L-(+)-Tartaric acid is used the common commercial esters are the diethyl and dibutyl derivatives used for lacquers and in textile printing.
L-(+)-Tartaric acid is used Pharmaceutic aid (buffering agent).
L-(+)-Tartaric acid is widely utilized in pharmaceutical industries.
CAS Number: 87-69-4
EC Number: 201-766-0
MDL number: MFCD00064207
Molecular Formula: C4H6O6 / COOH(CHOH)2COOH / H2C4H4O6
Molecular Weight: 150.09 g/mol
SYNONYMS:
TARTARIC ACID, L-TARTARIC ACID, TARTRATE, (2R,3R)-2,3-DIHYDROXYSUCCINIC ACID, Tartaric, lev, 2,3-Dihydroxysuccinic acid, l-tartaric, 2,3-DIHYDROXYBUTANEDIOIC ACID, levo, (+)-L-Tartaric acid, (+)-Tartaric acid, 87-69-4, L-(+)-Tartaric acid, L-Tartaric acid, L(+)-Tartaric acid, tartaric acid, (2R,3R)-2,3-dihydroxysuccinic acid, (2R,3R)-2,3-dihydroxybutanedioic acid, (R,R)-Tartaric acid, Threaric acid, L-threaric acid, Dextrotartaric acid, Acidum tartaricum, Natural tartaric acid, (+)-(R,R)-Tartaric acid, (2R,3R)-(+)-Tartaric acid, Tartaric acid, L-, Rechtsweinsaeure, Kyselina vinna, (2R,3R)-Tartaric acid, (R,R)-(+)-Tartaric acid, tartrate, Succinic acid, 2,3-dihydroxy, Weinsteinsaeure, L-2,3-Dihydroxybutanedioic acid, (2R,3R)-rel-2,3-Dihydroxysuccinic acid, 1,2-Dihydroxyethane-1,2-dicarboxylic acid, EINECS 201-766-0, (+)-Weinsaeure, 133-37-9, NSC 62778, FEMA No. 3044, INS NO.334, DTXSID8023632, UNII-W4888I119H, CHEBI:15671, Kyselina 2,3-dihydroxybutandiova, AI3-06298, Lamb protein (fungal), INS-334, (+/-)-Tartaric Acid, Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, (R,R)-tartrate, NSC-62778, W4888I119H, Tartaric acid (VAN), DTXCID203632, E 334, E-334, RR-tartaric acid, (+)-(2R,3R)-Tartaric acid, Tartaric acid, L-(+)-, EC 201-766-0, TARTARIC ACID (L(+)-), Tartaric acid, Weinsaeure, BAROS COMPONENT TARTARIC ACID, L-2,3-DIHYDROXYSUCCINIC ACID, MFCD00064207, C4H6O6, L-tartarate, 4J4Z8788N8, 138508-61-9, (2R,3R)-2,3-Dihydroxybernsteinsaeure, Resolvable tartaric acid, d-alpha,beta-Dihydroxysuccinic acid, TARTARIC ACID (II), TARTARIC ACID [II], 144814-09-5, Kyselina 2,3-dihydroxybutandiova [Czech], REL-(2R,3R)-2,3-DIHYDROXYBUTANEDIOIC ACID, TARTARIC ACID (MART.), TARTARIC ACID [MART.], (1R,2R)-1,2-Dihydroxyethane-1,2-dicarboxylic acid, TARTARIC ACID (USP-RS), TARTARIC ACID [USP-RS], BUTANEDIOIC ACID, 2,3-DIHYDROXY-, (R-(R*,R*))-, Tartaric acid D,L, Butanedioic acid, 2,3-dihydroxy- (R-(R*,R*))-, TARTARIC ACID (EP MONOGRAPH), TARTARIC ACID [EP MONOGRAPH], Tartarate, L(+) tartaric acid, (2RS,3RS)-Tartaric acid, 2,3-dihydroxy-succinic acid, Traubensaeure, Vogesensaeure, Weinsaure, acide tartrique, acido tartarico, tartaric-acid, para-Weinsaeure, L-Threaric aci, 4ebt, NSC 148314, NSC-148314, (r,r)-tartarate, (+)-tartarate, l(+)tartaric acid, Tartaric acid; L-(+)-Tartaric acid, Tartaric acid (TN), (+-)-Tartaric acid, Butanedioic acid, 2,3-dihydroxy-, (R*,R*)-, L-(+) tartaric acid, (2R,3R)-Tartarate, 1d5r, DL TARTARIC ACID, TARTARICUM ACIDUM, 2,3-dihydroxy-succinate, TARTARIC ACID,DL-, SCHEMBL5762, TARTARIC ACID, DL-, Tartaric acid (JP17/NF), TARTARIC ACID [FCC], TARTARIC ACID [JAN], d-a,b-Dihydroxysuccinic acid, MLS001336057, L-TARTARIC ACID [MI], TARTARIC ACID [VANDF], DL-TARTARIC ACID [MI], CCRIS 8978, L-(+)-Tartaric acid, ACS, TARTARIC ACID [WHO-DD], CHEMBL1236315, L-(+)-Tartaric acid, BioXtra, TARTARICUM ACIDUM [HPUS], UNII-4J4Z8788N8, (2R,3R)-2,3-tartaric acid, CHEBI:26849, HMS2270G22, Pharmakon1600-01300044, TARTARIC ACID, DL- [II], TARTARIC ACID, (+/-)-, TARTARIC ACID,DL- [VANDF], HY-Y0293, STR02377, TARTARIC ACID [ORANGE BOOK], EINECS 