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CUMYL HYDROPEROXIDE

Cumyl hydroperoxide is the organic compound with the formula C6H5C(CH3)200H.
Cumyl hydroperoxide is classified as an oily liquid, organic hydroperoxide.
The decomposition products of cumene hydroperoxide are methylstyrene, acetophenone and 2-Phenyl-2-propanol.

Cumyl hydroperoxide is produced by an autoxidation, by treating the cluster with oxygen.
At temperatures >100 °C, oxygen passes through the liquid cluster:

C6H5(CH3)2CH + O 2 → C6H5(CH3)2COOH
Dicumyl peroxide is a by-product.

Cumyl hydroperoxide is an intermediate in the cumene process to produce phenol and acetone from benzene and propene.
Cumyl hydroperoxide is a free radical initiator for the production of acrylates.

Cumyl hydroperoxide is involved as an organic peroxide in the production of propylene oxide through the oxidation of propylene.

CH3CHCH2+ C6H5(CH3)2COOH → CH3CHCH2Ç + Ç6H5(CH3)2COH
Dehydrating and hydrogenating cumyl alcohol recycles cumyl.


CAS NUMBER: 80-15-9
EC NUMBER: 201-254-7
MOLECULAR FORMULA: C9H12O2
MOLECULAR WEIGHT: 152,193


Cumyl hydroperoxide is an intermediate in the cumene process to develop phenol and acetone from benzene and propene.
Cumyl hydroperoxide is typically used as an oxidizing agent.

The chemical structure of a molecule includes the arrangement of atoms and the chemical bonds that hold the atoms together.
The Cumyl hydroperoxid molecule contains a total of 23 bonds. 
Cumyl hydroperoxid has 11 non-H bond(s), 6 multiple bond(s), 2 rotatable bond(s), 6 aromatic bond(s), 1 six-membered ring(s) and 1 hydroxyl group(s).

Cumyl hydroperoxid is an oxidant used in the preparation of polystyrene nanocapsules.
By examining melatonin, it has been observed that it promotes lipid oxidation and inhibits protein synthesis.

Cumyl hydroperoxid is a relatively stable organic peroxide.
This oxidizing agent is commercially available with ~80% purity.
The half-life of a 0.2 M solution in benzene is 29 hours at 145°C.
The decomposition products of Cumyl hydroperoxid are methylstyrene, acetophenone and cumyl alcohol.
Pure Cumyl hydroperoxid can be stored at room temperature but has a high potential for uncontrolled reaction and explosion.
Can undergo rapid decomposition under the influence of a wide variety of trace compounds such as cumene and other hydroperoxides, acids and metals


Cumyl hydroperoxid is a relatively stable organic peroxide.
This oxidizing agent is commercially available with ~80% purity.
The half-life of a 0.2 M solution in benzene is 29 hours at 145°C.
The decomposition products of Cumyl hydroperoxid are methylstyrene, acetophenone and cumyl alcohol.
Pure Cumyl hydroperoxid can be stored at room temperature but has a high potential for uncontrolled reaction and explosion.
Can undergo rapid decomposition under the influence of a wide variety of trace compounds such as cumene and other hydroperoxides, acids and metals

Cumyl hydroperoxid (CHP) occupies an important position in both scientific and industrial fields due to its exceptional reactivity and versatility.
This white crystalline solid with a pungent odor acts as a strong oxidizing agent.
Derived from cumene, a petroleum-derived hydrocarbon, CHP plays an important role in the synthesis of various organic and inorganic compounds.
In addition, its applications include the production of polyurethane foam and polyvinyl chloride (PVC).


Cumyl hydroperoxid also contributes to the study of oxidation and reduction mechanisms, provides insights into the effects of oxidizing agents on organic compounds, as well as uncovering the complexities of polymerization and crosslinking reactions.
The strength of Cumyl hydroperoxid as an oxidizing agent comes from its extraordinary capacity to transfer oxygen atoms to other molecules.
Cumyl hydroperoxid manifests itself as a strong oxidizer, capable of oxidizing a wide variety of organic and inorganic compounds.
In addition, it exhibits strong reducing properties, facilitating the reduction of various organic and inorganic substances.

Cumyl hydroperoxid, also known as Cumyl hydroperoxid, is used as an oxidizing agent.
Unrated products supplied by Spectrum are indicative of a grade fit for general industrial or research purposes and are generally not fit for human consumption or therapeutic use.


Melting point :-30 °C

Boiling point :100-101 °C/8 mmHg (lit)

density : 1.03 g/mL at 25 °C

vapor density :5.4 (against air)

vapor pressure :<0.03 mm Hg (20 °C)

refractive index:N20/day1.5230

Fp:192 °C

retention degree. :2-8°C

Solubility :Chloroform (Soluble), Ethyl Acetate (Slightly), Methanol (Soluble)

form : clear liquid

pka:pK1:12.60 (25°C)

Color : Colorless to Nearly colorless

Water solubility : Slightly soluble


Cumyl hydroperoxid (CAS No: 80-15-9) Or 1-Methyl-1-phenylethyl Hydroperoxide, Cumyl hydroperoxid is a strong oxidizing agent used in making Acetone and Phenol as a curing agent.

