PRODUCTS

GLYCERYL MONOOLEATE

GMO = GLYCERYL MONOOLEATE

CAS NO:111-03-5
EC NO:203-827-7

Glyceryl Monooleate is a biodegradable esterification product of Glycerin and Oleic Acid.
Glyceryl Monooleate is an amber liquid to be bonded at room temperature, it can be used as water-in-oil emulsifier, pigment dispersant, lubricant and dispersing agent in chemical formulations.

Industry Uses
Fuels and fuel additives
Lubricants and lubricant additives
Paint additives and coating additives not described by other categories
Pigments
Solvents (which become part of product formulation or mixture)
Surface active agents

Consumer Uses
Cleaning and furnishing care products
Food packaging
Fuels and related products
Lawn and garden care products
Lubricants and greases
Paints and coatings
Personal care products
Plastic and rubber products not covered elsewhere

Industry Processing Sectors
All other chemical product and preparation manufacturing
All other petroleum and coal products manufacturing
Custom compounding of purchased resin
Paint and coating manufacturing
Petroleum lubricating oil and grease manufacturing
Plastic material and resin manufacturing
Soap, cleaning compound, and toilet preparation manufacturing
Textiles, apparel, and leather manufacturing

Properties:
Glyceryl Monooleate is a clear amber or pale yellow liquid (Magrabar, 1997; Uniqema, 1999).
Glyceryl Monooleate is insoluble in water, very slightly soluble in cold alcohol, and soluble in hot alcohol, in chloroform, in ether, and in petroleum ether (Food Chemicals Codex, 1996). Glyceryl Monooleate is also oil soluble, giving it particularly desirable properties as a food
emulsion (Chen and Dickinson, 1999). Like other surfactants, its properties are distinct from those of the reactants.
Glyceryl Monooleate can form a micro-emulsion in water. Glycerine is completely soluble in water, while oleic acid is 60 insoluble in water (Burdock, 1997). The hydrophilic-lipophilic balance (HLB) ofGlyceryl Monooleate is 3.8 (Griffin, 1979).

Specific Uses:
Glyceryl Monooleate is used as an antifoam in juice processing and as a lipophilic emulsifier for water-in-oil applications.
Glyceryl Monooleate also serves as a moisturizer, emulsifier, and flavoring agent. Various forms of glycerol oleate are widely used in cosmetics (Cosmetic Ingredient Review Expert Panel, 1986).
Glyceryl Monooleate is also widely used as an excipient in antibiotics and other drugs.

Glyceryl Monooleate has been used in liquid crystal studies and research shows that in the presence of monoolein, the penetration of the drug cisplatin is doubled. Monoolein (1-Oleoyl-rac-glycerol) is used in the development of monoolein-based nanoparticulate liquid dispersions as possible vehicles for drug delivery.

Glyceryl monooleate (GMO) is a polar lipid that can exist in various liquid crystalline phases in the presence of different amounts of water.
Glyceryl monooleate is regarded as a permeation enhancer due to its amphiphilic property. Various phases of GMO/solvent system containing sodium fluorescein were prepared to compare permeability using confocal laser scanning microscopy (CLSM).

Glyceryl monooleate (gliseril monooleat), commonly known as Glyceryl monooleate (gliseril monooleat), is a monoglyceride commonly used as an emulsifier in foods.
Glyceryl monooleate takes the form of a white, odorless, and sweet-tasting flaky powder that is hygroscopic. Chemically it is the glycerol ester of stearic acid.

Glyceryl monooleate (gliseril monooleat) exists as three stereoisomers, the enantiomeric pair of 1-Glyceryl monooleate (gliseril monooleat) and 2-Glyceryl monooleate (gliseril monooleat). Typically these are encountered as a mixture as many of their properties are similar.

Glyceryl monooleate (gliseril monooleat) occurs naturally in the body as a product of the breakdown of fats by pancreatic lipase.
Glyceryl monooleate is present at very low levels in certain seed oils.

