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TETRASODIUMPYROPHOSPHATE

TETRASODIUMPYROPHOSPHATE

Tetrasodium pyrophosphate is an inorganic salt used as a buffering agent.

Tetrasodium pyrophosphate, also called sodium pyrophosphate, tetrasodium phosphate or TSPP, is an inorganic compound with the formula Na4P2O7. 
As a salt, Tetrasodium pyrophosphate is a white, water-soluble solid. 
Tetrasodium pyrophosphate is composed of pyrophosphate anion and sodium ions. 


CAS: 7722-88-5
European Community (EC) Number: 231-767-1

IUPAC Name: tetrasodium;phosphonato phosphate

Molecular Formula: Na4P2O7
Na4O7P2
Molecular Weight: 265.90 g/mol

Odor: Odorless.
Boiling Point: Decomposes
Melting Point: 1810 °F 
Solubility: 7 % at 77 °F 
Density: 2.45
Vapor Pressure: 0 mmHg (approx) 
pH: Between 9,8 and 10,8 (1 % solution)
INDEX OF REFRACTION: 1.450, 1.453, 1.460 /DECAHYDRATE/


Tetrasodium pyrophosphate is an inorganic salt used as a buffering agent.

Tetrasodium pyrophosphate, also called sodium pyrophosphate, tetrasodium phosphate or TSPP, is an inorganic compound with the formula Na4P2O7. 
As a salt, Tetrasodium pyrophosphate is a white, water-soluble solid. 
Tetrasodium pyrophosphate is composed of pyrophosphate anion and sodium ions. 


The principal food uses for tetrasodium pyrophosphate are as an emulsifier, buffer, nutrient, dietary supplement, sequestrant, and texturizer in bread and cereal products. 
Tetrasodium pyrophosphate may be prepared from processes involving neutralization of phosphoric acid using sodium carbonate or sodium hydroxide to produce dibasic sodium phosphate, which is further dehydrated molecularly to produce TSPP. 


Tetrasodium pyrophosphate can be prepared by molecular dehydration of dibasic sodium phosphate at 500°C.
Sodium phosphates are generally prepared by the partial or total neutralization of phosphoric acid using sodium carbonate or sodium hydroxide. 
Crystals of a specific hydrate can then be obtained by evaporation of the resultant solution within the temperature range over which the hydrate is stable. 
Another way to prepare Tetrasodium pyrophosphate involves the calcination of sodium tripolyphosphate and a sodium salt. 


Tetrasodium Pyrophosphate (TSPP) is a widely used chemical in many different applications. 
In food, Tetrasodium pyrophosphate is used as a buffer for puddings and processed foods. It can also be used as a calcium sequestrant. 
For water treatment, Tetrasodium pyrophosphate has excellent softening, peptizing, and dispersing agent properties. 
This can help with magnesium hardness, scale control, sequestering, and red and black water control. 
Tetrasodium pyrophosphate also meets the EPA Lead and Copper rule which means it is also used frequently in corrosion prevention.

Typical Uses:

-Breath Fresheners
-Buffer
-Cheese
-Dispersant
-Ice Cream
-Marshmellow
-Mouthwash
-Potato Products
-Poultry
-Processed Meat
-Protein Modifier
-Seafood
-Sequestrant
-Teeth Whitening
-Toothpaste
-Whipped Toppings

Tetrasodium pyrophosphate is an inorganic compound with the formula Na4P2O7.
As a salt, Tetrasodium pyrophosphate is a white, water-soluble solid. 
Tetrasodium pyrophosphate is composed of pyrophosphate anion and sodium ions.

Tetrasodium pyrophosphate, also known as TSPP, is a sodium phosphate derivative with the chemical formula Na₄P₂O₇. 
Tetrasodium pyrophosphate is a white, crystalline powder that is highly soluble in water. 
Tetrasodium pyrophosphate has various applications, primarily in the food industry and as a detergent additive.


Tetrasodium pyrophosphate is odourless, white powder or granules, which comes in different grades.  
Tetrasodium pyrophosphate also called Sodium pyrophosphate is used in many applications as a buffering agent, an emulsifier, a dispersing agent, a thickening agent, general sequestering agent, chelating agent in antimicrobial studies, and in the food industry as a nutrient, dietary supplement and texturier in food additive. 
Tetrasodium pyrophosphate also acts as a tartar control agent in toothpaste and dental floss.  
Tetrasodium pyrophosphate is also used as a food additive in common foods such as chicken nuggets, crab meat, and canned tuna. 

Tetrasodium pyrophosphate is used in cleaning compounds for the metal finishing industry.  
Tetrasodium pyrophosphate is used on oil well drilling rigs for cleaning the mud off the equipment. 
Tetrasodium pyrophosphate has excellent applications in rust removal, ink erasers, and electrodeposition on metals. 
Tetrasodium pyrophosphate is also used as a water softener, wool de-fatting agent, soap and synthetic detergent builder, and general sequestering agent.