205-105-7, Tox21_300155, (2R,3R)-2,3-dihydroxysuccinicacid, NSC759609, s6233, AKOS016843282, L-(+)-Tartaric acid, >=99.5%, CS-W020107, DB09459, NSC-759609, (2R,3R)-2,3-dihydroxy-succinic acid, Butanedioic acid, 2,3-dihydroxy-; Butanedioic acid, 2,3-dihydroxy-, (R-(R*,R*))-, CAS-87-69-4, L-(+)-Tartaric acid, AR, >=99%, TARTARIC ACID COMPONENT OF BAROS, (R*,R*)-2,3-dihydroxybutanedioic acid, NCGC00247911-01, NCGC00254043-01, BP-31012, SMR000112492, SBI-0207063.P001, (2R,3R)-rel-2,3-dihydroxybutanedioic acid, NS00074184, T0025, EN300-72271, (R*,R*)-(+-)-2,3-dihydroxybutanedioic acid, C00898, D00103, D70248, L-(+)-Tartaric acid, >=99.7%, FCC, FG, L-(+)-Tartaric acid, ACS reagent, >=99.5%, L-(+)-Tartaric acid, BioUltra, >=99.5% (T), J-500964, TARTARIC ACID, L-TARTARIC ACID, TARTRATE, (2R,3R)-2,3-DIHYDROXYSUCCINIC ACID, Tartaric, lev, 2,3-Dihydroxysuccinic acid, l-tartaric, 2,3-DIHYDROXYBUTANEDIOIC ACID, levo, [R-(R*,R*)]-2,3-Dihydroxybutanedioic acid, L-2,3-Dihydroxybutanedioic acid, ordinary tartaric acid, natural tartaric acid, d-tartaric acid, (+)-tartaric acid, dextrotartaric acid, d-α,β-dihydroxysuccinic acid, Weinsure, Weinsteinsure, (2R,3R)-(+)-Tartaric acid, L-Threaric acid, L-2,3-Dihydroxybutanedioic acid, (2R,3R)-2,3-Dihydroxysuccinic acid, J-520420, L-(+)-Tartaric acid, ReagentPlus(R), >=99.5%, L-(+)-Tartaric acid, SAJ first grade, >=99.5%, L-(+)-Tartaric acid, tested according to Ph.Eur., Butanedioic acid, 2,3-dihydroxy-, (R*,R*)-(+-)-, L-(+)-Tartaric acid, JIS special grade, >=99.5%, L-(+)-Tartaric acid, natural, >=99.7%, FCC, FG, L-(+)-Tartaric acid, p.a., ACS reagent, 99.0%, L-(+)-Tartaric acid, Vetec(TM) reagent grade, 99%, Q18226455, F8880-9012, Z1147451717, Butanedioic acid, 2,3-dihydroxy-, (theta,theta)-(+-)-, 000189E3-11D0-4B0A-8C7B-31E02A48A51F, L-(+)-Tartaric acid, puriss. p.a., ACS reagent, >=99.5%, L-(+)-Tartaric acid, certified reference material, TraceCERT(R), Tartaric acid, United States Pharmacopeia (USP) Reference Standard, L-(+)-Tartaric acid, anhydrous, free-flowing, Redi-Dri(TM), ACS reagent, >=99.5%, L-(+)-Tartaric acid, p.a., ACS reagent, reag. ISO, reag. Ph. Eur., 99.5%, Tartaric Acid, Pharmaceutical Secondary Standard; Certified Reference Material, 132517-61-4, 2,3-Dihydroxybutanedioic acid, l-tartaric acid, l-+-tartaric acid, l +-tartaric acid, 2r,3r-2,3-dihydroxysuccinic acid, tartaric acid, 2r,3r-2,3-dihydroxybutanedioic acid, r,r-tartaric acid, #NAME?, dextrotartaric acid, l-threaric acid, L-Tartaric acid, L-2,3-dihydroxybutanedioic acid, L-2,3-dihydroxysuccinic acid, Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, Butanedioic acid, 2,3-dihydroxy- [R-(R*,R*)]-, Tartaric acid, L-(+)- (8CI), (2R,3R)-2,3-Dihydroxybutanedioic acid, (+)-(2R,3R)-Tartaric acid, (+)-(R,R)-Tartaric acid, (+)-L-Tartaric acid, (+)-Tartaric acid, (2R,3R)-(+)-Tartaric acid, (2R,3R)-2,3-Dihydroxysuccinic acid, (2R,3R)-Tartaric acid, (R,R)-(+)-Tartaric acid, (R,R)-Tartaric acid, 1,2-Dihydroxyethane-1,2-dicarboxylic acid, 2,3-Dihydroxybutanedioic acid, 2,3-Dihydroxysuccinic acid, Dextrotartaric acid, Dihydroxysuccinic acid, E 334, L-(+)-Tartaric acid, L-Tartaric acid, NSC 62778, Natural tartaric acid, Tartaric acid, Threaric acid, d-Tartaric acid, d-a,ß-Dihydroxysuccinic acid, l-tartaric acid,l-+-tartaric acid,l +-tartaric acid,2r,3r-2,3-dihydroxysuccinic acid,tartaric acid,2r,3r-2,3-dihydroxybutanedioic acid,r,r-tartaric acid,+-l-tartaric acid,dextrotartaric acid,l-threaric acid
L-(+)-Tartaric acid, or "natural" tartaric acid, is abundant in nature, especially in fruits.