Glyceryl monooleate (gliseril monooleat) is a food additive used as a thickening, emulsifying, anticaking, and preservative agent; an emulsifying agent for oils, waxes, and solvents; a protective coating for hygroscopic powders; a solidifier and control release agent in pharmaceuticals; and a resin lubricant.
Glyceryl monooleate is also used in cosmetics and hair-care products.

Glyceryl monooleate (gliseril monooleat) is largely used in baking preparations to add; to the food.
Glyceryl monooleate is somewhat responsible for giving ice cream and whipped cream their smooth texture.
Glyceryl monooleate is sometimes used as an antistaling agent in bread.

Glyceryl monooleate (gliseril monooleat) is an oil soluble surfactant and is classified as a monoglyceride.
Glyceryl monooleate (gliseril monooleat) is used as an antifoam in juice processing and as a lipophilic emulsifier for water-in-oil applications.
Glyceryl monooleate (gliseril monooleat) is a moisturizer, emulsifier, and flavoring agent. Various forms of glycerol oleate are widely used in cosmetics and it is also used as an excipient in antibiotics and other drugs.
Glyceryl monooleate (gliseril monooleat) is classified by the U.S. Food and Drug Administration (FDA) as generally recognized as safe (GRAS).

Glyceryl Monooleate(C21H40O4) is a clear amber or pale yellow liquid.
Glyceryl Monooleate is an oil soluble surfactant and is classified as a monoglyceride.
Glyceryl Monooleate is used as an antifoam in juice processing and as a lipophilic emulsifier for water-in-oil applications.
Glyceryl Monooleate is a moisturizer, emulsifier, and flavoring agent. Various forms of glycerol oleate are widely used in cosmetics and it is also used as an excipient in antibiotics and other drugs.

Chemical Properties
White Waxy Solid

Uses
Monoglycerides fatty acid esters 93% 1-Oleoyl, 7% 2-oleoyl.

Uses
glyceryl oleate is an emollient and stabilizer derived from olive oil.
Glyceryl Monooleate is a water-in-oil emulsifier that allows for softer emulsions than Glyceryl Monooleate.

Uses
Glyceryl Monooleate is a flavoring agent that is prepared by esterification of commercial oleic acid that is derived either from edible sources or from tall oil fatty acids.

Glyceryl Monooleate contains and glyceryl esters of fatty acids present in commercial oleic acid. The ingredient is also used as an adjuvant and as a solvent and vehicle.
Definition
ChEBI: A 1-monoglyceride where the acyl group is oleoyl.

Sources/Uses
Used in foods, pharmaceuticals, cosmetics, rust-preventive oils, vinyl light stabilizers, odorless base paints, textile finishing, and flavoring; Used as emulsifier for liquid and paste waxes, polishes, and cleaners;

Glyceryl Monooleate is a clear or light yellow oil that is used as an antifoam in juice processing.
Glyceryl Monooleate has been used as an emulsifier, a moisturizer, and a flavoring agent.

Glyceryl Monooleate, also called monstearin or glyceryl stearate, is a hard, waxy mass, powder or flake ingredient, which is typically white.
Glyceryl Monooleate is derived from vegetable oils.

Glyceryl Monooleate is often used as an emulsifier.
Glyceryl Monooleate is found in dozens of personal care products, such as moisturizers, eye cream, sunscreen, makeup, hand cream, and other products.
Glyceryl Monooleate is also used in foods as a thickener.

Glyceryl monooleate also known as GMO is a multi-functional emulsifier useful in the production of cosmetics, pharmaceuticals, food and plastic products.

What is Glyceryl Monooleate?
Glyceryl Monooleate is an effective emulsifier used in the baking industry available in the form of small beads, flakes, or powders. In addition to emulsification, GMS is a thickening agent and a stabilizer.

In baking, it is used to improve dough quality and stabilize fat/protein emulsions.