Tetrasodium pyrophosphate (TSPP), also called tetrasodium disphosphate or sodium pyrophosphate, is a synthetic ingredient that can be used as an acid regulator, sequestrant, protein modifier, coagulant, and a dispersing agent in food with the European food additive number E450. 

Tetrasodium pyrophosphate can be produced by the neutralization of phosphoric acid with sodium hydroxide with mol proportions of 2:1.

Food grade Tetrasodium pyrophosphate exists as two forms, and follows the corresponding chemical formula: 

Tetrasodium pyrophosphate Anhydrous: Na4P2O7
Tetrasodium pyrophosphate Decahydrate: Na4P2O7 · 10H2O

Uses:

Tetrasodium pyrophosphate is used as a buffering agent, an emulsifier, a dispersing agent, and a thickening agent, and is often used as a food additive. 
Common foods containing tetrasodium pyrophosphate include chicken nuggets, marshmallows, pudding, crab meat, imitation crab, canned tuna, and soy-based meat alternatives and cat foods and cat treats where it is used as a palatability enhancer.

In toothpaste and dental floss, tetrasodium pyrophosphate acts as a tartar control agent, serving to remove calcium and magnesium from saliva and thus preventing them from being deposited on teeth. 
Tetrasodium pyrophosphate is used in commercial dental rinses before brushing to aid in plaque reduction.

Tetrasodium pyrophosphate is sometimes used in household detergents to prevent similar deposition on clothing, but due to its phosphate content it causes eutrophication of water, promoting algae growth.

The specific use petitioned is as a pH buffer and dough conditioner for use in organic meat alternative products. 
Cereal and baked goods account for the greatest food use of phosphate additives. 
The principal food uses for tetrasodium pyrophosphate are as an emulsifier, buffer, nutrient, dietary supplement, sequestrant, and texturizer. 
Tetrasodium pyrophosphate is also used in cleaning compounds, oil well drilling, rust removal, ink erasers, and in electrodeposition on metals. 

Tetrasodium Pyrophosphate,(TSPP) Granular & Powder is an anhydrous, white, crystalline material in powder form. 
Tetrasodium pyrophosphate is used as a dispersing agent, sequestrant, buffering agent, protein modifier, and coagulant.

Tetrasodium pyrophosphate is used to modify the proteins enabling them to retain moisture during storage, thawing, and cooking. 
Tetrasodium pyrophosphate also increases shelf life of the product by sequestering multivalent cations responsible for lipid oxidation and rancidity development. 
Tetrasodium pyrophosphate is added to improve whipping efficiency and improve foam stability. 
Granular Tetrasodium pyrophosphate helps to buffer the pH of the processed cheese and interacts with milk proteins to promote emulsification. 
Tetrasodium pyrophosphate sequesters iron in potato products to prevent after-cooking blackening and to stabilize color. 
To maintain fat dispersion in an ice cream/dessert mix, Tetrasodium pyrophosphate may be added so "churning" will not form lumps of butter during freezing.

With the properties of chelating metal ions, increasing protein water holding capacity, PH buffering, stabilization, emulsification, casein thickening and ect, tetrasodium pyrophosphate is widely used in food to improve the gel strength and the tenderness of meat products/analogs. 

Also, Tetrasodium pyrophosphate is used with other phosphates (e.g. sodium hexametaphosphate, sodium acid pyrophosphate) in seafood to increase the water retention. 


Food
Food grade Tetrasodium pyrophosphate is mainly used in following two functions:

A buffering agent: with the PH value from 9.8 to 10.8 (1% solution), TSPP can be used as an alkaline to adjust pH in processed food, pudding and etc.
A calcium sequestrant: TSPP can remove naturally occurring calcium ions from proteins and crosslink with proteins, which results in accelerating protein gelation, improving texture (mouthfeel) and reducing cooking loss in meat analog production (e.g. soy protein).

Following food list may contain TSPP:

-Meat analogs, such as soy or wheat based food, with the appearance, flavor and mouth-feel the same with meat but not made from meat. 
-Marshmallows
-Pudding
-Cheese
-Ice cream
-Milk protein products
-Tuna
-Toothpaste

Orally the main purpose of TSPP is to prevent the formation of calculus by reducing the deposition of calcium and magnesium on teeth. 
Thus it is commonly used as the anticalculus component of many tartar-control toothpastes and mouth rinse. 
Disodium pyrophosphate also has the same function.

Applications :

• Tetra Sodium pyrophosphate is used as a buffering agent, also as an emulsifier and as a dispersing agent
• Tetra Sodium Pyrophosphate also used as a thickening agent and also often used as a food additive
• Tetrasodium pyrophosphate is used in common baking powders and also in toothpaste and dental floss as a tartar control
• Sometimes Tetrasodium pyrophosphate is also used in household detergents

Production
Tetrasodium pyrophosphate is produced by the reaction of furnace-grade phosphoric acid with sodium carbonate to form disodium phosphate, which is then heated to 450 °C to form tetrasodium pyrophosphate:

2 Na2HPO4 → Na4P2O7 + H2O


Physical Description

Tetrasodium pyrophosphate appears as odorless, white powder or granules. 
mp: 995 °C. 
Density: 2.53 g/cm3. 
Solubility in water: 3.16 g/100 mL (cold water); 40.26 g/100 mL boiling water. 
Used as a wool de-fatting agent, in bleaching operations, as a food additive. 
The related substance tetrasodium pyrophosphate decahydrate (Na4P2O7*10H2O) occurs as colorless transparent crystals. 
Loses its water when heated to 93.8 °C.

