
-Solvent

SYNONYMS:

TRIETHYLENE GLYCOL
112-27-6
Triglycol
2,2'-(Ethane-1,2-diylbis(oxy))diethanol
Trigen
Triethylenglykol
Triethyleneglycol
2,2'-Ethylenedioxydiethanol
2-[2-(2-Hydroxyethoxy)ethoxy]ethanol
1,2-Bis(2-hydroxyethoxy)ethane
2,2'-(Ethylenedioxy)diethanol
2,2'-Ethylenedioxybis(ethanol)
3,6-Dioxaoctane-1,8-diol
2,2'-Ethylenedioxyethanol
Di-beta-hydroxyethoxyethane
Glycol bis(hydroxyethyl) ether
Trigol
2,2'-[ethane-1,2-diylbis(oxy)]diethanol
Caswell No. 888
Ethanol, 2,2'-[1,2-ethanediylbis(oxy)]bis-
Triethylene glcol
Ethylene glycol dihydroxydiethyl ether
Bis(2-hydroxyethoxyethane)
TEG
Ethanol, 2,2'-(ethylenedioxy)di-
2,2'-(1,2-Ethanediylbis(oxy))bisethanol
NSC 60758
HSDB 898
Ethylene glycol-bis-(2-hydroxyethyl ether)
EINECS 203-953-2
EPA Pesticide Chemical Code 083501
BRN 0969357
CCRIS 8926
2-[2-(2-HYDROXY-ETHOXY)-ETHOXY]-ETHANOL
119438-10-7
DTXSID4021393
UNII-3P5SU53360
CHEBI:44926
AI3-01453
NSC-60758
MACROGOL 150
3P5SU53360
PEG-3
3,6-Dioxa-1,8-octanediol
Di-.beta.-hydroxyethoxyethane
DTXCID601393
Ethanol, 2,2'-(1,2-ethanediylbis(oxy))bis-
EC 203-953-2
4-01-00-02400 (Beilstein Handbook Reference)
NCGC00163798-03
2-[2-(2-hydroxyethoxy)ethoxy]ethan-1-ol
103734-98-1
122784-99-0
137800-98-7
145112-98-7
2,2'-(ethane-1,2-diylbis(oxy))bis(ethan-1-ol)
TRIETHYLENE GLYCOL (USP-RS)
TRIETHYLENE GLYCOL [USP-RS]
Triethylenglykol [Czech]
MFCD00081839
2-(2-(2-hydroxyethoxy)ethoxy)ethanol
CAS-112-27-6
2-(2-(2-HYDROXY-ETHOXY)-ETHOXY)-ETHANOL
OH-PEG3-OH
Trigenos
triethylenglycol
triethylene-glycol
Triethyleneglycol,
Tri-ethylene glycol
3,8-diol
TEG (GLYCOL)
Triethylene glycol, puriss.
SCHEMBL14929
WLN: Q2O2O2Q
AMY375
Ethanol,2'-(ethylenedioxy)di-
TRIETHYLENE GLYCOL [MI]
CHEMBL1235259
1,8-dihydroxy-3,6-dioxaoctane
TRIETHYLENE GLYCOL [HSDB]
TRIETHYLENE GLYCOL [INCI]
TRIETHYLENE GLYCOL DIMALEATE
NSC60758
STR02345
TRIETHYLENE GLYCOL [WHO-DD]
Tox21_112073
Tox21_202440
Tox21_300306
MFCD00002880
MFCD01779596
MFCD01779599
MFCD01779601
MFCD01779603
MFCD01779605
MFCD01779609
MFCD01779611
MFCD01779612
MFCD01779614
MFCD01779615
MFCD01779616
STL282716
AKOS000120013
CS-W018156
DB02327
HY-W017440
USEPA/OPP Pesticide Code: 083501
NCGC00163798-01
NCGC00163798-02
NCGC00163798-04
NCGC00163798-05
NCGC00163798-06
NCGC00254097-01
NCGC00259989-01
1,2-DI(BETA-HYDROXYETHOXY)ETHANE
2-[2-(2-Hydroxyethoxy)ethoxy]ethanol #
BP-21036
Triethylene glycol, ReagentPlus(R), 99%
Ethanol,2'-[1,2-ethanediylbis(oxy)]bis-
FT-0652416
FT-0659862
T0428
EN300-19916
2,2'-(1,2-Ethanediyl bis (oxy))-bisethanol
F71165
ETHYLENE GLYCOL-BIS(2-HYDROXYETHYL)ETHER
Triethylene glycol, SAJ first grade, >=96.0%
ETHYLENE GLYCOL-BIS-(2-HYDROXYETHYL)ETHER
Q420630
SR-01000944720
Triethylene glycol, Vetec(TM) reagent grade, 98%
J-506706
SR-01000944720-1
ETHANOL, 2,2'-(1,2-ETHANEDIYLBIS (OXY))BIS-
F0001-0256
Triethylene glycol, BioUltra, anhydrous, >=99.0% (GC)
Z104476078
InChI=1/C6H14O4/c7-1-3-9-5-6-10-4-2-8/h7-8H,1-6H
Triethylene glycol, United States Pharmacopeia (USP) Reference Standard


 

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