Composition
Glyceryl Monooleate is a non-ionic ester of glycerol and stearic acid.
Glyceryl Monooleate is soluble in ethanol at 122°F (50°C) but immiscible with water.
Glyceryl Monooleate often consists of a mixture of mono, di, and triesters of fatty acids occurring in food oils and fats. They may contain small amounts of free fatty acids and glycerol.

Commercial Production
Glyceryl Monooleate is produced either through heating oils/fats with excess glycerol or by direct esterification of glycerol (of animal or plant sources) with stearic acid. The proportion of monoester formed is dependent on the proportion of glycerol and reaction temperature range of 86-140°F (60-80°C). Further purification is carried out by high vacuum distillation.

Function
The ratio of hydrophilic to lipophilic moieties, called hydrophilic-lipophilic balance (HLB) is used in classifying emulsions. HLB values range from 0-20 with lower values indicating dominant lipophilic character while higher values indicate hydrophilic character.
Glyceryl Monooleate has a HLB value of 3.8, making it lipophilic and suitable for uses in w/o emulsions, such as batters and doughs, dairy and other products.3

Glyceryl Monooleate is used in a paste form, i.e. mixed with water and other ingredients to improve gel stability.
Glyceryl Monooleate is an unsaturated monoglyceride and offers better stability than other unsaturated monoglycerides, such as oleic acid.

Glyceryl Monooleate is used in the baking industry to:

Help in the formation and maintenance of uniform dispersions of immiscible solvents.
Stabilize emulsions via displacing proteins from oil, wax or solvent surfaces.Improve bread texture, and retard staling due to its complexation with starch amylopectin
Improve aeration of doughs and batters.

Applications
Glyceryl Monooleate has been used in the following applications:

To improve the physical and rheological properties of the batter and thus better-quality cakes
In sponge cakes and pancakes for aeration.
Dairy products such as cream, whipped cream, ice cream, cream powder, imitation creams, etc.
Fruit/vegetable spreads, jams, jellies, marmalades

Glyceryl Monooleate - is a mixture of monoglycerides, mainly glyceryl monooleate, together with variable quantities of diglycerides and triglycerides.
Glyceryl Monooleate is a synthetic compound that is considered a monoglyceride.

Glyceryl Monooleate is an anionic monoester of stearic acid with glycerin.
Glyceryl Monooleate is an O / W emulsifier and can be used as it is or as a co-emulsifier to adjust the viscosity of the final product.
Glyceryl Monooleate is incorporated in face care products providing stability to the final emulsion.
Glyceryl Monooleate is a clear or light yellow oil that is used as an antifoam in juice processing.
Glyceryl Monooleate has been used as an emulsifier, a moisturizer, and a flavoring agent.

Glyceryl Monooleate, commonly known as monoolein, is a glycerol monoester of oleic acid. The PhEur describes glyceryl monooleate as a mixture of monoacylglycerols, mainly monooleoylgcerols, together with variable quantities of di-and tri-acyglycerols.

Glyceryl monooleates are defined by the nominal content of monoacylglycerols and obtained by partial glycerolysis of vegetable oils mainly containing triacylglycerols of oleic acid or by esterification of glycerol by oleic acid, this fatty acid being of vegetable or animal origin. A suitable antioxidant may be added.

Glyceryl Monooleate occur as amber oily liquids, which may be partially solidified at room temperature and have a characteristic odor.

Physicochemical Properties
Physical form Liquid
Boiling point 238-2400C
Density 0.942g/cm3
Flash point 216 oC
HLB value 3.3 (n/e); 4.1 (s/e)
Melting point 350C
Refractive index 1.4626
Solubility Soluble in ethanol (95%) and mineral. Emulsifying grade is dispersible in water.
Viscosity (kinematic) 100 – 100cSt at 400C

Glyceryl Monooleate is also known as 1-monoolein and 2,3-Dihydroxypropyl oleate.
Glyceryl Monooleate is a classified member of the 1-monoacylglycerols.
Glyceryl Monooleate is a white, odorless, sweet-tasting powder.