L-(+)-Tartaric acid's primary commercial source is as a byproduct of the wine industry.
L-(+)-Tartaric acid is used as an additive in many foods, such as soft drinks, bakery products, and candies.
Industrial uses of L-(+)-Tartaric acid include tanning, ceramics manufacture, and the production of tartrate esters for lacquers and textile printing.
L-(+)-Tartaric acid is a tetraric acid that is butanedioic acid substituted by hydroxy groups at positions 2 and 3.
L-(+)-Tartaric acid is a conjugate acid of a L-tartrate(1-).
L-(+)-Tartaric acid is an enantiomer of a D-tartaric acid.
L-(+)-Tartaric acid belongs to the group of carboxylic acids, and is abundantly found in grapes and wine.
L-(+)-Tartaric acid is a tartaric acid.
L-(+)-Tartaric acid is a conjugate acid of a L-tartrate(1-).
L-(+)-Tartaric acid is an enantiomer of a D-tartaric acid.
L-(+)-Tartaric acid is a white crystalline organic acid that occurs naturally in many plants, most notably in grapes.
Tartaric is an alpha-hydroxy-carboxylic acid, is diprotic and aldaric in acid characteristics, and is a dihydroxyl derivative of succinic acid.
L-(+)-Tartaric acid is a metabolite found in or produced by Escherichia coli.
L-(+)-Tartaric acid is a white crystalline dicarboxylic acid found in many plants, particularly tamarinds and grapes.
L-(+)-Tartaric acid is used to generate carbon dioxide through interaction with sodium bicarbonate following oral administration.
Carbon dioxide extends the stomach and provides a negative contrast medium during double contrast radiography.
In high doses, L-(+)-Tartaric acid acts as a muscle toxin by inhibiting the production of malic acid, which could cause paralysis and maybe death.
L-(+)-Tartaric acid is a white crystalline organic acid.
L-(+)-Tartaric acid occurs naturally in many plants, particularly grapes and tamarinds, and is one of the main acids found in wine.
L-(+)-Tartaric acid is added to other foods to give a sour taste, and is used as an antioxidant.
Salts of L-(+)-Tartaric acid are known as tartrates.
L-(+)-Tartaric acid is a dihydroxy derivative of dicarboxylic acid.
L-(+)-Tartaric acid is included in many foods, especially sour-tasting sweets.
As a food additive, L-(+)-Tartaric acid is used as an antioxidant with E number E334, tartrates are other additives serving as antioxidants or emulsifiers.
Naturally-occurring L-(+)-Tartaric acid is chiral, meaning that it has molecules that are non-superimposable on their mirror-images.
L-(+)-Tartaric acid is a useful raw material in organic chemistry for the synthesis of other chiral molecules.
The naturally occurring form of the acid is L-(+)-tartaric acid or dextrotartaric acid.
The mirror-image (enantiomeric) form, levotartaric acid or D-(-)-tartaric acid, and the achiral form, mesotartaric acid, can be made artificially.
Tartarate is believed to play a role in inhibiting kidney stone formation.
Most tartarate that is consumed by humans is metabolized by bacteria in the gastrointestinal tract -- primarily in the large intestine.
Only about 15-20% of consumed tartaric acid is secreted in the urine unchanged.
L-(+)-Tartaric acid is a white crystalline organic acid that occurs naturally in many plants, most notably in grapes.
Tartaric is an alpha-hydroxy-carboxylic acid, is diprotic and aldaric in acid characteristics, and is a dihydroxyl derivative of succinic acid.
L-(+)-Tartaric acid is a tartaric acid.
L-(+)-Tartaric acid is a conjugate acid of a L-tartrate(1-).
L-(+)-Tartaric acid is an enantiomer of a D-tartaric acid.
L-(+)-Tartaric acid occurs as colorless monoclinic crystals, or a white or almost white crystalline powder.
L-(+)-Tartaric acid is odorless, with an extremely tart taste.
L-(+)-Tartaric Acid is a naturally occurring chemical compound found in berries, grapes and various wines.
L-(+)-Tartaric acid provides antioxidant properties and contributes to the sour taste within these products
L(+)-Tartaric acid is colorless or translucent crystals, or a white, fine granular, crystalline powder.
L-(+)-Tartaric acid is odorless, has an acid taste, and is stable in air.
L-(+)-Tartaric acid, or "natural" tartaric acid, is abundant in nature, especially in fruits.