Action:
Phosphates in general interact with proteins, such as casein, to function as emulsifiers and prevent the separation of both fat and water in cheese. 
Casein is precipitated by pyrophosphates to form thick gels. 
This is believed to be the result of the negative ionic charge of pyrophosphate anions reacting with the positively charged cations in casein. 
Pyrophosphates are good sequestrants for copper and iron, which often catalyze oxidation in fruits and vegetables. 
One source notes considerable debate about the mechanisms of phosphate functionality, with reference to water holding capacity of meat and fish. 
The addition of phosphates to muscle food homogenates, raw and cooked meats, in sausages, hams, poultry, and seafood will decrease the amount of drip loss, enhance waterbinding and water holding capacity resulting in enhanced sensory characteristics. 


Combinations:
Tetrasodium pyrophosphate is combined with calcium phosphates as leavening agents. 
Tetrasodium pyrophosphate has a synergistic effect on various foaming agents, such as alkyl polycarboxylates and triethyl citrate. 
Other salts, such as sodium chloride, can have a synergistic effect on water-holding capacity of sodium phosphates


Historic Use:
The interaction of shorter chain polyphosphates—including pyrophosphates—with proteins was first known in 1916. 
Industrial manufacturing of pyrophosphates occurred as early as the 1920s. 
Commercial application of polyphosphates for preparing vegetable protein-polyphosphate compounds in food processing appears to date back to the late 1940s.


Uses:

-Buffering Agent

-Emulsifier

-Dispersing Agent

-Thickening Agent

-Tartar Control Agent

-Toothpaste


SYNONYMS:

Sodium pyrophosphate
TETRASODIUM PYROPHOSPHATE
7722-88-5
TSPP
Phosphotex
Tetrasodium diphosphate
Sodium diphosphate
Diphosphoric acid, tetrasodium salt
Victor TSPP
Caswell No. 847
Sodium pyrophosphate tetrabasic
Natrium pyrophosphat
Sodium pyrophosphate [USAN]
Sodium diphosphate, anhydrous
Pyrophosphoric acid tetrasodium salt
Sodium phosphate (Na4P2O7)
HSDB 854
sodium pyrophosphate(V)
Sodium diphosphate (Na4P2O7)
Sodium pyrophosphate, tetrabasic
Sodium pyrophosphate (Na4P2O7)
Anhydrous tetrasodium pyrophosphate
Tetrasodium pyrophosphate, anhydrous
EINECS 231-767-1
NSC 56751
EPA Pesticide Chemical Code 076405
DTXSID9042465
UNII-O352864B8Z
CHEBI:71240
NSC-56751
Na4P2O7
O352864B8Z
DTXCID7022465
EC 231-767-1
Sodium pyrophosphate (USAN)
Natrium pyrophosphat [German]
SODIUM PYROPHOSPHATE (II)
SODIUM PYROPHOSPHATE [II]
SODIUM PYROPHOSPHATE (MART.)
SODIUM PYROPHOSPHATE [MART.]
Tetranatriumpyrophosphat [German]
MFCD00003513
Sodium diphosphate tetrabasic
Tetrasodium pyrophosphate, anhydride
Tetrasodium pyrophosphate (anhydrous)
SODIUMPYROPHOSPHATE
tetra sodium pyrophosphate
ACCOLINE 126
Na4O7P2
TETRON (DISPERSANT)
Diphosphoric acid sodium salt
DTXCID408842
FQENQNTWSFEDLI-UHFFFAOYSA-J
Sodium diphosphate (Na4(P2O7))
SODIUM PYROPHOSPHATE [FCC]
Tetrasodium pyrophosphate Anhydrous
SODIUM PYROPHOSPHATE [HSDB]
CS-B1771
SODIUM PYROPHOSPHATE [VANDF]
tetrasodium (phosphonooxy)phosphonate
Tox21_110033
SODIUM PYROPHOSPHATE [WHO-DD]
TETRASODIUM PYROPHOSPHATE [MI]
AKOS015914004
AKOS024418778
Diphosphoric acid, sodium salt (1:4)
TETRASODIUM PYROPHOSPHATE [INCI]
NCGC00013687-01
CAS-7722-88-5
TETRASODIUM DIPHOSPHATE (NA4P2O7)
TETRASODIUM PYROPHOSPHATE (NA4P2O7)
E 450
FT-0689073
D05873
E75941
EN300-332889
Q418504
1004291-85-3


 

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