Glyceryl Monooleate is the glycerol ester of esteric acid.
Glyceryl Monooleate is neutral in nature and insoluble in water.
Glyceryl Monooleate consists of 3 stereoisomers, the enantiomeric pair of 1-glycerol Monooleate and 2-glycerol Monooleate.

Applications of Glyceryl Monooleate:
Glyceryl Monooleate is mainly used as an emulsifier and thickening agent in the food and beverage industry and cosmetics industry.
Glyceryl Monooleate is also used as a stabilizer in the pharmaceutical industry.
Glyceryl Monooleate is used as an emulsifying agent for oils and waxes.
Glyceryl Monooleate acts as a protective coating for hygroscopic dusts.
Glyceryl Monooleate is also used as an anti-adhesive agent and preservative agent in the baking industry.
Glyceryl Monooleate is used as an additive in fuels, paints and coatings, lubricants and greases.

Usage: Emulsifiers for pharmaceuticals and cosmetics, Additives for Lubricants

Glyceryl Monooleate has a wide application as Glyceryl Monooleate, Emulsifier, Fiber matting agent, PVC bottle, film, foil manufacturing.

Glyceryl Monooleate, Mold release agent, Pigment dispersant, Rust inhibitor, lubricant etc. Can be used as

Glyceryl Monooleate is used as a water-in-oil emulsifier for soft creams with a high degree of water absorbency, good resistance to temperature fluctuations.

Glyceryl Monooleate can be used as emollient and dispersing agent in bath oil, pigment dispersant in make-up, and lubricant and moisturizing cream.
Glyceryl Monooleate is also used as a lubricant and antistatic aid in the processing of PVC films and is often used as an anti-rust additive for compound oils.
In the textile industry, Glyceryl Monooleate finds applications in the preparation of neutral emulsions of Lubricating oils or finishing waxes.
Glyceryl Monooleate is also used as a dispersing agent for pigments and as a fiber matting agent and as a lubricant component in synthetic fiber spinning surfaces.

Glyceryl Monooleate is used as an emulsifier and diluent in oleoresins and lubrication applications.
Glyceryl Monooleate helps to prepare stable emulsion and improve dispersibility for coffee whiteners, liquids.
Glyceryl Monooleate also acts as antifoaming agents for protein foams.
Glyceryl Monooleate can be used for flavor stability in sports drinks and for Vitamin oil solubilizer for Vitamins, Vitamin Mineral Supplements and Vitamin drops.

Usage: Pharmaceutical & Veterinary, Flavors & Fragrances, Adhesives & Lubricants, Inks & Coatings, Industrial, Cosmetic & Personal Care, Cleaning & Detergents

Glyceryl Monooleate is used as a defoamer in juice processing and as a lipophilic emulsifier for water-in-oil applications.
Glyceryl Monooleate also serves as a humectant, emulsifier, and sweetener. Various forms of glycerol oleate are widely used in cosmetics.
Glyceryl Monooleate is also widely used as an excipient in antibiotics and other drugs.

Glyceryl monooleate is prepared by esterification of commercial oleic acid obtained from edible sources or tallow fatty acids.

Glyceryl Mono Oleate is a drug delivery system and encapsulation agent in pharmaceutical preparations.
Glyceryl Mono Oleate is an emulsifier, emollient in cosmetic formulations such as sun care products, antiperspirants, hand and body lotions, shower gels/body shampoos, styling aids, color cosmetics.

Glyceryl Mono Oleate is an amber liquid, can be used as W/O emulsifier, pigment dispersant, lubricant and dispersing agent.

Glyceryl Monooleate is an emulsifier and dispersant made using glycerin and oleic acid from vegetable oil sources.

Glyceryl monooleate (GMO) is one of the most popular amphiphilic lipids that can promote the development of well-defined, thermodynamically stable nanostructures called lyotropic liquid crystal dispersions in the presence of different amounts of water and appropriate amount of stabilizer.