L-(+)-Tartaric acid's primary commercial source is as a byproduct of the wine industry.
L-(+)-Tartaric acid is used as an additive in many foods, such as soft drinks, bakery products, and candies.
Industrial uses of L-(+)-Tartaric acid include tanning, ceramics manufacture, and the production of tartrate esters for lacquers and textile printing.
L-(+)-Tartaric acid is a tetraric acid that is butanedioic acid substituted by hydroxy groups at positions 2 and 3.
L-(+)-Tartaric acid is a conjugate acid of a L-tartrate(1-).
L-(+)-Tartaric acid is an enantiomer of a D-tartaric acid.
L-(+)-Tartaric acid belongs to the group of carboxylic acids, and is abundantly found in grapes and wine.
USES and APPLICATIONS of L-(+)-TARTARIC ACID:
L-(+)-Tartaric acid is widely used as an acidulant in beverage and other foods.
With its optical activity, L-(+)-Tartaric acid is used as a chemical resolving agent to resolve DL-amino-butanol, an intermediate for the antitubercular drug.
And L-(+)-Tartaric acid is used as a chiral pool to synthesize tartrate derivatives.
With its acidity, L-(+)-Tartaric acid is used as a catalyst in the resin finishing of polyester fabric or pH value regulator in oryzanol production.
With its complexation, L(+)-Tartaric acid is used in electroplating, sulfur removal, and acid pickling.
L-(+)-Tartaric acid is also used as a complexing agent, food additives screening agent or chelating agent in chemical analysis and pharmaceutical inspection, or as resist agent in dyeing.
With its reduction, L-(+)-Tartaric acid is used as a reductive agent in manufacturing mirror chemically or imaging agent in photography.
L-(+)-Tartaric acid can also complex with metal ion and can be used as a cleaning agent or polishing agent of the metal surface.
In the soft drink industry, L-(+)-Tartaric acid is used confectionery products, bakery products, gelatin desserts, as an acidulant.
In photography, tanning, ceramics, manufacture of tartrate.
L-(+)-Tartaric acid is used the common commercial esters are the diethyl and dibutyl derivatives used for lacquers and in textile printing.
L-(+)-Tartaric acid is used Pharmaceutic aid (buffering agent).
L-(+)-Tartaric acid is widely utilized in pharmaceutical industries.
L-(+)-Tartaric acid is used in soft drinks, confectionaries, food products, gelatin desserts and as a buffering agent.
L-(+)-Tartaric acid forms a compound, TiCl2(O-i-Pr)2 with Diels-Alder catalyst and acta as a chelate agent in metal industries.
Owing to its efficient chelating property towards metal ions, L-(+)-Tartaric acid is used in farming and metal industries for complexing micronutrients and for cleaning metal surfaces, respectively.
L-(+)-Tartaric acid is widely used in drugs, food, and beverage industry.
-Pharmaceutical Applications
L-(+)-Tartaric acid is used in beverages, confectionery, food products, and pharmaceutical formulations as an acidulant.
L-(+)-Tartaric acid may also be used as a sequestering agent and as an antioxidant synergist.
In pharmaceutical formulations, L-(+)-Tartaric acid is widely used in combination with bicarbonates, as the acid component of effervescent granules, powders, and tablets.
L-(+)-Tartaric acid is also used to form molecular compounds (salts and cocrystals) with active pharmaceutical ingredients to improve physicochemical properties such as dissolution rate and solubility.
ALTERNATIVE PARENTS OF L-(+)-TARTARIC ACID:
*Short-chain hydroxy acids and derivatives
*Beta hydroxy acids and derivatives
*Monosaccharides
*Fatty acids and conjugates
*Dicarboxylic acids and derivatives
*Alpha hydroxy acids and derivatives
*Secondary alcohols
*1,2-diols
*Carboxylic acids
*Organic oxides
*Hydrocarbon derivatives
*Carbonyl compounds
SUBSTITUENTS OF L-(+)-TARTARIC ACID:
*Sugar acid
*Short-chain hydroxy acid
*Beta-hydroxy acid
*Fatty acid
*Monosaccharide
*Hydroxy acid
*Dicarboxylic acid or derivatives
*Alpha-hydroxy acid
*Secondary alcohol
*1,2-diol
*Carboxylic acid
*Carboxylic acid derivative
*Organic oxide
*Hydrocarbon derivative
*Carbonyl group
*Alcohol
*Aliphatic acyclic compound
PRODUCTION OF L-(+)-TARTARIC ACID:
The L-(+)-Tartaric acid isomer of tartaric acid is industrially produced in the largest amounts.
L-(+)-Tartaric acid is obtained from lees, a solid byproduct of fermentations.
The former byproducts mostly consist of potassium bitartrate (KHC4H4O6).
This potassium salt is converted to calcium tartrate (CaC4H4O6) upon treatment with calcium hydroxide (Ca(OH)2):
KH(C4H4O6) + Ca(OH)2 → Ca(C4H4O6) + KOH + H2O
In practice, higher yields of calcium tartrate are obtained with the addition of calcium sulfate.