Cumyl hydroperoxid can be stored at room temperature.
Cumyl hydroperoxid is an organic compound.
Cumyl hydroperoxid is used as the polymerization initiator.
Cumyl hydroperoxid is also used as a source of phenol and acetone, and as peroxysulfuric acid, an inorganic compound used as an oxidizing agent.

Cumyl hydroperoxid is a colorless to light yellow liquid with a pungent liquid.
Cumyl hydroperoxid flash point is 175 F.
Cumyl hydroperoxid boils at 153 C and 100 C at a reduced pressure of 8 mmHg.

Cumyl hydroperoxid is an oily liquid made by air oxidation of cumene.
Cumyl hydroperoxid is an eposiding reagent for allylic alcohols and fatty acid esters.
Cumyl hydroperoxid decomposes around 100°C.

Cumyl hydroperoxid is used in the preparation of polystyrene nanocapsules.
Cumyl hydroperoxid acts as a hardener for polyester resins and as an oxidizer in organic chemical reactions.
Cumyl hydroperoxid acts as an initiator in radical polymerization, especially for acrylate and methacrylate monomers.
Cumyl hydroperoxid is also used as an intermediate in the cumene process to develop phenol and acetone from benzene and propene.
Cumyl hydroperoxid is also used as an epoxidation reagent for allylic alcohols and fatty acid esters.
Cumyl hydroperoxid is also used in the preparation of methylstyrene, acetophenone and cumyl alcohol.


Cumyl hydroperoxid is used in the preparation of polystyrene nanocapsules.
Cumyl hydroperoxid acts as a hardener for polyester resins and as an oxidizer in organic chemical reactions.
Cumyl hydroperoxid acts as an initiator in radical polymerization, especially for acrylate and methacrylate monomers.
Cumyl hydroperoxid is also used as an intermediate in the cumene process to develop phenol and acetone from benzene and propene.
Cumyl hydroperoxid is also used as an epoxidation reagent for allylic alcohols and fatty acid esters.
Cumyl hydroperoxid is also used in the preparation of methylstyrene, acetophenone and cumyl alcohol.


Cumyl hydroperoxid (CHP) has been used as an initiator in the production of phenol and acetone by catalytic cleavage and in polymerization.
However, many serious fires and explosions have occurred due to its thermal instability and incompatibility.
In fact, CHP has been given a flammable type or Class III hazard classification by the National Fire Protection Association (NFPA).
However, to date, the hazards of reactive and incompatible have not yet been clearly defined.
In this study, thermal decomposition and leakage behavior of CHP with approximately 1% wt mismatches such as H 2 SO 4 , HCl, NaOH, KOH, Fe 2 O 3 , FeCl 3 and Fe 2 (SO 4 ) 3 were investigated.
Cumyl hydroperoxid was analyzed by DSC thermal analysis and VSP2 adiabatic calorimetry.
Thermokinetic data obtained through calorimetry, such as initial temperature, heat of decomposition, adiabatic temperature rise, and self-heating rate, were also compared with data from CHP in your cluster.

Hydroxide ion and ferric ion were found to be quite incompatible with CHP.
The worst case of thermal runaway of CHP was observed when mixed with hydroxides (in the production or storage of CHP).
The adiabatic self-heating rate of 15% by weight CHP was 9 °C min -1 in VSP2, which increased quite dramatically to 100 °C min -1.
This study reveals that the thermal hazards of CHP affected by incompatibilities should not be ignored.
The different thermokinetic data affected by mismatches are key considerations for ERS (Emergency Assistance System) design in CHP-related processes using DIERS technology.
The decomposition pathway of CHP in various impurities was suggested using chromatography in product analyses.


Cumyl hydroperoxid is used in the preparation of polystyrene nanocapsules.
Cumyl hydroperoxid acts as a hardener for polyester resins and as an oxidizer in organic chemical reactions.
Cumyl hydroperoxid acts as an initiator in radical polymerization, especially for acrylate and methacrylate monomers.
Cumyl hydroperoxid is also used as an intermediate in the cumene process to develop phenol and acetone from benzene and propene.
Cumyl hydroperoxid is also used as an epoxidation reagent for allylic alcohols and fatty acid esters.


Cumyl hydroperoxid is also used in the preparation of methylstyrene, acetophenone and cumyl alcohol.
This Thermo Scientific Chemicals branded product was originally part of the Alfa Aesar product portfolio.
Some documents and label information may refer to the old brand.
The original Alfa Aesar product/product code or SKU reference remained unchanged as part of the brand transition to Thermo Scientific Chemicals.

SYNONYMS:
1-Methyl-1-phenylethyl hydroperoxide;
7-Cumyl hydroperoxide;
alpha,alpha-Dimethylbenzyl hydroperoxide;
alpha-Cumene hydroperoxide;
alpha-Cumyl hydroperoxide;
CHP;
cumene hydroperoxide;
Cumenyl hydroperoxide;
Cumolhydroperoxide;
Cumyl hydroperoxide;
Hydroperoxyde cumene;
Cumyle in Hydroperoxyde;
Isopropylbenzene hydroperoxide
 

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