Glyceryl monooleate (GMO) is a well-known molecule widely used as an emulsifying agent, biocompatible controlled release material, and food additive.
Glyceryl monooleate is considered a non-toxic, biodegradable and biocompatible material classified as "generally recognized as safe" (GRAS).
Glyceryl monooleate is included in the FDA's Guide to Inactive Ingredients and is available in non-parenteral medications.

Glyceryl monooleate (GMO) is defined as a specialized lipid that plays an important role in drug delivery systems due to its ability to self-assemble in water and form a variety of well-defined, thermodynamically stable liquid crystal structures.
Glyceryl monooleate can also be used as one, two or threeexhibits long-range order in size.
Glyceryl monooleate is widely known as a non-toxic, biodegradable and biocompatible product.
Glyceryl monooleate has been generally recognized as safe (GRAS) status from the Food and Drug Administration (FDA) and is included in the Inactive Ingredients Guidelines.

Properties:
Glyceryl monooleate is a clear amber or pale yellow liquid.
Glyceryl monooleate is insoluble in water, slightly soluble in cold alcohol, and soluble in hot alcohol, chloroform, ether and petroleum ether.
Glyceryl monooleate is also fat soluble, giving it particularly desirable properties as a food emulsion.
Like other surfactants, their properties differ from those of the reactants.
Glyceryl monooleate can form a microemulsion in water.
While glycerin is completely soluble in water, oleic acid is insoluble in water.
The hydrophilic-lipophilic balance (HLB) of glycerol monooleate is 3.8.

Uses
Glyceryl monooleate is an emollient and stabilizer derived from olive oil.
Glyceryl monooleate is a water-in-oil emulsifier that allows for softer emulsions than glyceryl stearate.

Uses
Glyceryl Monooleate is a flavoring agent that is prepared by esterification of commercial oleic acid that is derived either from edible sources or from tall oil fatty acids.
Glyceryl monooleate contains and glyceryl esters of fatty acids present in commercial oleic acid. The ingredient is also used as an adjuvant and as a solvent and vehicle.

UPAC names
2,3-dihydroxypropyl (9Z)-octadec-9-enoate
2,3-dihydroxypropyl (Z)-octadec-9-enoate
2,3-Dihydroxypropyl oleate
2,3-dihydroxypropyl oleate

SYNONYMS:
1-Oleoyl-rac-glycerol
(9Z)-9-Octadécénoate de 2,3-dihydroxypropyle [French] [ACD/IUPAC Name]
1-(cis-9-Octadecenoyl)-rac-glycerol
111-03-5 [RN]
1728976
1-GLYCERYL OLEATE
1-Mono(cis-9-octacenoyl)glycerol
1-Monooleoylglycerol
1-monooleoyl-rac-glycerol
1-oleoyl glycerol
1-OLEOYLGLYCEROL
1-O-Oleyl-rac-glycerol
2,3-Dihydroxypropyl (9Z)-9-octadecenoate [ACD/IUPAC Name]
2,3-Dihydroxypropyl (9Z)-octadec-9-enoate
2,3-Dihydroxypropyl oleate
2,3-Dihydroxypropyl-(9Z)-9-octadecenoat [German] [ACD/IUPAC Name]
203-827-7 [EINECS]
9-Octadecenoic acid, 2,3-dihydroxypropyl ester, (9Z)- [ACD/Index Name]
Aldo HMO
a-Monoolein
D3AEF6S35P
Danisco MO 90
dl-α-Monoolein
DL-α-Monoolein
Glycerin 1-monooleate
Glycerol 1-monooleate
Glycerol α-monooleate
GLYCERYL 1-OLEATE
Glyceryl cis-9-octadecenoate
Glyceryl Monooleate
Glyceryl Monooleate (VAN)
MFCD00042735 [MDL number]
MG(18:1(9Z)/0:0/0:0)[rac]
Monoolein
Monoolein (VAN)
Oleic acid glycerol monoester
Oleic monoglyceride
OLEOYL GLYCEROL
rac-1-Monooleoylglycerol
rac-Glycerol 1-monooleate
UNII:D3AEF6S35P
α-Monoolein
α-Monoolein