Calcium tartrate is then converted to tartaric acid by treating the salt with aqueous sulfuric acid:
Ca(C4H4O6) + H2SO4 → H2(C4H4O6) + CaSO4
CHEMICAL PROPERTIES OF L-(+)-TARTARIC ACID:
L-(+)-Tartaric acid occurs as colorless monoclinic crystals, or a white or almost white crystalline powder.
L-(+)-Tartaric acid is odorless, with an extremely tart taste.
L-(+)-Tartaric Acid is a naturally occurring chemical compound found in berries, grapes and various wines.
L-(+)-Tartaric acid provides antioxidant properties and contributes to the sour taste within these products.
BIOCHEM/PHYSIOL ACTIONS OF L-(+)-TARTARIC ACID:
L-(+)-Tartaric acid serves as a donor ligand for biological processes.
L-(+)-Tartaric acid is used as a food additive in candies and soft drinks to impart a sour taste.
STORAGE OF L-(+)-TARTARIC ACID:
storage
L-(+)-Tartaric acid is stable and should be stored in a well-closed container in a cool, dry place.
INCOMPATIBILITIES OF L-(+)-TARTARIC ACID:
L-(+)-Tartaric acid is incompatible with silver and reacts with metal carbonates and bicarbonates (a property exploited in effervescent preparations).
PRODUCTION METHODS OF L-(+)-TARTARIC ACID:
L-(+)-Tartaric acid occurs naturally in many fruits as the free acid or in combination with calcium, magnesium, and potassium.
Commercially, L-(+)-tartaric acid is manufactured from potassium tartrate (cream of tartar), a by-product of wine making.
Potassium tartrate is treated with hydrochloric acid, followed by the addition of a calcium salt to produce insoluble calcium tartrate.
This precipitate is then removed by filtration and reacted with 70% sulfuric acid to yield tartaric acid and calcium sulfate.
STEREOCHEMISTRY OF L-(+)-TARTARIC ACID:
Naturally occurring form of the acid is dextro tartaric acid or L-(+)-tartaric acid (obsolete name d-tartaric acid).
Because it is available naturally, L-(+)-Tartaric acid is cheaper than its enantiomer and the meso isomer.
The dextro and levo prefixes are archaic terms.
Modern textbooks refer to the natural form as (2R,3R)-tartaric acid (L-(+)-tartaric acid), and its enantiomer as (2S,3S)-tartaric acid (D-(-)-tartaric acid).
The meso diastereomer is referred to as (2R,3S)-tartaric acid or (2S,3R)-tartaric acid.
Dextro and levo form monoclinic sphenoidal crystals and orthorhombic crystals.
Racemic tartaric acid forms monoclinic and triclinic crystals (space group P1).
Anhydrous meso tartaric acid form two anhydrous polymorphs: triclinic and orthorhombic.
Monohydrated meso tartaric acid crystallizes as monoclinic and triclinic polymorphys depending on the temperature at which crystallization from aqueous solution occurs.
Tartaric acid in Fehling's solution binds to copper(II) ions, preventing the formation of insoluble hydroxide salts.
REACTIVITY OF L-(+)-TARTARIC ACID:
L-(+)-tartaric acid, can participate in several reactions.
As shown the reaction scheme below, dihydroxymaleic acid is produced upon treatment of L-(+)-tartaric acid with hydrogen peroxide in the presence of a ferrous salt.
HO2CCH(OH)CH(OH)CO2H + H2O2 → HO2CC(OH)C(OH)CO2H + 2 H2O
Dihydroxymaleic acid can then be oxidized to tartronic acid with nitric acid.
PHYSICAL and CHEMICAL PROPERTIES of L-(+)-TARTARIC ACID:
CAS number: 87-69-4
EC number: 201-766-0
Grade: Ph Eur, BP, ChP, JP, NF, E 334
Hill Formula: C₄H₆O₆
Chemical formula: HOOCCH(OH)CH(OH)COOH
Molar Mass: 150.09 g/mol
HS Code: 2918 12 00
Density: 1.76 g/cm³ (20 °C)
Flash point: 150 °C
Ignition temperature: 425 °C
Melting Point: 170 - 172 °C
pH value: 1.6 (100 g/l, H₂O, 25 °C)
Vapor pressure: <0.05 hPa (20 °C)
Bulk density: 1000 kg/m³
Solubility: 1390 g/l
CAS: 87-69-4
Molecular Formula: HO2CCH(OH)CH(OH)CO2H
Molecular Weight: 150.09 g/mol
Storage Details: Ambient
Harmonised Tariff Code: 2918120000
CAS: 87-69-4
Molecular Formula: C4H6O6
Molecular Weight (g/mol): 150.09
MDL Number: MFCD00064207
InChI Key: FEWJPZIEWOKRBE-UHFFFAOYNA-N
Molecular Weight: 150.09
Appearance Form: crystalline
Color: white
Odor: No data available
Odor Threshold: No data available
pH: 1,0 - 2 at 150 g/l at 25 °C
Melting point/freezing point:
Melting point/range: 170 - 172 °C - lit.
Initial boiling point and boiling range: 179,1 °C at 1.010 hPa
Flash point: 150 °C - closed cup
Evaporation rate: No data available
Flammability (solid, gas):
The product is not flammable.
Upper/lower flammability or explosive limits: No data available
Vapor pressure: < 0,05 hPa at 20 °C - NF T 20-048
Vapor density: 5,18 - (Air = 1.0)
Relative density: 1,76 g/cm³ at 20 °C -
Water solubility: 150 g/l at 20 °C - completely soluble
Partition coefficient: n-octanol/water log Pow: -1,91 at 20 °C - OECD
Bioaccumulation is not expected.
Autoignition temperature: 375 °C at 1.015 hPa - NF T 20-036
Decomposition temperature: > 170 °C -
Viscosity:
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Explosive properties No data available
Flash Point: 150 °C/302 °F (Lit.)
Hazard Statements: H315-H319-H335
Solubility:
Soluble in water (115 g/100 mL at 0 °C; 126 g/100 mL at 10 °C;
139 g/100 mL at 20 °C; 156 g/100 mL at 30 °C; 176 g/100 mL at 40 °C;
195 g/100 mL at 50 °C; 217 g/100 mL at 60 °C; 244 g/100 mL at 70 °C;
273 g/100 mL at 80 °C; 307 g/100 mL at 90 °C; 343 g/100 mL at 100 °C)
Methanol (1 g/1.7 mL)
Ethanol (1 g/3 mL)
Propanol (1 g/10.5 mL)
Ether (1 g/250 mL) or glycerol;
Insoluble in chloroform.
Melting Point: 166 - 176 °C
Optical Rotation: +12 ± 5° (c=2, water)
pH: 2.2 at 25 °C (0.1 N solution)(Lit.)
pKa: pKa1 = 2.98 at 25 °C; pKa2 = 4.34 at 25 °C (Lit.)
Purity: ≥99.0%
Vapor Density 5.18 (vs air)Lit.
Appearance: Powder
Physical State: Solid
Solubility: Soluble in water
Storage: Store at room temperature
Melting Point: 170-172° C (lit.)
Optical Activity: α20/D +12.4°, c = 20 in water;
α20/D +12°±5°, c = 2 in water
Water Solubility: 161 g/L
logP: -1.3
logP: -1.8
logS: 0.03
pKa (Strongest Acidic): 2.72
pKa (Strongest Basic): -4.3
Physiological Charge: -2
Hydrogen Acceptor Count: 6
Hydrogen Donor Count: 4
Polar Surface Area: 115.06 Ų
Rotatable Bond Count: 3
Refractivity: 26.21 m³·mol⁻¹
Polarizability: 11.33 ų
Molecular Weight: 150.09 g/mol
XLogP3-AA: -1.9
Hydrogen Bond Donor Count: 4
Hydrogen Bond Acceptor Count: 6
Rotatable Bond Count: 3
Exact Mass: 150.01643791 g/mol
Monoisotopic Mass: 150.01643791 g/mol
Topological Polar Surface Area: 115 Ų
Heavy Atom Count: 10
Formal Charge: 0
Complexity: 134
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 2
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes
CAS Number: 87-69-4
Beilstein: 1725147
EC Number: 201-766-0
MDL number: MFCD00064207
PubChem CID: 444305
ChEBI: CHEBI:15671
IUPAC Name: (2R,3R)-2,3-dihydroxybutanedioic acid
SMILES: OC(C(O)C(O)=O)C(O)=O
IUPAC Name: (2R,3R)-2,3-dihydroxybutanedioic acid
Traditional IUPAC Name: L(+)-tartaric acid
Formula: C4H6O6
InChI: InChI=1S/C4H6O6/c5-1(3(7)8)2(6)4(9)10/h1-2,5-6H,(H,7,8)(H,9,10)/t1-,2-/m0/s1
InChI Key: FEWJPZIEWOKRBE-LWMBPPNESA-N
Molecular weight: 150.0868
Exact mass: 150.016437924
SMILES: OC@@HC(O)=O
Molecular Formula / Molecular Weight: C4H6O6 = 150.09
Physical State (20 deg.C): Solid
Storage Temperature: Room Temperature
(Recommended in a cool and dark place, <15°C)
CAS RN: 87-69-4
Reaxys Registry Number: 1725147
PubChem Substance ID: 87576049
Merck Index (14): 9070
MDL Number: MFCD00064207
CAS: 87-69-4
IUPAC Name: 2,3-dihydroxybutanedioic acid
Molecular Formula: C4H6O6
InChI Key: FEWJPZIEWOKRBE-UHFFFAOYNA-N
SMILES: OC(C(O)C(O)=O)C(O)=O
Molecular Weight (g/mol): 150.09
Synonym: (.+-.)-tartaric acid|L-(+)-tartaric acid
MDL Number: MFCD00064207
CAS NUMBER: 87-69-4
MOLECULAR WEIGHT: 150.10
BEILSTEIN REGISTRY NUMBER: 1725147
EC NUMBER: 201-766-0
MDL NUMBER: MFCD00064207
CBNumber: CB8212874
Molecular Formula: C4H6O6
Molecular Weight: 150.09
MDL Number: MFCD00064207
MOL File: 87-69-4.mol
Melting Point: 170-172 °C (lit.)
Alpha: 12º (c=20, H2O)
Boiling Point: 191.59°C (rough estimate)
Density: 1.76
Vapor Density: 5.18 (vs air)
Vapor Pressure: <5 Pa (20 °C)
FEMA Number: 3044 | TARTARIC ACID (D-, L-, DL-, MESO-)
Refractive Index: 12.5 ° (C=5, H2O)
Flash Point: 210 °C
Storage Temperature: Store at +5°C to +30°C.
Solubility: H2O: soluble 1M at 20°C, clear, colorless
Form: Solid
pKa: 2.98, 4.34 (at 25°C)
Color: White or colorless
Odor: Odorless at 100.00%
pH: 3.18 (1 mM solution); 2.55 (10 mM solution); 2.01 (100 mM solution)
Odor Type: Odorless
Optical Activity: [α]20/D +13.5±0.5°, c = 10% in H2O
Water Solubility: 1390 g/L (20 °C)
Merck Index: 14, 9070
JECFA Number: 621
BRN: 1725147
Dielectric Constant: 35.9 (-10°C)
Stability: Stable.
Incompatible with oxidizing agents, bases, reducing agents.
InChIKey: FEWJPZIEWOKRBE-JCYAYHJZSA-N
LogP: -1.43
FDA 21 CFR: 184.1099; 582.1099; 582.6099
Substances Added to Food (formerly EAFUS): TARTARIC ACID, L
SCOGS (Select Committee on GRAS Substances): L(+)-tartaric acid
CAS DataBase Reference: 87-69-4 (CAS DataBase Reference)
FDA UNII: W4888I119H
NIST Chemistry Reference: Butanedioic acid, 2,3-dihydroxy- [r-(r*,r*)]-(87-69-4)
EPA Substance Registry System: Tartaric acid (87-69-4)
CAS number: 87-69-4
EC number: 201-766-0
Grade: ACS, ISO, Reag. Ph Eur
Hill Formula: C₄H₆O₆
Chemical formula: HOOCCH(OH)CH(OH)COOH
Molar Mass: 150.09 g/mol
HS Code: 2918 12 00
Density: 1.76 g/cm³ (20 °C)
Flash point: 150 °C
Ignition temperature: 425 °C
Melting Point: 170 - 172 °C
pH value: 1.6 (100 g/l, H₂O, 25 °C)
Vapor pressure: <0.05 hPa (20 °C)
Bulk density: 1000 kg/m³
Solubility: 1390 g/l
Linear Formula: HO₂CCH(OH)CH(OH)CO₂H
CAS Number: 87-69-4
Molecular Weight: 150.09
Beilstein: 1725147
EC Number: 201-766-0
MDL number: MFCD00064207
UNSPSC Code: 12352100
PubChem Substance ID: 24855129
NACRES: NA.21
Physical state: crystalline
Color: white
Odor: odorless
Melting point/freezing point:
Melting point/range: 170 - 172 °C - lit.
Initial boiling point and boiling range: 399.3 °C
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits:
No data available
Flash point: 150 °C - closed cup
Autoignition temperature: 375 °C at 1.015 hPa - NF T 20-036
Decomposition temperature: > 170 °C
pH: 1.6 at 100 g/l at 25 °C
Viscosity:
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Water solubility: 1.390 g/l at 20 °C
Partition coefficient:
n-octanol/water log Pow: -1.91 at 20 °C
Vapor pressure: < 0.05 hPa at 20 °C - NF T 20-048
Density: 1.76 g/cm³ at 20 °C
Relative density: 1.878 at 20.6 °C - OECD Test Guideline 109
Relative vapor density: 5.18 - (Air = 1.0)
Particle characteristics: No data available
Explosive properties: No data available
Oxidizing properties: none
Other safety information:
Relative vapor density: 5.18 - (Air = 1.0)
Empirical formula: C₄H₆O₆
Molar mass (M): 150.09 g/mol
Density (D): 1.76 g/cm³
Boiling point (bp): 179.1 °C
Flash point (flp): >100 °C
Melting point (mp): 170 °C
WGK: 1
CAS No.: 87-69-4
EG-Nr.: 201-766-0
Molecular Formula / Molecular Weight: C₄H₆O₆ = 150.09
Physical State (20 deg.C): Solid
Storage Temperature: Room Temperature (Recommended in a cool and dark place, <15°C)
CAS RN: 87-69-4
Reaxys Registry Number: 1725147
PubChem Substance ID: 87576049
Merck Index (14): 9070
MDL Number: MFCD00064207
Form: Crystals or crystalline powder or powder
Assay from Supplier's CofA: ≥98.5% (U.S. sourced material)
Comment: Material Sourced in the U.S. and in other countries
Identification (FTIR): Conforms
Melting Point: 164-172°C (non-U.S. sourced material)
Optical Rotation: +13.0° ± 1.0° (c=20, water)
Assay (Silylated GC): ≥98.5% (non-U.S. sourced material)
Appearance (Color): White to pale cream
Assay (Aqueous acid-base Titration): ≥98.5 to ≤101.5% (non-U.S. sourced material)
IUPAC Name: 2,3-dihydroxybutanedioic acid
Molecular Formula: C₄H₆O₆
InChI Key: FEWJPZIEWOKRBE-UHFFFAOYNA-N
SMILES: OC(C(O)C(O)=O)C(O)=O
Molecular Weight (g/mol): 150.09
Synonym: (±)-tartaric acid | L-(+)-tartaric acid
MDL Number: MFCD00064207
CAS: 87-69-4
CBNumber: CB8212874
Molecular Formula: C₄H₆O₆
Molecular Weight: 150.09
MDL Number: MFCD00064207
MOL File: 87-69-4.mol
Physical state: Crystalline
Color: White
Odor: Odorless
Melting point/freezing point:
Melting point/range: 170 - 172 °C - lit.
Initial boiling point and boiling range: 399.3 °C
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Flash point: 150 °C - closed cup
Autoignition temperature: 375 °C at 1.015 hPa - NF T 20-036
Decomposition temperature: > 170 °C
pH: 1.6 at 100 g/l at 25 °C
Viscosity:
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Water solubility: 1.390 g/l at 20 °C
Partition coefficient:
n-octanol/water log Pow: -1.91 at 20 °C
Bioaccumulation is not expected.
Vapor pressure: < 0.05 hPa at 20 °C - NF T 20-048
Density: 1.76 g/cm³ at 20 °C
Relative density: 1.878 at 20.6 °C - OECD Test Guideline 109
Relative vapor density: 5.18 - (Air = 1.0)
Particle characteristics: No data available
Explosive properties: No data available
Oxidizing properties: None
Other safety information:
Relative vapor density: 5.18 - (Air = 1.0)
Empirical formula: C4H6O6
Molar mass (M): 150.09 g/mol
Density (D): 1.76 g/cm³
Boiling point (bp): 179.1 °C
Flash point (flp): >100 °C
Melting point (mp): 170 °C
WGK: 1
CAS No.: 87-69-4
EG-Nr.: 201-766-0
Molecular Formula / Molecular Weight: C4H6O6 = 150.09
Physical State (20 °C): Solid
Storage Temperature: Room Temperature
(Recommended in a cool and dark place, <15 °C)
CAS RN: 87-69-4
Reaxys Registry Number: 1725147
PubChem Substance ID: 87576049
Merck Index (14): 9070
MDL Number: MFCD00064207
Form: Crystals or crystalline powder or powder
Assay from Supplier's CofA: ≥98.5% (U.S. sourced material)
Comment: Material Sourced in the U.S. and in other countries
Identification (FTIR): Conforms
Melting Point: 164-172 °C (non-U.S. sourced material)
Optical Rotation: +13.0° ± 1.0° (c=20, water)
Assay (Silylated GC): ≥98.5% (non-U.S. sourced material)
Appearance (Color): White to pale cream
Assay (Aqueous acid-base Titration): ≥98.5 to ≤101.5% (non-U.S. sourced material)
IUPAC Name: 2,3-Dihydroxybutanedioic acid
Molecular Formula: C4H6O6
InChI Key: FEWJPZIEWOKRBE-UHFFFAOYNA-N
SMILES: OC(C(O)C(O)=O)C(O)=O
Molecular Weight (g/mol): 150.09
Synonym: (±)-Tartaric acid | L-(+)-Tartaric acid
MDL Number: MFCD00064207
CAS: 87-69-4
CBNumber: CB8212874
Molecular Formula: C4H6O6
Molecular Weight: 150.09
MDL Number: MFCD00064207
MOL File: 87-69-4.mol
FIRST AID MEASURES of L-(+)-TARTARIC ACID:
-Description of first-aid measures:
General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation: fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Immediately call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed:
No data available
ACCIDENTAL RELEASE MEASURES of L-(+)-TARTARIC ACID:
-Personal precautions, protective equipment and emergency procedures:
Ensure adequate ventilation.
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Take up dry.
Clean up affected area.
FIRE FIGHTING MEASURES of L-(+)-TARTARIC ACID:
-Extinguishing media:
Suitable extinguishing media:
Water Foam, Carbon dioxide (CO2), Dry powder
Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.
EXPOSURE CONTROLS/PERSONAL PROTECTION of L-(+)-TARTARIC ACID:
-Control parameters:
Ingredients with workplace control parameters:
-Exposure controls:
Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Tightly fitting safety goggles.
*Skin protection:
Protective clothing.
Protective boots, if the situation requires.
Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Splash contact:
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
*Body Protection:
Protective clothing.
*Hand protection:
Protective gloves.
-Control of environmental exposure:
Do not let product enter drains.
HANDLING and STORAGE of L-(+)-TARTARIC ACID:
-Conditions for safe storage, including any incompatibilities:
Storage conditions:
Tightly closed.
Dry.
-Precautions for safe handling:
*Technical measures:
Handling is performed in a well ventilated place.
Wear suitable protective equipment.
Wash hands and face thoroughlyafterhandling.
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Keep container tightly closed.
Store in a cool and dark place.
STABILITY and REACTIVITY of L-(+)-TARTARIC ACID:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature).
-Incompatible materials:
No data available